Transition metals are colored+ paramagnetic except Sc/Ti" + / In
·
Geometric isomers can be square .
that are colorless because
·
e-fill "S" Orbital first EXCEPT Cr/Cu planar or octanedral
3 relativela
atomic size +
empty or filled d level
of
·
Optical somers are octahedral
·
Y IE/EN Ligandi can be ...
electrosle potential texcEpicu
·
Neutral (0) H20/NH3/co/ No
IE/EN 1
)
&
·
anionic (-)F-/c-1Br-11-IOH- /CN-
~
·
nuclear charge --
Density↑
·
anionic drop-ide and add - o
·
Reactivity ↓
·
Alsomers :
same formula , diff properties
A period 6 contains MOST DENSE elments
1) Constitution /I Structural : same form , connected diff
·
HEAVIER metals have HIGH EN + form ↳ coordination : exchange of complex exchange of
or
wi counterion ligands
more COVALENT BONDS
4)
linkage : diff composition of the ligand (NOCIONO
2) Stereoisomers : diff spatial arrangements
have multiple of stateswl highest
·
can
↳ Geometric/CI) TRANS : on the
can be
groups
.
being group # always has
same or
opposite side of antral metal
multiple ligands -
ADJACENT/TRANS
I
↑ CIS are are ACROSS
o State 4 Covalent Acidic ENT Oxide acidity ↑
↳ optical/enantiomers : identical
oX state + lonk Basic ENU Oxide acslty ↓ except for rotation direction
Lanthanides "Inner transition Actinides * CIS) NOT SUPERIMPOSED/OPTICAL
euments" (5d)
Period 6 (4d) Period 7 *TRANS / SUPERIMPOSED / NOT OPTICAL
·
"rare earth elements" common + 3 ox State
·
·
Except
Bonding in Complex lons
radioactive
most In ground all are
·
·
state
Ce/6d/Lu 1) Valence bond (VB) theory : when form
silver +
high . Melting
·
a complex son filled ligand orbital
[ charge of charge of
J
,
=
total charge
Coordination (mpds metal overlaps w/ empty metal orbital to
complex of ligands
donate/accept - +
form coord covalent bond
[its(b) (13] 3
look at OX
Astrong ligands/LARDER A
4
* weak
state first ligands are LB , metal lons are LA
ligands/SMALLER A then ligand & metal
complex llgand counter hybridization determines geometry
Central
metal con lon
strength
2) Crystal field explains how color
theory : t
CATIONIC
complex/ ANIONIC counters
higher
·
I is magnetism arises from splitting dorbitals
complexion
complex) [eg
↓
ANIONIC CATIDNIC counters ItalHed SpyO
·
+ =
D ( + 29)
metal adds
-
anion , zg
be absorbed to excite
Accordination # : # of ligands binded -
ate to end lower level e-
Coord# snape writing coord cmpds Naming Coord (mpds
·
color of a
ligand depends on
ox state of metal
n
2 linear 1) cation before anyon 1) cation before anion
4
splitting
metal ox
square planar 2) balance charges ↑I
2) ligands in alphabetical State energy A
T
tetrahedral
3) neutral ligands before
3) anionis
ligands drop-ide and add o
u
S
-
octahedral order
anion in alphabetical
ligand 4) numerical prefix specifies # of llgands higher energies
4) counter brackets
# of lone pairs lons outside
a
are absorbed from
donating to metal
is
bis(2) , tris (3) , tetrakis (4) SHORTER Wavel
F (fluoridel CN-(cyanidel of Inydroxide)
-
5)
~ · ·
MONO dentate Roman numeral indicates metal ox St.
·
H20(water) ·
ICN-(thocyanate)
·
NO z
-
Intrite)
NHz lammonia) cl-chlorides
6) If metal adds-ate
·
complexion
-
-
is anionic
,
en Jethylenediamine (
·
Bidentate
(20y (oxalate) -
>
1) All counter cons are listed as if there's only one
diethylenetriamine EDTAY
-
·
>
-
polydentate 6 626E
.
