TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Pagecv
1
,Chaptercv1cvStructurecvandcvBonding
Chaptercv2cvAcidscvandcvBases
Chaptercv3cvIntroductioncvtocvOrganiccvMoleculescvandcvFunctionalcvGroups
Chaptercv4cvAlkanes
Chaptercv5cvStereochemistry
Chaptercv6cvUnderstandingcvOrganiccvReactions
Chaptercv7cvAlkylcvHalidescvandcvNucleophiliccvSubstitution
Chaptercv8cvAlkylcvHalidescvandcvEliminationcvReactions
Chaptercv9cvAlcohols,cvEthers,cvandcvRelatedcvCompounds
Chaptercv10cvAlkenescvandcvAdditioncvReactions
Chaptercv11cvAlkynescvandcvSynthesis
Chaptercv12cvOxidationcvandcvReduction
SpectroscopycvAcvMasscvSpectrometry
SpectroscopycvBcvInfraredcvSpectroscopy
SpectroscopycvCcvNuclearcvMagneticcvResonancecvSpectroscopy
Chaptercv13cvRadicalcvReactions
Chaptercv14cvConjugation,cvResonance,cvandcvDienes
Chaptercv15cvBenzenecvandcvAromaticcvCompounds
Chaptercv16cvReactionscvofcvAromaticcvCompounds
Chaptercv17cvIntroductioncvtocvCarbonylcvChemistry:cvOrganometalliccvReagents;cv
OxidationcvandcvReduction
Chaptercv18cvAldehydescvandcvKetones—NucleophiliccvAddition
Chaptercv19cvCarboxyliccvAcidscvandcvNitriles
Chaptercv20cvCarboxyliccvAcidscvandcvTheircvDerivatives-
cvNucleophiliccvAcylcvSubstitution
Chaptercv21cvSubstitutioncvReactionscvofcvCarbonylcvCompoundscvatcvthecvα-Carbon
Chaptercv22cvCarbonylcvCondensationcvReactions
Chaptercv23cvAmines
Chaptercv24cvCarbon-CarboncvBond-FormingcvReactionscvincvOrganiccvSynthesis
Chaptercv25cvPericycliccvReactions
Chaptercv26cvCarbohydrates
Chaptercv27cvAminocvAcidscvandcvProteins
Chaptercv28cvSyntheticcvPolymers
Chaptercv29cvLipidscv(Availablecvonline)
Pagecv
2
, Chapter 1: Structure and Bonding
cv cv cv cv
1. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvcarboncvatom?cvA)c v 1s2,cv2s2,cv2p
5
B)c v 1s2,cv2s2,cv2p2 C)c v 1s2,cv2s2,cv2p6
2 2 4
D)c v 1s ,cv2s ,cv2p
2. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvfluorinecvatom?cvA)c v 1s2,cv2s2,cv2p
2
B)c v 1s2,cv2s2,cv2p3 C)c v 1s2,cv2s2,cv2p4
D)c v 1s2,cv2s2,cv2p5
3. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvmagnesiumcvcationcv(Mg2+)?cAv )
2 2 6
1s ,cv2s ,cv2p C) 1s ,cv2s ,cv2p ,cv3s2
2 2 6
B) 1s2,cv2s2,cv2p6,cv3s1 D) 1s2,cv2s2,cv2p6,cv3s2,cv3p2
4. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvchlorinecvanioncv(Cl—)?A
cv )
2 2 6
1s ,cv2s ,cv2p C) 1s ,cv2s ,cv2p6,cv3s2,cv3p5
2 2
B) 1s2,cv2s2,cv2p6,cv3s2,cv3p6 D) 1s2,cv2s2,cv2p6,cv3s2,cv3p4
5. Whichcvofcvthecvfollowingcvstatementscvaboutcvvalencecvelectronscviscvtrue?
A) Theycvarecvthecvmostcvtightlycvheldcvelectrons.
B) Theycvdocvnotcvparticipatecvincvchemicalcvreactions.
Pagecv
3
, Chaptercv1:cvStructurecvandcvBond
ing
C) Theycvarecvthecvoutermostcvelectrons.
D) Theycvrevealcvthecvperiodcvnumbercvofcvacvsecond-rowcvelement.
6. Whichcvofcvthecvfollowingcvstatementscvaboutcvbondingcviscvtrue?
A) Covalentcvbondscvresultcvfromcvthecvtransfercvofcvelectronscvfromcvonecvelementcvtocvanother
.
