~ Merrifield resins NCB250 - exam
7-9pm
↳ MF how to remove
friday
is
no class
other resin
~
any
↳ +FA
· ·
-be benzene
rings but
Shown
not
merrifield
-
Chapter 23-COENZYMEs
provide side chain
proteins for
-
substrate recognition, general
acid/base metal ions
3
is cofactor that vitamins
coenzyme a
molecule
is an organic
"cofactor"- > this can be a metal
or molecule
ion
organic
- used in stoichiometric
amounts
or catalytic
are vitamins
-
many coenzymes
or formed from vitamens
in organic chemistry
>
- reduction is addition of M2 or
-
removal of O
addition of 0 or
- oxidation is
-
removal of H2
1
-
- Coxidation)
CJH , 2 CHG
OH
-
M >
- M
-
Coxidation)
-
↳ Hiz CH , 20
17 >
- m Creduction)
V
GH12 G +, y
H
Chydration)
=
~
Gor
neither
, Oxidation States
of carbon
reduction Oxidation
- -
-
4 -
2
O + 2 + 4
H H
I
Hz H2
↳-
V -O +
H C : C 0
q
c
CL
H & c - 0 =
·
-> =
- -
: = o
Gr
I
↓ H20 ↓ 10
↓
It H
↓
Hz0
mo
O
i
i It
H - H
40 -
c -
on
CHzOH
-
n
↓ 10
n
↓ 120 ↓ H20
H c
H
No-on
e
Oh
-
-
One di
on
Formaldehyde
m
hydrate unstable
added
in bioorganic chemistry , He can be in 2
ways
1) add "H-" the +
,
.
2 ) e-
,
H
+, e, M
+
(giving 2e- & 2M)
H
no source
m
Nat
eqir :
nature
Ri
O
NH2
T ~
OH -
-N/
NI COT IN AMIDE
Niacin
NICOTINAMIDE
NICOTINIC ACID -
tn
G
ADENINE
&atte
-
DINUCLEOTIDE I
timnicotinamide
/
- -
>
-
① ↳
O
NADH
Briti
O
II coxidized Creduced
·
Go P
-
version ( version)
&
00 = p
omig
malate
= -
& NAD
dehydrogenase
NAD +
I ↓ NAD
+
no o H =
MALATE oxaloacetate
-
+ Ht
3-on
y
S
= NAP
contr
, malate
E O
O It
u0
I Non B
↓
M
O
M
oxalo acetate
wi
⑦ O
>
-
o
II
0 !
NADT
19
MINNE
/
↳
NADH
exchanging
removing
m
&
this
S oh glyceraldehyde
G
It
i
↑ ?
P
ope >
- HO
-
I - - 2 -
⑧
3-phosphate-dehydrogenase OPz
I O
11
g
↳
NADT %0-p-OH
,
glyceraldehyde-3-phosphate
de
1, 3-bisphosphoglycerate
+ NADH + H
7-9pm
↳ MF how to remove
friday
is
no class
other resin
~
any
↳ +FA
· ·
-be benzene
rings but
Shown
not
merrifield
-
Chapter 23-COENZYMEs
provide side chain
proteins for
-
substrate recognition, general
acid/base metal ions
3
is cofactor that vitamins
coenzyme a
molecule
is an organic
"cofactor"- > this can be a metal
or molecule
ion
organic
- used in stoichiometric
amounts
or catalytic
are vitamins
-
many coenzymes
or formed from vitamens
in organic chemistry
>
- reduction is addition of M2 or
-
removal of O
addition of 0 or
- oxidation is
-
removal of H2
1
-
- Coxidation)
CJH , 2 CHG
OH
-
M >
- M
-
Coxidation)
-
↳ Hiz CH , 20
17 >
- m Creduction)
V
GH12 G +, y
H
Chydration)
=
~
Gor
neither
, Oxidation States
of carbon
reduction Oxidation
- -
-
4 -
2
O + 2 + 4
H H
I
Hz H2
↳-
V -O +
H C : C 0
q
c
CL
H & c - 0 =
·
-> =
- -
: = o
Gr
I
↓ H20 ↓ 10
↓
It H
↓
Hz0
mo
O
i
i It
H - H
40 -
c -
on
CHzOH
-
n
↓ 10
n
↓ 120 ↓ H20
H c
H
No-on
e
Oh
-
-
One di
on
Formaldehyde
m
hydrate unstable
added
in bioorganic chemistry , He can be in 2
ways
1) add "H-" the +
,
.
2 ) e-
,
H
+, e, M
+
(giving 2e- & 2M)
H
no source
m
Nat
eqir :
nature
Ri
O
NH2
T ~
OH -
-N/
NI COT IN AMIDE
Niacin
NICOTINAMIDE
NICOTINIC ACID -
tn
G
ADENINE
&atte
-
DINUCLEOTIDE I
timnicotinamide
/
- -
>
-
① ↳
O
NADH
Briti
O
II coxidized Creduced
·
Go P
-
version ( version)
&
00 = p
omig
malate
= -
& NAD
dehydrogenase
NAD +
I ↓ NAD
+
no o H =
MALATE oxaloacetate
-
+ Ht
3-on
y
S
= NAP
contr
, malate
E O
O It
u0
I Non B
↓
M
O
M
oxalo acetate
wi
⑦ O
>
-
o
II
0 !
NADT
19
MINNE
/
↳
NADH
exchanging
removing
m
&
this
S oh glyceraldehyde
G
It
i
↑ ?
P
ope >
- HO
-
I - - 2 -
⑧
3-phosphate-dehydrogenase OPz
I O
11
g
↳
NADT %0-p-OH
,
glyceraldehyde-3-phosphate
de
1, 3-bisphosphoglycerate
+ NADH + H
