,Approximate proton Approxim
chemical shifts
TY PE OF CA
TYPE OF PROTON CHEMICAL SHIFT (cf, ppm)
1 ° Alkyl. RCH 3 1• Alk yl~ RC
0.8- 1.2
2° AJkyl. RCH 2R 1.2-1.5 2'° Alkyl, RC
3° AJky l, R3CH 1.4 -1.8
3 .. Alk11l, RC
Altylic. R.,C=C-CH3 1.6- 1.9
- I
R Alkyl halide
Ketone. RCCH 3 2. 1-2.6
II
0 Aicohol or e
Benzyhc, ArCH3 2.2- 2.6
Acerylenic. RC = CH 2.5 - 3. 1
A[kyne, -C
Ether. ROCH 2R 3.3- 3.9
Alcohol, HOCH1R 3.3- 4.0
\
Aikene, C=
Alkyl iodide, RCH1 1 3. 1- 3.3 I
Alkyl bromide , RCH 2Br
Alkyl chloride. RC H2Ci
Vinylic. R2C = CH 2
3.4-3.6
3.6-3.8
4.6 -5.0
Aryl , 0
Vinylic, R.,C = CH 5.2-5.7 Nitriles~- c
- I
R 0
Aroanatic. ArH 6.0-8.5 II
, STUDY
A
SOLUTION
TO ACC
ORG
CHEM
TWELFTH
T. W. GRAHAM
University o
CRAIG
Pacific Luth
, ACKNOWLEDGMENTS
We are grateful to those people who
editions of this study guide. These
Wenzinger, and J. E. Fernandez at
Oklahoma State University; John
Traynham, Louisiana State University
Chris Callam, The Ohio State Univer
Neal Tonks, College of Charleston.
We are especially grateful to R.G. (
and many contributions to this Study
T. W. Graham Solo
Cover Image Structure image fro
Duyne, G. D., Standaert, R. F., Schre
the Ramapmycin Human Immunoph
113, 7433.) created with JSMol.
This book was set in 10/12 Times Rom
Copyright© 2016, 2014, 2011, 2008
part of this publication may be reprod
any form or by any means, electronic,
chemical shifts
TY PE OF CA
TYPE OF PROTON CHEMICAL SHIFT (cf, ppm)
1 ° Alkyl. RCH 3 1• Alk yl~ RC
0.8- 1.2
2° AJkyl. RCH 2R 1.2-1.5 2'° Alkyl, RC
3° AJky l, R3CH 1.4 -1.8
3 .. Alk11l, RC
Altylic. R.,C=C-CH3 1.6- 1.9
- I
R Alkyl halide
Ketone. RCCH 3 2. 1-2.6
II
0 Aicohol or e
Benzyhc, ArCH3 2.2- 2.6
Acerylenic. RC = CH 2.5 - 3. 1
A[kyne, -C
Ether. ROCH 2R 3.3- 3.9
Alcohol, HOCH1R 3.3- 4.0
\
Aikene, C=
Alkyl iodide, RCH1 1 3. 1- 3.3 I
Alkyl bromide , RCH 2Br
Alkyl chloride. RC H2Ci
Vinylic. R2C = CH 2
3.4-3.6
3.6-3.8
4.6 -5.0
Aryl , 0
Vinylic, R.,C = CH 5.2-5.7 Nitriles~- c
- I
R 0
Aroanatic. ArH 6.0-8.5 II
, STUDY
A
SOLUTION
TO ACC
ORG
CHEM
TWELFTH
T. W. GRAHAM
University o
CRAIG
Pacific Luth
, ACKNOWLEDGMENTS
We are grateful to those people who
editions of this study guide. These
Wenzinger, and J. E. Fernandez at
Oklahoma State University; John
Traynham, Louisiana State University
Chris Callam, The Ohio State Univer
Neal Tonks, College of Charleston.
We are especially grateful to R.G. (
and many contributions to this Study
T. W. Graham Solo
Cover Image Structure image fro
Duyne, G. D., Standaert, R. F., Schre
the Ramapmycin Human Immunoph
113, 7433.) created with JSMol.
This book was set in 10/12 Times Rom
Copyright© 2016, 2014, 2011, 2008
part of this publication may be reprod
any form or by any means, electronic,