B) Ioniccvbondscvresultcvfromcvthecvtransfercvofcvelectronscvfromcvacvmetalcvtocvacvnon-metal.
C) Ioniccvbondscvresultcvfromcvthecvsharingcvofcvelectronscvbetweencvtwocvnon-metals.
D) Covalentcvbondscvresultcvfromcvthecvsharingcvofcvelectronscvbetweencvtwocvmetals.
7. Whichcvofcvthecvfollowingcvwouldcvyoucvexpectcvtocvhavecvioniccvbonds?
A) CO B)c v FBr C)c v NF3 D)c v NaCl
8. Whichcvofcvthecvfollowingcvmoleculescvhascvnonpolarcvcovalentcvbonds?
A) HCl B)c v N2 C)c v CHCl3 D)c v NO
9. Whichcvofcvthecvfollowingcvmoleculescvcontaincvbothcvcovalentcvandcvioniccvbonds?
A) I,cvII B)c v I,cvIV C)c v II,cvIII D)cvII,cvIV
10. Arrangecvthecvfollowingcvbondscvincvdecreasingcvordercvofcvioniccvcharacter,cvputtingcvth
ecvmostcivoniccvfirst.
A) Icv>cvIIcv>cvIIIcv>cvIV C) IVcv>cvIIIcv>cvIIcv>cvI
B) IVcv>cvIIcv>cvIcv>cvIII D) IVcv>cvIIcv>cvIIIcv>cvI
11. Whichcvofcvthecvfollowingcvstatementscvcorrectlycvdescribescvthecvtypicalcvnumbercvofcvbon
dscvforcvcarbon,cvnitrogen,cvandcvoxygencvincvmostcvneutralcvorganiccvmolecules?
A) Carboncvformscv4cvcovalentcvbonds,cvnitrogencvformscv2cvcovalentcvbondscvandcvoxygenc
vformsc3v cvcovalentcvbonds.
B) Carboncvformscv4cvcovalentcvbonds,cvnitrogencvformscv3cvcovalentcvbondscvandcvoxygenc
vformsc2v cvcovalentcvbonds.
Pagecv4
Smith / All Chapters 1 - 29 / Full Complete
Pagecv
1
,Chaptercv1cvStructurecvandcvBonding
Chaptercv2cvAcidscvandcvBases
Chaptercv3cvIntroductioncvtocvOrganiccvMoleculescvandcvFunctionalcvGroups
Chaptercv4cvAlkanes
Chaptercv5cvStereochemistry
Chaptercv6cvUnderstandingcvOrganiccvReactions
Chaptercv7cvAlkylcvHalidescvandcvNucleophiliccvSubstitution
Chaptercv8cvAlkylcvHalidescvandcvEliminationcvReactions
Chaptercv9cvAlcohols,cvEthers,cvandcvRelatedcvCompounds
Chaptercv10cvAlkenescvandcvAdditioncvReactions
Chaptercv11cvAlkynescvandcvSynthesis
Chaptercv12cvOxidationcvandcvReduction
SpectroscopycvAcvMasscvSpectrometry
SpectroscopycvBcvInfraredcvSpectroscopy
SpectroscopycvCcvNuclearcvMagneticcvResonancecvSpectroscopy
Chaptercv13cvRadicalcvReactions
Chaptercv14cvConjugation,cvResonance,cvandcvDienes
Chaptercv15cvBenzenecvandcvAromaticcvCompounds
Chaptercv16cvReactionscvofcvAromaticcvCompounds
Chaptercv17cvIntroductioncvtocvCarbonylcvChemistry:cvOrganometalliccvReagents;cv
OxidationcvandcvReduction
Chaptercv18cvAldehydescvandcvKetones—NucleophiliccvAddition
Chaptercv19cvCarboxyliccvAcidscvandcvNitriles
Chaptercv20cvCarboxyliccvAcidscvandcvTheircvDerivatives-
cvNucleophiliccvAcylcvSubstitution
Chaptercv21cvSubstitutioncvReactionscvofcvCarbonylcvCompoundscvatcvthecvα-Carbon
Chaptercv22cvCarbonylcvCondensationcvReactions
Chaptercv23cvAmines
Chaptercv24cvCarbon-CarboncvBond-FormingcvReactionscvincvOrganiccvSynthesis
Chaptercv25cvPericycliccvReactions
