TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Page,1
,Chapter,1,Structure,and,Bonding
Chapter,2,Acids,and,Bases
Chapter,3,Introduction,to,Organic,Molecules,and,Functional,Groups
Chapter,4,Alkanes
Chapter,5,Stereochemistry
Chapter,6,Understanding,Organic,Reactions
Chapter,7,Alkyl,Halides,and,Nucleophilic,Substitution
Chapter,8,Alkyl,Halides,and,Elimination,Reactions
Chapter,9,Alcohols,,Ethers,,and,Related,Compounds
Chapter,10,Alkenes,and,Addition,Reactions
Chapter,11,Alkynes,and,Synthesis
Chapter,12,Oxidation,and,Reduction
Spectroscopy,A,Mass,Spectrometry
Spectroscopy,B,Infrared,Spectroscopy
Spectroscopy,C,Nuclear,Magnetic,Resonance,Spectroscopy
Chapter,13,Radical,Reactions
Chapter,14,Conjugation,,Resonance,,and,Dienes
Chapter,15,Benzene,and,Aromatic,Compounds
Chapter,16,Reactions,of,Aromatic,Compounds
Chapter,17,Introduction,to,Carbonyl,Chemistry:,Organometallic,Reagents;,Oxida
tion,and,Reduction
Chapter,18,Aldehydes,and,Ketones—Nucleophilic,Addition
Chapter,19,Carboxylic,Acids,and,Nitriles
Chapter,20,Carboxylic,Acids,and,Their,Derivatives-
,Nucleophilic,Acyl,Substitution
Chapter,21,Substitution,Reactions,of,Carbonyl,Compounds,at,the,α-Carbon
Chapter,22,Carbonyl,Condensation,Reactions
Chapter,23,Amines
Chapter,24,Carbon-Carbon,Bond-Forming,Reactions,in,Organic,Synthesis
Chapter,25,Pericyclic,Reactions
Chapter,26,Carbohydrates
Chapter,27,Amino,Acids,and,Proteins
Chapter,28,Synthetic,Polymers
Chapter,29,Lipids,(Available,online)
Page,2
, Chapter 1: Structure and Bonding
, , , ,
1. What,is,the,ground-
state,electronic,configuration,of,a,carbon,atom?,A), 1s2,,2s2,,2p5
B), 1s2,,2s2,,2p2 C), 1s2,,2s2,,2p6 D), 1s2,,2s2,,2p4
2. What,is,the,ground-
state,electronic,configuration,of,a,fluorine,atom?,A), 1s2,,2s2,,2p2
B), 1s2,,2s2,,2p3 C), 1s2,,2s2,,2p4 D), 1s2,,2s2,,2p5
3. What,is,the,ground-state,electronic,configuration,of,a,magnesium,cation,(Mg2+)?,A)
1s2,,2s2,,2p6 C) 1s2,,2s2,,2p6,,3s2
B) 1s2,,2s2,,2p6,,3s1 D) 1s2,,2s2,,2p6,,3s2,,3p2
4. What,is,the,ground-state,electronic,configuration,of,a,chlorine,anion,(Cl—)?,A)
1s2,,2s2,,2p6 C) 1s2,,2s2,,2p6,,3s2,,3p5
B) 1s2,,2s2,,2p6,,3s2,,3p6 D) 1s2,,2s2,,2p6,,3s2,,3p4
5. Which,of,the,following,statements,about,valence,electrons,is,true?
A) They,are,the,most,tightly,held,electrons.
B) They,do,not,participate,in,chemical,reactions.
Page,3
, Chapter,1:,Structure,and,Bonding
C) They,are,the,outermost,electrons.
D) They,reveal,the,period,number,of,a,second-row,element.
6. Which,of,the,following,statements,about,bonding,is,true?
A) Covalent,bonds,result,from,the,transfer,of,electrons,from,one,element,to,another.
B) Ionic,bonds,result,from,the,transfer,of,electrons,from,a,metal,to,a,non-metal.
C) Ionic,bonds,result,from,the,sharing,of,electrons,between,two,non-metals.
D) Covalent,bonds,result,from,the,sharing,of,electrons,between,two,metals.
7. Which,of,the,following,would,you,expect,to,have,ionic,bonds?
A) CO B), FBr C), NF3 D), NaCl
8. Which,of,the,following,molecules,has,nonpolar,covalent,bonds?
A) HCl B), N2 C), CHCl3 D), NO
9. Which,of,the,following,molecules,contain,both,covalent,and,ionic,bonds?
A) I,,II B), I,,IV C), II,,III D),II,,IV
10. Arrange,the,following,bonds,in,decreasing,order,of,ionic,character,,putting,the,most,ioni
c,first.
A) I,>,II,>,III,>,IV C) IV,>,III,>,II,>,I
B) IV,>,II,>,I,>,III D) IV,>,II,>,III,>,I
11. Which,of,the,following,statements,correctly,describes,the,typical,number,of,bonds,for,car
bon,,nitrogen,,and,oxygen,in,most,neutral,organic,molecules?
A) Carbon,forms,4,covalent,bonds,,nitrogen,forms,2,covalent,bonds,and,oxygen,forms,3,co
valent,bonds.
B) Carbon,forms,4,covalent,bonds,,nitrogen,forms,3,covalent,bonds,and,oxygen,forms,2,co
valent,bonds.
