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Quantitative Chemical Analysis Exam Questions Answered Correctly (Graded A+)

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Quantitative Chemical Analysis Exam Questions Answered Correctly (Graded A+) Branch of analytical chemistry that deals with determination of an unknown chemical species in a sample - Answers Qualitative analysis Which branch of analytical chemistry deals with the determination of the amount of the unknown chemical species in a sample - Answers Quantitative analysis What are the SI units? - Answers Length- Meter Mass- Kilogram Time- Second Temperature- Kelvin Amount of Substance- Mole Electric Current- Ampere Luminous intensity- Candela Plane angle- Radian Solid angle- Steradian Frequency- Hz Force- N In physico-chemical experiments (in which temperature as well as the volume of the system may change), the most appropriate way of expressing concentration is through this unit: - Answers Molality Avogadro's number represents the number of particles present in this amount of a substance - Answers 1 mole- expressed 6.022×1023 mol-1 The average of this type of error is zero - Answers Random error This type of error cannot be eliminated - Answers Random error A laboratory protocol requires a reaction to be carried out using methanol as the solvent. A careless technician performed this reaction using hexane as the solvent. In this instance, this type of error has occurred - Answers Gross error Statistical methods are applied to improve data containing only this type of error - Answers Random Faulty calibration of an analytical instrument will cause this type of error: - Answers Systematic error The variance of a sample is represented by this symbol - Answers s^2 A symmetrical bell-shaped curve represents this type of distribution: - Answers Gaussian The maximum of the Gaussian distribution curve corresponds to this parameter of the sample presented on the x-axis - Answers Mean In Gaussian distribution, 95% of the data points are located within this span around the true value - Answers ±2sigma In order for experimental data to be meaningful, it must be accompanied by this information - Answers Error involved In replicate measurements, the closeness of the mean to the true value is represented by this term - Answers Accuracy Systematic error affects this in experimental measurements - Answers Accuracy The true value of a population is estimated by this parameter - Answers confidence interval This parameter is not a measure of precision: - Answers Mean A clinical technician has determined the concentration of thiol in blood of a rheumatoid arthritis patient in replicate measurements with the following results (in mM): 2.81, 4.06, 3.62, 3.56, 3.27, 3.46, and 3.76. The technician will have this many degrees of freedom in determining the variance of these measurements - Answers Six ( n-1) The confidence interval shows a range of values that includes this parameter of the population with an ascribed degree of confidence - Answers Mean In order to compare two means, one should perform this type of significance test: - Answers t-Test In order to compare two variances, one should perform this type of significance test: - Answers F-Test In a significance test, if the calculated value of the test parameter exceeds its critical value, then one should do this with the null hypothesis - Answers Reject When a null hypothesis is accepted, it signifies that the observed difference between the compared values is due to this - Answers Random variation Which term describes the minimum detectable concentration of an analytical method: - Answers Detection limit An analysis involves several steps and operations which depend on: - Answers 1- Problem 2- Expertise 3- Apparatus General steps in Chemical Analysis - Answers 1- Formulate question 2- Select method 3- Sampling 4- Sample preparation 5- Analysis 6- Interpretation 7- Conclusion Yotta - Answers 10^24 Zetta - Answers 10^21 Exa - Answers 10^18 Peta - Answers 10^15 Tera - Answers 10^12 Giga - Answers 10^9 Mega - Answers 10^6 Kilo - Answers 10^3 Hecto - Answers 10^2 Deca - Answers 10^1 Deci - Answers 10^-1 Centi - Answers 10^-2 Milli - Answers 10^-3 Micro - Answers 10^-6 Nano - Answers 10^-9 Pic - Answers 10^-12 Femto - Answers 10^-15 Atto - Answers 10^-18 Zepto - Answers 10^-21 Yocto - Answers 10^-24 Atomic mass units - Answers amu (daltons) Molality - Answers the number of moles of a solute in 1 kg of solvent Molarity - Answers the number of moles of a chemical specie X that is contained in 1 L of the solution. 1 M = 1mol/L Analytical molarity (formal concentration): - Answers the total number of moles of a solute in 1 L of the solution, regardless of its chemical states. Equilibrium molarity - Answers molar concentration of a particular species in a solution at equilibrium. Percent concentration - Answers -(w/w) = (weight solute)/(weight solution)X 100% commercial aqueous reagents -(v/v) = (volume solute)/(volume solution)X 100% liquid dilution (w/v) = (weight solute, g)/(volume solution, mL)X 100% Dilute aqueous solution from Solid Parts per million - Answers cppm = (mass of solute) / (mass of solution) =10^6 Part per billion - Answers cppb = (mass of solute) / (mass of solution) =10^9 General titration equation - Answers Mcon x V con = M dil x Vdil Lab notebook is needed for: - Answers 1- What has been done 2- Observed 3- To be understood by others 4- Legal records Lab notebooks need: - Answers Date, page number, purpose, methods, results, analysis and conclusion Balances - Answers 1-Electronic (single pan) 2- Mechanical Temperature effect - Answers T object T environment positive error T object T Environment negative error Normally used glassware - Answers Borosilicate (Pyrex, Kimax) because thermally stable Burets - Answers 1- Pinchcock- Flow when deformed 2- Stopcock- rotate Meniscus - Answers Curved surface of liquid at its interface with atmosphere Parallax - Answers Apparent displacement of a liquid level or of a pointer as an observer changes position Relative tolerance of Class A burets - Answers 0.1-0.2% Weighing bottles - Answers Dry samples Glass Plastic Volumetric flasks - Answers Fixed volume Pipets - Answers 1- Volumetric pipet- deliever fixed amount 2- Mohr- straight bore 3- Serological- straight bore

