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Organic Chemistry II Exam Review

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This is a In depth Understanding of what is on the Organic Chemistry II final, Including Aromatics, Organometallics, Polymerization, etc.

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Organic Chem II Final

Chapter 22

Halogenation




Ex Slowest step

9
affects 4
qfj
fecl CI
CI CI



CI

Nitration
NOR


HNO3
Hasoy


g Ng up Hg
Nos Fe HCI NaOH NO2 To
4504
no ÑH3CT NH2 NHa

, Sulfonification
5034

503
Hasoy



Friedel CraftsAlkylation




EI
HSC ChaffAIC's HSC CHT AIC 3
y
CanRearrange
EWG

No Rxn
EI
I
I
eFAICBHSC C
12 no
Does not Rearrange

, Electron Donating Electron Withdrawing
Group Groups

Halogens Carbonyls
Ethers Noa
Amines NH3

Alkyl chains Sulfur
Alcohols Xs
R Cyanide

ortho 1,2
EDG prefer ortho Para


meta 1,3
EWG prefer meta
Para 1,4

OCH OCH Most favored
Oct13
Noz Nor Resonancestructure

HNOs and Is ortho
42504
Para
COOH COOH Most Disfavored
No
Resonance Structure
HNO3
Haso and Prefers meta

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