organic chemistry mechanistic patterns
1st edition by Ghis w. Ogilvie and Nathan Ackroyd
All Chapters 1-20 Covered
CopyrightvCengagevLearning.vPoweredvbyvCognero. Pagev
1
,TABLE OF CONTENT
v v
CHAPTERv1vCarbonvandvItsvCompounds......Pagev27
CHAPTERv2vAnatomyvofvanvOrganicvMolecule......Pagev73
CHAPTERv3vMoleculesvinvMotion:vConformationsvbyvRotations......Pagev112
CHAPTERv4vStereochemistry:vThree-DimensionalvStructurevinvMolecules......Pagev151
CHAPTERv5vOrganicvReactionvMechanism:vUsingvCurvedvArrowsvtovAnalyzevReactionvMechanisms......Pagev212
CHAPTERv6vAcidsvandvBases......Pagev261
CHAPTERv7vπvBondsvasvElectrophiles:vReactionsvofvCarbonylsvandvRelatedvFunctionalvGroups......Pagev298
CHAPTERv8vπvBondsvasvNucleophiles:vReactionsvofvAlkenes,vAlkynes,vDienes,vandvEnols......Pagev354
CHAPTERv9vConjugationvandvAromaticity......Pagev424
CHAPTERv10vSynthesisvUsingvAromaticvMaterials:vElectrophilicvAromaticvSubstitutionvandvDirectedvOrthovMetalation......Pagev
457
CHAPTERv11vDisplacementvReactionsvonvSaturatedvCarbons:vSN1vandvSN2vSubstitutionvReactions......Pagev520
CHAPTERv12vFormationvofvπvBondsvbyvEliminationvProcesses:vEliminationvandvOxidationvReactions......Pagev566
CHAPTERv13vStructurevDeterminationvI:vNuclearvMagneticvResonancevSpectroscopy......Pagev603
CHAPTERv14vStructurevDeterminationvII:vMassvSpectrometryvandvInfraredvSpectroscopy......Pagev674
CHAPTERv15vπvBondvElectrophilesvConnectedvtovLeavingvGroups:vCarboxylicvAcidvDerivatives......Pagev722
CHAPTERv16vπvBondsvwithvHiddenvLeavingvGroups:vReactionsvofvAcetalsvandvRelatedvCompounds......Pagev790
CHAPTERv17vCarbonyl-BasedvNucleophiles:vAldol,vClaisen,vWittig,vandvRelatedvEnolatevReactions......Pagev836
CHAPTERv18vSelectivityvandvReactivityvinvEnolatevReactions:vControlvofvStereoselectivityvand......Pagev925
CHAPTERv19vRadicals:vHalogenation,vPolymerization,vandvReductionvReactions......Pagev997
CHAPTERv20vReactionsvControlledvbyvOrbitalvInteraction
CopyrightvCengagevLearning.vPoweredvbyvCognero. Pagev
2
,Chapter 1-20 v
CHAPTER 1 - Carbon and Its Compounds
v v v v v v
2-
1. Whichvofvthevfollowingvrepresentsvthevgroundvstatevelectronvconfigurationvforvav O ion?
a.v 1s22s22p4
b.v1s22s22p2
c.v 1s22s22p6
d.v2s22p4
ANSWER:vvc
2. Howvmanyvvalencevelectronsvdoesvavnitrogenvatomvcontain?
a. 2
b. 3
c. 5
d. 7
ANSWER:vvc
3. Howvmanyvvalencevelectronsvdoesvan O ionvcontain?
2-
a. 2
b. 6
c. 8
d. 10
ANSWER:vvc
4. WhatvisvthevLewisvstructurevofvavcompoundvthatvhasvthevformulavofvCCl3v andvcontainsv24vvalencevelectrons?
a.
b.
c.
CopyrightvCengagevLearning.vPoweredvbyvCognero. Pagev
3
, d.
CopyrightvCengagevLearning.vPoweredvbyvCognero. Pagev
4