Diels alder Study guides, Revision notes & Summaries

This document contains digitally taken, handwritten notes for the conjugated pi systems chapter. It covers topics on HOMO and LUMO structures, energy levels as well as molecule stability. Notes also cover information dienes, their nomenclature as well as their properties. Thoroughly explained subtopics include 1,2 and 1,4 addition, pericyclic reactions, Diel’s - Alder reaction as well as sigmatropic, Cope and Cleissen rearrangements. Notes show mechanism thoroughly and include explanation as n...

This study guide involves the stability of conjugated dienes, kinetic vs. thermodynamic control, and diels alder reactions. These are the first topics in organic chemistry II. These notes are written in an understated way and led me to receive a 92 on my test.

Chapter on Pericyclic reactions including full reaction mechanisms for every reaction and Woodward-Hoffman/Orbital analysis for key examinable material. Cycloadditions, sigmatropic rearrangements and electrocyclic reactions.

Includes how to determine the amount of hydrogen signals in one molecule as well as how many signals would show up in a NMR spectrum. Includes diels alder reactions, how to determine the starting materials for a diels alder reaction. Includes what causes drudged products , allylic halogenation, allylic chlorination, stability of carbocations and conjugated intermediates

Answer Key on last page Chapter 27: Pericyclic Reactions 1. Which of the following statements about pericyclic reactions is true? A) Pericyclic reactions occur by way of ionic intermediates. B) Pe ricyclic reactions occur by way of radical intermediates. C) Pericyclic reactions involve multiple steps. D) Reactive intermediates are not formed in pericyclic reactions. 2. Which of the following statements about pericyclic reactions is true? A) In pericyclic reactions, bonds are broken and formed in...

Notes on the types of carbocations and their relative reactivity, their reactions including rearrangements and shifts, how readily they will migrate. Reactions of benzene including Fiedel Crafts alkylation and acylation, nitration, sulfonation. A look at further substitution and the impact of resonance, inductive effects and steric factors at controlling additional substitution. Ways to form substituted aromatics are then given including Diels Alder and carbonyl condensation. A few reactions of ...

The impact of how orbitals interact on reactivity is introduced before looking at orbital interaction in different reaction types and the effect on transition states. Rearrangement reactions of hydroboration, Baeyer-Villiger reaction, Beckmann rearrangement and Pinacol reaction are given. Effect of orbital interactions on conformation is explored through ethane and anomeric effect on 6-membered rings and the consequences of it. The Diels-Alder reaction is introduced and explored through its sele...

Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Substitution/Elimination: SN1,SN2,E1,E2 Alkenes: Anti and syn addition (different selectivity), oxidation (ozonolysis, epoxidation), cyclopropanation Functional group directed reactions: Simmons-Smith Alkynes: HX and X2 addition, hydration ...

Organic chemistry lab content. Summaries and post and pre labs that can be used to help with homework

Organic chemistry lab content. Summaries and post and pre labs that can be used to help with homework