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UNE Chem 1011 EXAM QUESTIONS WITH COMPLETE SOLUTIONS

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UNE Chem 1011 EXAM QUESTIONS WITH COMPLETE SOLUTIONS

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UNE Chem 1011 EXAM QUESTIONS WITH
COMPLETE SOLUTIONS

Intermolecular forces (IMFs) | |




the forces of attraction between molecules of covalent compounds
| | | | | | | | |



(weak)




Intramolecular forces |




forces within molecules. Forces caused by the attraction and repulsion
| | | | | | | | | |



of charged particles (strong)
| | |




Dispersion forces |




present in all molecules
| | |




attractions between molecules caused by the electron motion on one
| | | | | | | | | |



molecule affecting the electron motion on the other through electrical
| | | | | | | | | |



forces; these are the weakest interactions between molecules
| | | | | | |




polarizability

,the ability to be polarized. a larger molecule or a longer straight
| | | | | | | | | | | |



molecule has MORE polarizability
| | |




Dipole
a polar molecule that has two poles, or regions, with opposite charges
| | | | | | | | | | |




hydrogen bond forces | |




intermolecular force between molecules -- attraction between two
| | | | | | | |



water molecules.
|




Instantaneous dipole |




temporary dipole that occurs for a brief moment in time when the
| | | | | | | | | | | |



electrons of an atom or molecule are distributed asymmetrically
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(through dispersion forces)
| |




Induced dipole |




a dipole temporarily created in an otherwise nonpolar molecule,
| | | | | | | | |



induced by a neighboring charge
| | | |

,Relation between atomic/molecular size and melting & boiling points
| | | | | | | |




melting and boiling points increase as atomic/molecule size increases
| | | | | | | |




Between polar and nonpolar molecules of the same mass, which tends
| | | | | | | | | | |



to have the higher boiling point?
| | | | |




Polar molecules have dipole-dipole attractions, which are stronger than
| | | | | | | | |



nonpolar dispersion factors. So, polar molecules have higher boiling
| | | | | | | | |



points.




Hydrogen bonded to __, __, or __ atoms creates a highly polar molecule
| | | | | | | | | | | |




fluorine, oxygen, nitrogen | |




(OH, HF, NH groups are signifiers of high polarity and therefore high
| | | | | | | | | | | |



boiling point) |




these bonds are so strong that it leaves a "naked nucleus" which
| | | | | | | | | | | |



increases the IMF force between molecules
| | | | |

, Viscosity
a measure of a liquid's resistance to flow.
| | | | | | |




cold = more viscous
| | |




Cohesive forces |




the result of the intermolecular forces that attract identical molecules
| | | | | | | | | |



(attraction between water molecules for example)
| | | | |




adhesive forces |




result of intermolecular forces between two different molecules (like
| | | | | | | | |



the liquid molecules and their container)
| | | | |




Surface tension |




caused by uneven (cohesive) forces at the surface of a liquid.
| | | | | | | | | |




increased surface tension causes the surface of a liquid to act like a
| | | | | | | | | | | | |



membrane

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