TEST BANK for Organic Chemistry 6th Edition Smith
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m / All Chapters 1 - 29 / Full Complete
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Page 1
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxi
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dation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives-
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mNucleophilic Acyl Substitution
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Chapter m 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter m 22 Carbonyl Condensation Reactions
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Chapter m 23 Amines
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Chapter m 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter m 25 Pericyclic Reactions
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Chapter m 26 Carbohydrates
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Chapter m 27 Amino Acids and Proteins
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Chapter m 28 Synthetic Polymers
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Chapter m 29 Lipids (Available online)
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Page 2
, Chapter 1: Structure and Bonding
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1. Whatmismthemground-
statemelectronicmconfigurationmofmamcarbonmatom?mA)m 1s2,m2s2,m2p5
B)m 1s2,m2s2,m2p2 C)m 1s2,m2s2,m2p6 D)m 1s2,m2s2,m2p4
2. Whatmismthemground-
statemelectronicmconfigurationmofmamfluorinematom?mA)m 1s2,m2s2,m2p2
B)m 1s2,m2s2,m2p3 C)m 1s2,m2s2,m2p4 D)m 1s2,m2s2,m2p5
3. Whatmismthemground-
statemelectronicmconfigurationmofmammagnesiummcationm(Mg2+)?mA)
1s2,m2s2,m2p6 C) 1s2,m2s2,m2p6,m3s2
B) 1s2,m2s2,m2p6,m3s1 D) 1s2,m2s2,m2p6,m3s2,m3p2
4. Whatmismthemground-statemelectronicmconfigurationmofmamchlorinemanionm(Cl—
)?mA) 1s2,m2s2,m2p6 C) 1s2,m2s2,m2p6,m3s2,m3p5
B) 1s2,m2s2,m2p6,m3s2,m3p6 D) 1s2,m2s2,m2p6,m3s2,m3p4
5. Whichmofmthemfollowingmstatementsmaboutmvalencemelectronsmismtrue?
A) Theymaremthemmostmtightlymheldmelectrons.
B) Theymdomnotmparticipateminmchemicalmreactions.
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, Chapter 1: Structure and Bonding
C) Theymaremthemoutermostmelectrons.
D) Theymrevealmthemperiodmnumbermofmamsecond-rowmelement.
6. Whichmofmthemfollowingmstatementsmaboutmbondingmismtrue?
A) Covalentmbondsmresultmfrommthemtransfermofmelectronsmfrommonemelementmtomanother.
B) Ionicmbondsmresultmfrommthemtransfermofmelectronsmfrommammetalmtomamnon-metal.
C) Ionicmbondsmresultmfrommthemsharingmofmelectronsmbetweenmtwomnon-metals.
D) Covalentmbondsmresultmfrommthemsharingmofmelectronsmbetweenmtwommetals.
7. Whichmofmthemfollowingmwouldmyoumexpectmtomhavemionicmbonds?
A) CO B)m FBr C)m NF3 D)m NaCl
8. Whichmofmthemfollowingmmoleculesmhasmnonpolarmcovalentmbonds?
A) HCl B)m N2 C)m CHCl3 D)m NO
9. Whichmofmthemfollowingmmoleculesmcontainmbothmcovalentmandmionicmbonds?
A) I,mII B)m I,mIV C)m II,mIII D)mII,mIV
10. Arrangemthemfollowingmbondsminmdecreasingmordermofmionicmcharacter,mputtingmthemm
ostmionicmfirst.
A) Im>mIIm>mIIIm>mIV C) IVm>mIIIm>mIIm>mI
B) IVm>mIIm>mIm>mIII D) IVm>mIIm>mIIIm>mI
11. Whichmofmthemfollowingmstatementsmcorrectlymdescribesmthemtypicalmnumbermofmbondsmf
ormcarbon,mnitrogen,mandmoxygenminmmostmneutralmorganicmmolecules?
A) Carbonmformsm4mcovalentmbonds,mnitrogenmformsm2mcovalentmbondsmandmoxygenmfor
msm3mcovalentmbonds.
B) Carbonmformsm4mcovalentmbonds,mnitrogenmformsm3mcovalentmbondsmandmoxygenmfor
msm2mcovalentmbonds.