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Quantitative Chemical Analysis Exam Questions Answered Correctly (Graded A+)

Branch of analytical chemistry that deals with determination of an unknown chemical species in a
sample - Answers Qualitative analysis

Which branch of analytical chemistry deals with the determination of the amount of the unknown
chemical species in a sample - Answers Quantitative analysis

What are the SI units? - Answers Length- Meter

Mass- Kilogram

Time- Second

Temperature- Kelvin

Amount of Substance- Mole

Electric Current- Ampere

Luminous intensity- Candela

Plane angle- Radian

Solid angle- Steradian

Frequency- Hz

Force- N

In physico-chemical experiments (in which temperature as well as the volume of the

system may change), the most appropriate way of expressing concentration is through this unit: -
Answers Molality

Avogadro's number represents the number of particles present in this amount of a

substance - Answers 1 mole- expressed 6.022×1023 mol-1

The average of this type of error is zero - Answers Random error

This type of error cannot be eliminated - Answers Random error

A laboratory protocol requires a reaction to be carried out using methanol as the solvent.

A careless technician performed this reaction using hexane as the solvent. In this instance, this type of

error has occurred - Answers Gross error

Statistical methods are applied to improve data containing only this type of error - Answers Random

,Faulty calibration of an analytical instrument will cause this type of error: - Answers Systematic error

The variance of a sample is represented by this symbol - Answers s^2

A symmetrical bell-shaped curve represents this type of distribution: - Answers Gaussian

The maximum of the Gaussian distribution curve corresponds to this parameter of the

sample presented on the x-axis - Answers Mean

In Gaussian distribution, 95% of the data points are located within this span around the

true value - Answers ±2sigma

In order for experimental data to be meaningful, it must be accompanied by this

information - Answers Error involved

In replicate measurements, the closeness of the mean to the true value is represented by

this term - Answers Accuracy

Systematic error affects this in experimental measurements - Answers Accuracy

The true value of a population is estimated by this parameter - Answers confidence interval

This parameter is not a measure of precision: - Answers Mean

A clinical technician has determined the concentration of thiol in blood of a rheumatoid

arthritis patient in replicate measurements with the following results (in mM): 2.81, 4.06, 3.62, 3.56,

3.27, 3.46, and 3.76. The technician will have this many degrees of freedom in determining the

variance of these measurements - Answers Six ( n-1)

The confidence interval shows a range of values that includes this parameter of the

population with an ascribed degree of confidence - Answers Mean

In order to compare two means, one should perform this type of significance test: - Answers t-Test

In order to compare two variances, one should perform this type of significance test: - Answers F-Test

In a significance test, if the calculated value of the test parameter exceeds its critical

value, then one should do this with the null hypothesis - Answers Reject

When a null hypothesis is accepted, it signifies that the observed difference between the

, compared values is due to this - Answers Random variation

Which term describes the minimum detectable concentration of an

analytical method: - Answers Detection limit

An analysis involves several steps and operations which depend on: - Answers 1- Problem

2- Expertise

3- Apparatus

General steps in Chemical Analysis - Answers 1- Formulate question

2- Select method

3- Sampling

4- Sample preparation

5- Analysis

6- Interpretation

7- Conclusion

Yotta - Answers 10^24

Zetta - Answers 10^21

Exa - Answers 10^18

Peta - Answers 10^15

Tera - Answers 10^12

Giga - Answers 10^9

Mega - Answers 10^6

Kilo - Answers 10^3

Hecto - Answers 10^2

Deca - Answers 10^1

Deci - Answers 10^-1

Centi - Answers 10^-2

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