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UNIT 13B APPLIED SCIENCE UP TO DISTINCTION

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Here are the key points I would highlight in the assignment: P4/P6 - Practical Work Measuring cell potentials for various half-cell combinations (Zn/Cu, Zn/Pb, Pb/Cu) Calculating standard cell potentials and comparing to measured values Titrations: Fe2+/MnO4-, Na2S2O3/KIO3 standardization, I2/Cu2+ determination Observations and calculations for titration volumes and concentrations Oxidation of alcohols (ethanol, ethanoic acid) with acidified K2Cr2O7 Health & Safety Proper PPE (lab coats, goggles, gloves) Handling hazardous chemicals (acids, oxidizers, toxins, etc.) Working in fume hoods for noxious fumes Safe chemical disposal P5 - Identifying and Balancing Redox Equations Using oxidation numbers to identify oxidation and reduction processes Balancing redox equations by balancing electron transfer Examples of redox reactions vs non-redox reactions M4 - Calculating Cell Potentials Calculating standard cell potentials from reduction potentials Comparing calculated vs measured cell potentials Accounting for differences (concentration effects, junction potentials, etc.) M5 - Redox Titrations Relating oxidation numbers to electron transfer in titrations Using balanced redox equations to determine titrant:analyte stoichiometry Calculating analyte concentration from titrant concentration and volume D2 - Industrial Applications Iodine/thiosulfate titrations in various industries Chemical Oxygen Demand (COD) analysis applications Advantages and limitations of redox titration methods Alternative analytical procedures involving redox reactions The key points cover the main practical work, calculations, theory of redox reactions and titrations, as well as the industrial applications and other related analytical techniques.

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P5- Determine which equations are examples of redox reactions and
which are not. Explain how you have balanced the redox equations in
terms of No. of electrons involved.
1. NaCl (aq) + AgNO3 (aq) → AgCl (s) + NaNO3 (aq)
2. H2 (aq) + F2 (aq) → 2HF (aq)
3. PCl5 (aq) + 4H2O (l) → H3PO4 (aq) + 5HCl (aq)
4. Zn (s) + 2HCl (aq) → ZnCl2 (aq) + 2H2 (g)
5. Ca(OH)2 (aq) + 2HCl (aq) → CaCl2 (aq) + 2H2O (l)
6. 3CuS (s) + 8HNO3 (aq) → 3CuSO4 (aq) + 8NO (g) + 4H2O (l)
7. KMnO4 (aq) + 6H2SO4 (aq) → 2K2SO4 (aq) + 4MnSO4 (aq) + 6H2O (l) + 5O2
(g)



OIL RIG:

Oxidation is loss.

Reduction is gain

If the oxidation number changes, it's a redox reaction



1. NaCl (aq) + AgNO3 (aq) → AgCl (s) + NaNO3 (aq)

This equation represents a double displacement reaction, where the ions
exchange partners. No elements undergo a change in oxidation state, so it is not
a redox reaction.



2. H2 (g) + F2 (g) → 2HF (g)

In this equation, hydrogen (H2) is oxidized by losing electrons to fluorine (F2),
which is reduced by gaining electrons. Therefore, it is a redox reaction. The
balanced equation involves the transfer of two electrons.



3. PCl5 (aq) + 4H2O (l) → H3PO4 (aq) + 5HCl (aq)

This reaction involves the transfer of electrons from the oxygen atoms in water
to the phosphorus atom, resulting in the oxidation of oxygen and the reduction
of phosphorus. Therefore, it is a redox reaction. The balanced equation involves
the transfer of 20 electrons.

, 4. Zn (s) + 2HCl (aq) → ZnCl2 (aq) + H2 (g)

In this reaction, zinc (Zn) is oxidized by losing electrons to hydrogen ions (H+),
which are reduced by gaining electrons to form hydrogen gas (H2). Therefore, it
is a redox reaction. The balanced equation involves the transfer of two electrons.



5. Ca(OH)2 (aq) + 2HCl (aq) → CaCl2 (aq) + 2H2O (l)

This is an acid-base neutralization reaction involving the transfer of protons (H+)
from hydrochloric acid to the hydroxide ions (OH-) in calcium hydroxide. No
elements undergo a change in oxidation state, so it is not a redox reaction.



6. 3CuS (s) + 8HNO3 (aq) → 3Cu(NO3)2 (aq) + 2NO (g) + 4H2O (l) + 3S (s)

In this reaction, copper (Cu) in copper sulfide (CuS) is oxidized by nitric acid
(HNO3), and the nitrogen in HNO3 is reduced to form nitric oxide (NO) gas.
Therefore, it is a redox reaction. The balanced equation involves the transfer of
24 electrons.



7. KMnO4 (aq) + 8H2SO4 (aq) → K2SO4 (aq) + 2MnSO4 (aq) + 5O2 (g) +
8H2O (l)

In this reaction, the manganese in potassium permanganate (KMnO4) is reduced
from a +7 oxidation state to a +2 oxidation state, while the sulfuric acid (H2SO4)
is oxidized. Therefore, it is a redox reaction. The balanced equation involves the
transfer of 10 electrons.



P6- Descriptions of the observations from a test tube reaction of an
organic compound being oxidized with acidified potassium
permanganate:
OXIDATION OF
ALCOHOL
Ethanol Ethanoic acid

CH3CH2OH CH2 COOH

Start End

orange orange

orange light green

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