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m m m m m m m
m / All Chapters 1 - 29 / Full Complete
m m m m m m m m
Page 1
,Chapter 1 Structure and Bonding
m m m m
Chapter 2 Acids and Bases
m m m m
Chapter 3 Introduction to Organic Molecules and Functional Groups
m m m m m m m m
Chapter 4 Alkanes
m m
Chapter 5 Stereochemistry
m m
Chapter 6 Understanding Organic Reactions
m m m m
Chapter 7 Alkyl Halides and Nucleophilic Substitution
m m m m m m
Chapter 8 Alkyl Halides and Elimination Reactions
m m m m m m
Chapter 9 Alcohols, Ethers, and Related Compounds
m m m m m m
Chapter 10 Alkenes and Addition Reactions
m m m m m
Chapter 11 Alkynes and Synthesis
m m m m
Chapter 12 Oxidation and Reduction
m m m m
Spectroscopy A Mass Spectrometry
m m m
Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
m m m m m
Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
m m m m m
Chapter 15 Benzene and Aromatic Compounds
m m m m m
Chapter 16 Reactions of Aromatic Compounds
m m m m m
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxi
m m m m m m m m
dation and Reduction
m m
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
m m m m m
Chapter 19 Carboxylic Acids and Nitriles
m m m m m
Chapter 20 Carboxylic Acids and Their Derivatives-
m m m m m m
mNucleophilic Acyl Substitution
m m
Chapter m 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
m m m m m m m m
Chapter m 22 Carbonyl Condensation Reactions
m m m
Chapter m 23 Amines
m
Chapter m 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
m m m m m m
Chapter m 25 Pericyclic Reactions
m m
Chapter m 26 Carbohydrates
m
Chapter m 27 Amino Acids and Proteins
m m m m
Chapter m 28 Synthetic Polymers
m m
Chapter m 29 Lipids (Available online)
m m m
Page 2
, Chapter 1: Structure and Bonding
m m m m
1. Whatmismthemground-
statemelectronicmconfigurationmofmamcarbonmatom?mA)m 1s2,m2s2,m2p5
B)m 1s2,m2s2,m2p2 C)m 1s2,m2s2,m2p6 D)m 1s2,m2s2,m2p4
2. Whatmismthemground-
statemelectronicmconfigurationmofmamfluorinematom?mA)m 1s2,m2s2,m2p2
B)m 1s2,m2s2,m2p3 C)m 1s2,m2s2,m2p4 D)m 1s2,m2s2,m2p5
3. Whatmismthemground-
statemelectronicmconfigurationmofmammagnesiummcationm(Mg2+)?mA)
1s2,m2s2,m2p6 C) 1s2,m2s2,m2p6,m3s2
B) 1s2,m2s2,m2p6,m3s1 D) 1s2,m2s2,m2p6,m3s2,m3p2
4. Whatmismthemground-statemelectronicmconfigurationmofmamchlorinemanionm(Cl—
)?mA) 1s2,m2s2,m2p6 C) 1s2,m2s2,m2p6,m3s2,m3p5
B) 1s2,m2s2,m2p6,m3s2,m3p6 D) 1s2,m2s2,m2p6,m3s2,m3p4
5. Whichmofmthemfollowingmstatementsmaboutmvalencemelectronsmismtrue?
A) Theymaremthemmostmtightlymheldmelectrons.
B) Theymdomnotmparticipateminmchemicalmreactions.
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, Chapter 1: Structure and Bonding
C) Theymaremthemoutermostmelectrons.
D) Theymrevealmthemperiodmnumbermofmamsecond-rowmelement.
6. Whichmofmthemfollowingmstatementsmaboutmbondingmismtrue?
A) Covalentmbondsmresultmfrommthemtransfermofmelectronsmfrommonemelementmtomanother.
B) Ionicmbondsmresultmfrommthemtransfermofmelectronsmfrommammetalmtomamnon-metal.
C) Ionicmbondsmresultmfrommthemsharingmofmelectronsmbetweenmtwomnon-metals.
D) Covalentmbondsmresultmfrommthemsharingmofmelectronsmbetweenmtwommetals.
7. Whichmofmthemfollowingmwouldmyoumexpectmtomhavemionicmbonds?
A) CO B)m FBr C)m NF3 D)m NaCl
8. Whichmofmthemfollowingmmoleculesmhasmnonpolarmcovalentmbonds?
A) HCl B)m N2 C)m CHCl3 D)m NO
9. Whichmofmthemfollowingmmoleculesmcontainmbothmcovalentmandmionicmbonds?
A) I,mII B)m I,mIV C)m II,mIII D)mII,mIV
10. Arrangemthemfollowingmbondsminmdecreasingmordermofmionicmcharacter,mputtingmthemm
ostmionicmfirst.
A) Im>mIIm>mIIIm>mIV C) IVm>mIIIm>mIIm>mI
B) IVm>mIIm>mIm>mIII D) IVm>mIIm>mIIIm>mI
11. Whichmofmthemfollowingmstatementsmcorrectlymdescribesmthemtypicalmnumbermofmbondsmf
ormcarbon,mnitrogen,mandmoxygenminmmostmneutralmorganicmmolecules?
A) Carbonmformsm4mcovalentmbonds,mnitrogenmformsm2mcovalentmbondsmandmoxygenmfor
msm3mcovalentmbonds.
B) Carbonmformsm4mcovalentmbonds,mnitrogenmformsm3mcovalentmbondsmandmoxygenmfor
msm2mcovalentmbonds.
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