Page,4
Smith / All Chapters 1 - 29 / Full Complete
Page,1
,Chapter,1,Structure,and,Bonding
Chapter,2,Acids,and,Bases
Chapter,3,Introduction,to,Organic,Molecules,and,Functional,Groups
Chapter,4,Alkanes
Chapter,5,Stereochemistry
Chapter,6,Understanding,Organic,Reactions
Chapter,7,Alkyl,Halides,and,Nucleophilic,Substitution
Chapter,8,Alkyl,Halides,and,Elimination,Reactions
Chapter,9,Alcohols,,Ethers,,and,Related,Compounds
Chapter,10,Alkenes,and,Addition,Reactions
Chapter,11,Alkynes,and,Synthesis
Chapter,12,Oxidation,and,Reduction
Spectroscopy,A,Mass,Spectrometry
Spectroscopy,B,Infrared,Spectroscopy
Spectroscopy,C,Nuclear,Magnetic,Resonance,Spectroscopy
Chapter,13,Radical,Reactions
Chapter,14,Conjugation,,Resonance,,and,Dienes
Chapter,15,Benzene,and,Aromatic,Compounds
Chapter,16,Reactions,of,Aromatic,Compounds
Chapter,17,Introduction,to,Carbonyl,Chemistry:,Organometallic,Reagents;,Oxida
tion,and,Reduction
Chapter,18,Aldehydes,and,Ketones—Nucleophilic,Addition
Chapter,19,Carboxylic,Acids,and,Nitriles
Chapter,20,Carboxylic,Acids,and,Their,Derivatives-
,Nucleophilic,Acyl,Substitution
Chapter,21,Substitution,Reactions,of,Carbonyl,Compounds,at,the,α-Carbon
Chapter,22,Carbonyl,Condensation,Reactions
Chapter,23,Amines
Chapter,24,Carbon-Carbon,Bond-Forming,Reactions,in,Organic,Synthesis
Chapter,25,Pericyclic,Reactions
Chapter,26,Carbohydrates
Chapter,27,Amino,Acids,and,Proteins
Chapter,28,Synthetic,Polymers
Chapter,29,Lipids,(Available,online)
Page,2
, Chapter 1: Structure and Bonding
, , , ,
1. What,is,the,ground-
state,electronic,configuration,of,a,carbon,atom?,A), 1s2,,2s2,,2p5
B), 1s2,,2s2,,2p2 C), 1s2,,2s2,,2p6 D), 1s2,,2s2,,2p4
2. What,is,the,ground-
state,electronic,configuration,of,a,fluorine,atom?,A), 1s2,,2s2,,2p2
B), 1s2,,2s2,,2p3 C), 1s2,,2s2,,2p4 D), 1s2,,2s2,,2p5
3. What,is,the,ground-state,electronic,configuration,of,a,magnesium,cation,(Mg2+)?,A)
1s2,,2s2,,2p6 C) 1s2,,2s2,,2p6,,3s2
B) 1s2,,2s2,,2p6,,3s1 D) 1s2,,2s2,,2p6,,3s2,,3p2
4. What,is,the,ground-state,electronic,configuration,of,a,chlorine,anion,(Cl—)?,A)
1s2,,2s2,,2p6 C) 1s2,,2s2,,2p6,,3s2,,3p5
B) 1s2,,2s2,,2p6,,3s2,,3p6 D) 1s2,,2s2,,2p6,,3s2,,3p4
5. Which,of,the,following,statements,about,valence,electrons,is,true?
A) They,are,the,most,tightly,held,electrons.
B) They,do,not,participate,in,chemical,reactions.
Page,3
, Chapter,1:,Structure,and,Bonding
C) They,are,the,outermost,electrons.
D) They,reveal,the,period,number,of,a,second-row,element.
6. Which,of,the,following,statements,about,bonding,is,true?
A) Covalent,bonds,result,from,the,transfer,of,electrons,from,one,element,to,another.
B) Ionic,bonds,result,from,the,transfer,of,electrons,from,a,metal,to,a,non-metal.
C) Ionic,bonds,result,from,the,sharing,of,electrons,between,two,non-metals.
D) Covalent,bonds,result,from,the,sharing,of,electrons,between,two,metals.
7. Which,of,the,following,would,you,expect,to,have,ionic,bonds?
A) CO B), FBr C), NF3 D), NaCl
8. Which,of,the,following,molecules,has,nonpolar,covalent,bonds?
A) HCl B), N2 C), CHCl3 D), NO
9. Which,of,the,following,molecules,contain,both,covalent,and,ionic,bonds?
A) I,,II B), I,,IV C), II,,III D),II,,IV
10. Arrange,the,following,bonds,in,decreasing,order,of,ionic,character,,putting,the,most,ioni
c,first.
A) I,>,II,>,III,>,IV C) IV,>,III,>,II,>,I
B) IV,>,II,>,I,>,III D) IV,>,II,>,III,>,I
11. Which,of,the,following,statements,correctly,describes,the,typical,number,of,bonds,for,car
bon,,nitrogen,,and,oxygen,in,most,neutral,organic,molecules?
A) Carbon,forms,4,covalent,bonds,,nitrogen,forms,2,covalent,bonds,and,oxygen,forms,3,co
valent,bonds.
B) Carbon,forms,4,covalent,bonds,,nitrogen,forms,3,covalent,bonds,and,oxygen,forms,2,co
valent,bonds.
Page,4