Mannich reaction Study guides, Revision notes & Summaries

Organic chemistry,name reaction,mannich reaction and it's mechanism

Brief overview of reactions and mechanisms described in chapter 21.

Summary of S3 - Catalytic Asymmetric Reactions 1. Introduction 2. Organocatalytic aldol reactions 3. Asymmetric Mannich, oxygenation and amination reactions 4. Other organocatalytic enamine reactions 5. Organocatalytic radical reactions 6. Asymmetric iminium ion catalysis 7. Catalytic asymmetric cycloaddition reactions 8. Asymmetric nucleophilic addition to aldehydes

An introduction to heterocycles with examples of aromatic and non-aromatic heterocycles and how the aromaticity is formed in the 5 and 6 membered heterocycles. It then goes on to look at the reactions of 5 membered heterocycles including Friedel Crafts, Mannich reaction and Vilsmeir Reaction. This is further developed by looking at how they react when already substituted and how resonance forms explain their selectivity. Metallation and reduction reactions are looked at. How to synthesise hetero...

Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Carbonyl rearrangements: Schmidt, Beckmann, Curtius, Wolff Enols and Enolates: ketone deuteration, alpha-halogenations, alpha-alkylations, enamine alkylations, decarboxylation Aldol Reaction: general, condensation, Cross Aldol condensation, ...