Nyls Study guides, Class notes & Summaries

These notes are on the topic of allenes and biphenyls based on the topic Stereochemistry. These notes explain how the stereochemistry of allenes and biphenyls are determined and there are practice questions to which the answers will be revealed in the document "Stereoselectivity in Synthesis"

These notes explain how to find the stereochemistry of allenes and biphenyls.

OCR CHEMISTRY A-LEVEL CARBONYLS SUMMARY.

Carbanions are looked at with examples and how to stabilise through inductive and resonance effects. Enolate formation reaction is introduced and a look at different bases and how complete deprotonation can be. The stabilisation of enolates develops the topic before the α-halogenation by base or acid catalysed reactions. More enolate reactions are given. Alkylate aldehydes formation through enamines. Aldol reaction through acid and base conditions in either equilibrating and non-equilibrating c...

An introduction to the reactions of malonates and 1,3 dicarbonyls including Claisen reaction, alkylation, ring synthesis. A look at enones, how to create them and their reactivity of 1,2 and 1,4 addition attack, the use of organometallics with enones. Then notes on the formation and addition of 1,5 dicarbonyls including Robinson's annelation. An introduction to the disconnection approach for retrosynthesis. 1,4 dicarbonyls and their reactions are introduced. 1,2 Dicarbonyls/Difunctionals reacti...

Class notes, including cases and professor comments. Professor Korngold NYLS Spring 2019

Tort Final Outline, Professor Sherwin

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