Chaptercv26cvCarbohydrates
Chaptercv27cvAminocvAcidscvandcvProteins
Chaptercv28cvSyntheticcvPolymers
Chaptercv29cvLipidscv(Availablecvonline)
Pagecv
2
, Chapter 1: Structure and Bonding
cv cv cv cv
1. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvcarboncvatom?cvA)c v 1s2,cv2s2,cv2p
5
B)c v 1s2,cv2s2,cv2p2 C)c v 1s2,cv2s2,cv2p6
2 2 4
D)c v 1s ,cv2s ,cv2p
2. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvfluorinecvatom?cvA)c v 1s2,cv2s2,cv2p
2
B)c v 1s2,cv2s2,cv2p3 C)c v 1s2,cv2s2,cv2p4
D)c v 1s2,cv2s2,cv2p5
3. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvmagnesiumcvcationcv(Mg2+)?cAv )
2 2 6
1s ,cv2s ,cv2p C) 1s ,cv2s ,cv2p ,cv3s2
2 2 6
B) 1s2,cv2s2,cv2p6,cv3s1 D) 1s2,cv2s2,cv2p6,cv3s2,cv3p2
4. Whatcviscvthecvground-
statecvelectroniccvconfigurationcvofcvacvchlorinecvanioncv(Cl—)?A
cv )
2 2 6
1s ,cv2s ,cv2p C) 1s ,cv2s ,cv2p6,cv3s2,cv3p5
2 2
B) 1s2,cv2s2,cv2p6,cv3s2,cv3p6 D) 1s2,cv2s2,cv2p6,cv3s2,cv3p4
5. Whichcvofcvthecvfollowingcvstatementscvaboutcvvalencecvelectronscviscvtrue?
A) Theycvarecvthecvmostcvtightlycvheldcvelectrons.
B) Theycvdocvnotcvparticipatecvincvchemicalcvreactions.
Pagecv
3
, Chaptercv1:cvStructurecvandcvBond
ing
C) Theycvarecvthecvoutermostcvelectrons.
D) Theycvrevealcvthecvperiodcvnumbercvofcvacvsecond-rowcvelement.
6. Whichcvofcvthecvfollowingcvstatementscvaboutcvbondingcviscvtrue?
A) Covalentcvbondscvresultcvfromcvthecvtransfercvofcvelectronscvfromcvonecvelementcvtocvanother
.
B) Ioniccvbondscvresultcvfromcvthecvtransfercvofcvelectronscvfromcvacvmetalcvtocvacvnon-metal.
C) Ioniccvbondscvresultcvfromcvthecvsharingcvofcvelectronscvbetweencvtwocvnon-metals.
D) Covalentcvbondscvresultcvfromcvthecvsharingcvofcvelectronscvbetweencvtwocvmetals.
7. Whichcvofcvthecvfollowingcvwouldcvyoucvexpectcvtocvhavecvioniccvbonds?
A) CO B)c v FBr C)c v NF3 D)c v NaCl
8. Whichcvofcvthecvfollowingcvmoleculescvhascvnonpolarcvcovalentcvbonds?
A) HCl B)c v N2 C)c v CHCl3 D)c v NO
9. Whichcvofcvthecvfollowingcvmoleculescvcontaincvbothcvcovalentcvandcvioniccvbonds?
A) I,cvII B)c v I,cvIV C)c v II,cvIII D)cvII,cvIV
10. Arrangecvthecvfollowingcvbondscvincvdecreasingcvordercvofcvioniccvcharacter,cvputtingcvth
ecvmostcivoniccvfirst.
A) Icv>cvIIcv>cvIIIcv>cvIV C) IVcv>cvIIIcv>cvIIcv>cvI
B) IVcv>cvIIcv>cvIcv>cvIII D) IVcv>cvIIcv>cvIIIcv>cvI
11. Whichcvofcvthecvfollowingcvstatementscvcorrectlycvdescribescvthecvtypicalcvnumbercvofcvbon
dscvforcvcarbon,cvnitrogen,cvandcvoxygencvincvmostcvneutralcvorganiccvmolecules?
A) Carboncvformscv4cvcovalentcvbonds,cvnitrogencvformscv2cvcovalentcvbondscvandcvoxygenc
vformsc3v cvcovalentcvbonds.
B) Carboncvformscv4cvcovalentcvbonds,cvnitrogencvformscv3cvcovalentcvbondscvandcvoxygenc
vformsc2v cvcovalentcvbonds.
Pagecv4