CHM 2211C Lesson 11: Carboxylic Acid Derivatives K€+
1. For each of the following reactions, draw the structure of the major organic product in the box
provided. Each numbered set of reagents above, or below, the arrow represents a complete, separate
reaction. For multi-step reactions, give only the structure of the final product in the box.
a)
aldewydes
O h-‘-\oncs
Z OH 1) LiAlH,; ether Coarvonylie
2) H;0" acid g
(6]
b)
O Adenydes
O OH 1) NaBHy; ether. Re bones
2) H;0*
c)
0 0 S\2ene
H, e yne
H
o Raney Ni N\dewyde
Vae ‘ong
? | adm
d)
Qlcownol
(e} >_
OH Ettevificarion
OH
H2SO4; A
e)
inbernol
esverificalion
gl H,SO
H.c-)\/\)J\OH 2 4.
\ccrone
, Yorm
SOCl, Q/‘Kc. onid
e lor ide
pyridine
g
Corm
acsd
PCl, cw\oride
pyridine <\
h)
d‘Monq \adion
H,0
)\/r‘\
On
D
esyrerificadion
NaOCH,CH,
HOCH,CH,
k)
Cl
o] estreriticod ion
1. For each of the following reactions, draw the structure of the major organic product in the box
provided. Each numbered set of reagents above, or below, the arrow represents a complete, separate
reaction. For multi-step reactions, give only the structure of the final product in the box.
a)
aldewydes
O h-‘-\oncs
Z OH 1) LiAlH,; ether Coarvonylie
2) H;0" acid g
(6]
b)
O Adenydes
O OH 1) NaBHy; ether. Re bones
2) H;0*
c)
0 0 S\2ene
H, e yne
H
o Raney Ni N\dewyde
Vae ‘ong
? | adm
d)
Qlcownol
(e} >_
OH Ettevificarion
OH
H2SO4; A
e)
inbernol
esverificalion
gl H,SO
H.c-)\/\)J\OH 2 4.
\ccrone
, Yorm
SOCl, Q/‘Kc. onid
e lor ide
pyridine
g
Corm
acsd
PCl, cw\oride
pyridine <\
h)
d‘Monq \adion
H,0
)\/r‘\
On
D
esyrerificadion
NaOCH,CH,
HOCH,CH,
k)
Cl
o] estreriticod ion
