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Summary of Organic Mechanisms - Chemistry 214.

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All summarised organic mechanisms needed to know for Chemistry 214. Includes some additional notes. Notes include: Nucleophilic addition to carbonyls, formation of organometallic reagents, Nucleophilic substitution at the carbonyl group, Nucleophilic substitution at C=O with the loss of oxygen and SN1 vs SN2 reactions.

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Institution
Stellenbosch University (SUN)
Course
Chemistry 214

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Mechanisms:
Nucleophilic addition to carbonyls:

Sodium Borohydride Nabha B Organometallic Reagents R M reacting them
aldehydes ketones imines

Li iii a
HI
phot
t
r s
joy Mein
µ p if a the
Br
Mg

c Cyanide Reagents CN

no p
Na
fffff fff p sgff.gg
it


all give alcohols
Organometallic reagents:


Created via oxidative insertion
anm.gg halogen exchange
problem
solutiggingto

1 Br EE MgBr
y Nat By
t.pe
in B
2 a Lehane a trio

Organometallic rxn's w aldehyde O

iii
Br
i
on i.it
Formaldehyde Grignard 1 alcohol
Aldehyde Grignard 2 alcohol

IE aIigia9a dcaio
yiiihici RM9Br 7H30 o
canalsodo mn win coz not a
insteadof
p o MgBr
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Institution
Stellenbosch University (SUN)
Course
Chemistry 214

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Uploaded on
January 26, 2025
Number of pages
3
Written in
2024/2025
Type
SUMMARY

Subjects

  • organic chemistry
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