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Chemistry class 12th Solubility of solid in liquid

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Solubility of a solid in a liquid refers to the maximum amount of the solid that can dissolve in a given quantity of liquid at a specific temperature and pressure. It depends on factors such as temperature, nature of the solute and solvent, and presence of other substances. Generally, solubility increases with temperature for most solids, as higher temperatures provide more energy to break intermolecular bonds. The solubility is also influenced by polarity—polar solids dissolve better in polar solvents (e.g., salt in water), while non-polar solids dissolve in non-polar solvents (e.g., wax in benzene). Saturation occurs when no more solute can dissolve.

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Solubility of Solid in a Liquid




Solubility of a solid in a liquid refers to the maximum amount of a solid that can dissolve in a given

amount of liquid solvent at a specific temperature and pressure, forming a homogeneous solution.



1. Definition

- It is expressed in g/100 mL, mol/L, or ppm.



2. Factors Affecting Solubility of a Solid in a Liquid

a. Nature of the Solute and Solvent

- Polar solutes dissolve in polar solvents (e.g., salt in water).

- Non-polar solutes dissolve in non-polar solvents (e.g., wax in benzene).



b. Temperature

- Generally, increasing temperature increases solubility of solids (e.g., sugar in hot water).

- Some exceptions exist, like calcium sulfate.



c. Stirring

- Increases the rate of dissolution but does not change solubility.



d. Particle Size

- Smaller particles dissolve faster due to increased surface area.



e. Pressure

- Unlike gases, pressure has little effect on solid solubility.
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