Test Bank for Organic Chemistry, 6th Edition by Janice Smith

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Chapter 1Structure andBonding Chapter 2
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AcidsandBases
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Chapter 3IntroductiontoOrganic Moleculesand Functional Groups Chapter 4Alkanes
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Chapter5Stereochemistry v v




Chapter6UnderstandingOrganicReactions
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Chapter 7Alkyl Halides andNucleophilicSubstitution Chapter 8
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Alkyl Halides and EliminationReactions Chapter 9Alcohols,
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Ethers,andRelatedCompounds Chapter 10Alkenesand
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Addition Reactions
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Chapter 11Alkynesand Synthesis Chapter
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12Oxidation andReduction SpectroscopyA
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MassSpectrometry SpectroscopyBInfrared
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Spectroscopy
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SpectroscopyCNuclear MagneticResonanceSpectroscopy Chapter 13 v v v v v v v




RadicalReactions
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Chapter 14Conjugation,Resonance,andDienes Chapter 15
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BenzeneandAromaticCompounds Chapter 16Reactionsof
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AromaticCompounds
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Chapter17IntroductiontoCarbonylChemistry:OrganometallicReagents; Oxidation
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andReduction
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Chapter18AldehydesandKetones—NucleophilicAddition Chapter 19
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CarboxylicAcidsandNitriles
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Chapter 20CarboxylicAcidsandTheir Derivatives-NucleophilicAcyl Substitution
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Chapter 21SubstitutionReactionsof CarbonylCompoundsat the α-Carbon Chapter22
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CarbonylCondensationReactions
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Chapter 23Amines v v




Chapter24Carbon-CarbonBond-FormingReactionsinOrganicSynthesis Chapter25
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PericyclicReactions
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Chapter26Carbohydrates v v




Chapter 27AminoAcids and Proteins
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Chapter 28SyntheticPolymers Chapter 29
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Lipids(Available online)
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Chapter 1: Structure and Bonding v v v v




1. What is the ground-state electronic configuration of a carbon atom? A)
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1s2, 2s2, 2p5
v v B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2,2s2,2p4
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2. What is the ground-state electronic configuration of a fluorine atom? A)
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1s2, 2s2, 2p2
v v B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2,2p5
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3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)? A)
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1s2, 2s2, 2p6
v v C) 1s2, 2s2, 2p6, 3s2 v v v




B) 1s2, 2s2, 2p6, 3s1
v v v D) 1s2, 2s2,2p6, 3s2, 3p2
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4. What is the ground-state electronic configuration of a chlorine anion (Cl—)? A)
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1s2, 2s2, 2p6
v v C) 1s2, 2s2, 2p6, 3s2, 3p5 v v v v




B) 1s2, 2s2, 2p6, 3s2, 3p6
v v v v D) 1s2, 2s2, 2p6, 3s2, 3p4
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5. Which ofthe following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding v v v v




C) They are the outermost electrons. v v v v




D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result fromthe transfer ofelectrons from one element to another. v v v v v v v v v v v v




B) Ionic bonds result fromthe transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result fromthe sharing ofelectrons between two metals. v v v v v v v v v v




7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl vv v vv




8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO v v vv




9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II
v B) I, IV vv v C) II, III vv v D) II, IV v v




10. Arrange the following bonds in decreasing order of ionic character, putting the most
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vionic first.
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A) I > II > III > IV
v v v v v v C) IV > III > II > I
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B) IV > II > I > III
v v v v v v D) IV > II > III > I
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11. Which of the following statements correctly describes the typical number of bonds for
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vcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms 3
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covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms 2
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covalent bonds.
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