l l l l l l l
ition by Ghis w. Ogilvie nathan Ackroyd All Chapters 1-
l l l l l l l l l
20 Covered l
CopyrightlCengagelLearning.lPoweredlbylCognero. Pagel1
,TABLElOFlCONTENT
CHAPTERl1lCarbonlandlItslCompounds......Pagel27
CHAPTERl2lAnatomyloflanlOrganiclMolecule......Pagel73
CHAPTERl3lMoleculeslinlMotion:lConformationslbylRotations......Pagel112
CHAPTERl4lStereochemistry:lThree-DimensionallStructurelinlMolecules......Pagel151
CHAPTERl5lOrganiclReactionlMechanism:lUsinglCurvedlArrowsltolAnalyzelReactionlMechanisms......Pagel212
CHAPTERl6lAcidslandlBases......Pagel261
CHAPTERl7lπlBondslaslElectrophiles:lReactionsloflCarbonylslandlRelatedlFunctionallGroups......Pagel298
CHAPTERl8lπlBondslaslNucleophiles:lReactionsloflAlkenes,lAlkynes,lDienes,landlEnols......Pagel354
CHAPTERl9lConjugationlandlAromaticity......Pagel424
CHAPTERl10lSynthesislUsinglAromaticlMaterials:lElectrophiliclAromaticlSubstitutionlandlDirectedlOrtholMetalati
on......Pagel457
CHAPTERl11lDisplacementlReactionslonlSaturatedlCarbons:lSN1landlSN2lSubstitutionlReactions......Pagel520
CHAPTERl12lFormationloflπlBondslbylEliminationlProcesses:lEliminationlandlOxidationlReactions......Pagel566
CHAPTERl13lStructurelDeterminationlI:lNuclearlMagneticlResonancelSpectroscopy......Pagel603
CHAPTERl14lStructurelDeterminationlII:lMasslSpectrometrylandlInfraredlSpectroscopy......Pagel674
CHAPTERl15lπlBondlElectrophileslConnectedltolLeavinglGroups:lCarboxyliclAcidlDerivatives......Pagel722
CHAPTERl16lπlBondslwithlHiddenlLeavinglGroups:lReactionsloflAcetalslandlRelatedlCompounds......Pagel790
CHAPTERl17lCarbonyl-BasedlNucleophiles:lAldol,lClaisen,lWittig,landlRelatedlEnolatelReactions......Pagel836
CHAPTERl18lSelectivitylandlReactivitylinlEnolatelReactions:lControlloflStereoselectivityland......Pagel925
CHAPTERl19lRadicals:lHalogenation,lPolymerization,landlReductionlReactions......Pagel997
CHAPTERl20lReactionslControlledlbylOrbitallInteraction
CopyrightlCengagelLearning.lPoweredlbylCognero. Pagel2
,Test Bank for
l l
OrganiclChemistrylMechanisticlPatternsl1stlEditionlbylOgilvie,lAckroyd,lBrowning,l Deslong
champs,lSauerlISBNl9780176702717
Chapterl1-20
CHAPTERl1l-lCarbonlandlItslCompounds
2-
1. Whichloflthelfollowinglrepresentslthelgroundlstatelelectronlconfigurationlforlal O ion?
a.l 1s22s2 2p4
b.l1s22s2 2p2
c.l 1s22s2 2p6
d.l2s2 2p4
ANSWER:llc
2. Howlmanylvalencelelectronsldoeslalnitrogenlatomlcontain?
a. 2
b. 3
c. 5
d. 7
ANSWER:llc
2-
3. Howlmanylvalencelelectronsldoeslan O ionlcontain?
a. 2
b. 6
c. 8
d. 10
ANSWER:llc
CopyrightlCengagelLearning.lPoweredlbylCognero. Pagel3
, 4. WhatlislthelLewislstructureloflalcompoundlthatlhaslthelformulaloflCCl3l andlcontainsl24lvalencelelectrons?
a.
b.
c.
d.
ANSWER:lld
5. Howlmanylbondedlandlnon-
bondedlelectronsldoeslalmoleculelwithlnolformallchargeslandlthelformulal C2H4O2l contain?
a. 4lbonded,l4lnon-bonded
b. 7lbonded.l4lnon-bonded
c. 7lbonded,l5lnon-bonded
d. 4lbonded,l7lnon-bonded
ANSWER:llb
Figurel1
6. ReferringltolFigurel1,lwhatlislthelformallchargelofltheloxygenlatomlatlI?
a.l +1
b. 0
c. -1
d. -2
ANSWER:llb
7. ReferringltolFigurel1,lwhatlislthelformallchargelofltheloxygenlatomlatlII?
a.l +1
b. 0
c. -1
d. -2
CopyrightlCengagelLearning.lPoweredlbylCognero. Pagel4