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Chemistry class 12th Elevation of boiling point

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Elevation of the boiling point is a colligative property where the boiling point of a solvent increases when a non-volatile solute is added. This occurs because solute particles disrupt solvent molecules at the surface, requiring more energy (higher temperature) to convert the liquid into vapor. The increase in boiling point depends on the solute concentration and its van 't Hoff factor (degree of dissociation). This phenomenon is described by ΔTb = iKb m, where Kb is the boiling point elevati...

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Chemistry class 12th Depression of freezing point

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Depression of the freezing point is a colligative property in which the freezing point of a solvent decreases when a solute is added. This occurs because solute particles disrupt the formation of a solid crystalline structure, requiring a lower temperature for freezing. The extent of freezing point depression depends on the solute concentration and its van 't Hoff factor (number of particles it dissociates into). This principle is used in applications such as antifreeze in car engines, de-icing...

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Chemistry class 12th Osmosis and osmotic pressure

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Osmosis is the movement of water molecules through a semipermeable membrane from a region of lower solute concentration to higher concentration, aiming to equalize concentrations on both sides. This natural process is essential in biological systems, such as nutrient absorption in cells. Osmotic pressure is the pressure required to stop this water movement. It depends on solute concentration—the higher the concentration, the greater the osmotic pressure. This principle is used in medical treat...

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Chemistry class 12th Reverse osmosis and water purification

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Reverse osmosis (RO) is a water purification process that removes contaminants by using pressure to force water through a semipermeable membrane. This membrane blocks impurities such as bacteria, viruses, salts, and chemicals, allowing only pure water molecules to pass through. RO is widely used for drinking water purification, wastewater treatment, and desalination. It effectively removes heavy metals, chlorine, and dissolved solids, improving taste and safety. However, the process produces was...

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Chemistry class 12th Abnormal molar masses

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Abnormal molar masses occur when a substance’s experimentally determined molar mass differs from its theoretical value. This deviation is often caused by molecular association or dissociation in a solution. Association happens when molecules cluster together, increasing the observed molar mass, while dissociation occurs when compounds break into smaller particles, reducing the molar mass. Factors like intermolecular forces, ionization, and colligative properties influence these anomalies. Elec...

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Chemistry class 12th Raoult's law

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Raoult’s Law states that in an ideal solution, the partial vapor pressure of each volatile component is proportional to its mole fraction in the liquid phase and its pure vapor pressure. Mathematically, P_A = X_A * P_A⁰, where P_A is the partial pressure, X_A is the mole fraction, and P_A⁰ is the pure component’s vapor pressure. This law explains colligative properties like vapor pressure lowering, boiling point elevation, and freezing point depression. It is most accurate for ideal solu...

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Chemistry class 12th Raoult's law and henry law

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Raoult's Law states that the partial vapor pressure of a component in an ideal liquid mixture is proportional to its mole fraction and its pure vapor pressure. It explains how the presence of a solute lowers the vapor pressure of a solvent. Henry's Law states that the amount of gas dissolved in a liquid is directly proportional to its partial pressure above the liquid, given constant temperature. It explains gas solubility in liquids, such as oxygen in water. Both laws describe equilibri...

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Chemistry class 12th Concentration of solutions

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The concentration of a solution refers to the amount of solute dissolved in a given quantity of solvent or solution. It is commonly expressed in terms of molarity (moles of solute per liter of solution), molality (moles of solute per kilogram of solvent), mass percent, volume percent, or parts per million (ppm). A solution can be dilute (low solute concentration) or concentrated (high solute concentration). Temperature and pressure can affect concentration, especially for gases. Dilution involve...

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Chemistry class 12th Solubility explanation

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Solubility is the ability of a substance (solute) to dissolve in a solvent to form a homogeneous solution. It depends on factors like temperature, pressure, and the nature of both solute and solvent. For solids in liquids, solubility usually increases with temperature, while for gases, it decreases. Polar solutes dissolve in polar solvents (e.g., sugar in water), while non-polar solutes dissolve in non-polar solvents (e.g., oil in benzene). A solution becomes saturated when it holds the maximum ...

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Chemistry class 12th Solubility of solid in liquid

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Solubility of a solid in a liquid refers to the maximum amount of the solid that can dissolve in a given quantity of liquid at a specific temperature and pressure. It depends on factors such as temperature, nature of the solute and solvent, and presence of other substances. Generally, solubility increases with temperature for most solids, as higher temperatures provide more energy to break intermolecular bonds. The solubility is also influenced by polarity—polar solids dissolve better in polar...

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