Enamine Study guides, Revision notes & Summaries

This document contains digitally taken, handwritten notes for the reactions of aldehydes and ketones. It covers information including nomenclature, synthesis and reactions with strong and weak nucleophiles. It also shows how to make hemi-acetals and acetals. Other reactions include the Wittig reaction and how to synthesize and Ylide. Notes are color coded.

Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Carbonyl rearrangements: Schmidt, Beckmann, Curtius, Wolff Enols and Enolates: ketone deuteration, alpha-halogenations, alpha-alkylations, enamine alkylations, decarboxylation Aldol Reaction: general, condensation, Cross Aldol condensation, ...

Carbanions are looked at with examples and how to stabilise through inductive and resonance effects. Enolate formation reaction is introduced and a look at different bases and how complete deprotonation can be. The stabilisation of enolates develops the topic before the α-halogenation by base or acid catalysed reactions. More enolate reactions are given. Alkylate aldehydes formation through enamines. Aldol reaction through acid and base conditions in either equilibrating and non-equilibrating c...

Protecting groups, reductive amination, Primary and secondary amine reactions with ketone, reverse wittig reaction, design a synthesis, alkyne substitution, base and substitution reaction, KrCrO3 in acid (H2SO4) Jones oxidation, Swern oxidation, enamine and imine. All answered - great worksheet exam prep and organic chemistry knowledge! Generic stuff they test in second year midterm/exams!

Protecting groups, reductive amination, Primary and secondary amine reactions with ketone, reverse wittig reaction, design a synthesis, alkyne substitution, base and substitution reaction, KrCrO3 in acid (H2SO4) Jones oxidation, Swern oxidation, enamine and imine. All answered - great worksheet exam prep and organic chemistry knowledge!

Protecting groups, reductive amination, Primary and secondary amine reactions with ketone, reverse wittig reaction, design a synthesis, alkyne substitution, base and substitution reaction, KrCrO3 in acid (H2SO4) Jones oxidation, Swern oxidation, enamine and imine. All answered - great worksheet exam prep and organic chemistry knowledge!