Enolates Study guides, Revision notes & Summaries

Reactions and details covered from Dr. Feducia's Orgo 2 class in Summer 19.

Carbanions are looked at with examples and how to stabilise through inductive and resonance effects. Enolate formation reaction is introduced and a look at different bases and how complete deprotonation can be. The stabilisation of enolates develops the topic before the α-halogenation by base or acid catalysed reactions. More enolate reactions are given. Alkylate aldehydes formation through enamines. Aldol reaction through acid and base conditions in either equilibrating and non-equilibrating c...

Notes on carbonyl chemistry, nucleophilic addition to carbonyls, use of organometallic reagents, acetal formation, nucleophilic substitution, the reactivity of these reagents, enolates

Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Carbonyl rearrangements: Schmidt, Beckmann, Curtius, Wolff Enols and Enolates: ketone deuteration, alpha-halogenations, alpha-alkylations, enamine alkylations, decarboxylation Aldol Reaction: general, condensation, Cross Aldol condensation, ...

Complete Solutions Manual for Organic Chemistry, 4th Edition by David R. Klein ; ISBN13: 9781119659594. Full Chapters included Chapter 1 to 27. 1. A Review of General Chemistry: Electrons, Bonds and Molecular Properties. 2. Molecular Representations. 3. Acids and Bases. 4. Alkanes and Cycloalkanes. 5. Stereoisomerism. 6. Chemical Reactivity and Mechanisms. 7. Alkyl Halides: Nucleophilic Substitution and Elimination Reactions. 8. Addition Reactions of Alkenes 356 9. Alkynes. 10. Radical...