Chem 202
University Of California - Irvine
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Organic Chemistry 202 Synthetic Transformations, Top Exam Questions & answers, Rated A+
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Organic Chemistry 202 Synthetic Transformations, Top Exam Questions & answers, Rated A+
reduction of an aldehyde or ketone to an alcohol LiAlH4 or NaBH4
H3O H2O
lithium dialkyl cuprate reagent from an alkyl halide 4 Li metal
CuI
reduction of a nitro group to an amine Zn(Hg) HCl
reduction of a benzyl carbonyl H2/Pd or Zn(Hg) HCl
NAS
(normal condition must be 1 EWG ortho/para to leaving group) nucleophile (–OH, –OR, R3N)
benzyne reactions 1) NaOH
2) dilute acid
benzyne...
Exam (elaborations)
Organic Chemistry 202 Synthetic Transformations, Top Exam Questions & answers, Rated A+
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Organic Chemistry 202 Synthetic Transformations, Top Exam Questions & answers, Rated A+ reduction of an aldehyde or ketone to an alcohol LiAlH4 or NaBH4 H3O H2O lithium dialkyl cuprate reagent from an alkyl halide 4 Li metal CuI reduction of a nitro group to an amine Zn(Hg) HCl reduction of a benzyl carbonyl H2/Pd or Zn(Hg) HCl NAS (normal condition must be 1 EWG ortho/para to leaving group) nucleophile (–OH, –OR, R3N) benzyne reactions 1) NaOH 2) dilute acid benzyne...
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