-
34
triphosphate
IA
A]
, :
form
rings in complexions OEs
S
called "crulates"
·
Geometric isomers can be square .
that are colorless because
·
e-fill "S" Orbital first EXCEPT Cr/Cu planar or octanedral
3 relativela
atomic size +
empty or filled d level
of
·
Optical somers are octahedral
·
Y IE/EN Ligandi can be ...
electrosle potential texcEpicu
·
Neutral (0) H20/NH3/co/ No
IE/EN 1
)
&
·
anionic (-)F-/c-1Br-11-IOH- /CN-
~
·
nuclear charge --
Density↑
·
anionic drop-ide and add - o
·
Reactivity ↓
·
Alsomers :
same formula , diff properties
A period 6 contains MOST DENSE elments
1) Constitution /I Structural : same form , connected diff
·
HEAVIER metals have HIGH EN + form ↳ coordination : exchange of complex exchange of
or
wi counterion ligands
more COVALENT BONDS
4)
linkage : diff composition of the ligand (NOCIONO
2) Stereoisomers : diff spatial arrangements
have multiple of stateswl highest
·
can
↳ Geometric/CI) TRANS : on the
can be
groups
.
being group # always has
same or
opposite side of antral metal
multiple ligands -
ADJACENT/TRANS
I
↑ CIS are are ACROSS
o State 4 Covalent Acidic ENT Oxide acidity ↑
↳ optical/enantiomers : identical
oX state + lonk Basic ENU Oxide acslty ↓ except for rotation direction
Lanthanides "Inner transition Actinides * CIS) NOT SUPERIMPOSED/OPTICAL
euments" (5d)
Period 6 (4d) Period 7 *TRANS / SUPERIMPOSED / NOT OPTICAL
·
"rare earth elements" common + 3 ox State
·
·
Except
Bonding in Complex lons
radioactive
most In ground all are
·
·
state
Ce/6d/Lu 1) Valence bond (VB) theory : when form
silver +
high . Melting
·
a complex son filled ligand orbital
[ charge of charge of
J
,
=
total charge
Coordination (mpds metal overlaps w/ empty metal orbital to
complex of ligands
donate/accept - +
form coord covalent bond
[its(b) (13] 3
look at OX
Astrong ligands/LARDER A
4
* weak
state first ligands are LB , metal lons are LA
ligands/SMALLER A then ligand & metal
complex llgand counter hybridization determines geometry
Central
metal con lon
strength
2) Crystal field explains how color
theory : t
CATIONIC
complex/ ANIONIC counters
higher
·
I is magnetism arises from splitting dorbitals
complexion
complex) [eg
↓
ANIONIC CATIDNIC counters ItalHed SpyO
·
+ =
D ( + 29)
metal adds
-
anion , zg
be absorbed to excite
Accordination # : # of ligands binded -
ate to end lower level e-
Coord# snape writing coord cmpds Naming Coord (mpds
·
color of a
ligand depends on
ox state of metal
n
2 linear 1) cation before anyon 1) cation before anion
4
splitting
metal ox
square planar 2) balance charges ↑I
2) ligands in alphabetical State energy A
T
tetrahedral
3) neutral ligands before
3) anionis
ligands drop-ide and add o
u
S
-
octahedral order
anion in alphabetical
ligand 4) numerical prefix specifies # of llgands higher energies
4) counter brackets
# of lone pairs lons outside
a
are absorbed from
donating to metal
is
bis(2) , tris (3) , tetrakis (4) SHORTER Wavel
F (fluoridel CN-(cyanidel of Inydroxide)
-
5)
~ · ·
MONO dentate Roman numeral indicates metal ox St.
·
H20(water) ·
ICN-(thocyanate)
·
NO z
-
Intrite)
NHz lammonia) cl-chlorides
6) If metal adds-ate
·
complexion
-
-
is anionic
,
en Jethylenediamine (
·
Bidentate
(20y (oxalate) -
>
1) All counter cons are listed as if there's only one
diethylenetriamine EDTAY
-
·
>
-
polydentate 6 626E
.
-
34
triphosphate
IA
A]
, :
form
rings in complexions OEs
S
called "crulates"
