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Hydrocarbons

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This notes contain a fundamental concept of the topic This includes illustration of my own and also from book and internet Hopefully this helps you in your exams and understanding the concept

Institution
Chemistry

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, 1
Hydrocarbon =
compounds with
Hydrogen and carbon only



found in
.
2 Natural
gas is upper Strata when
drilling wells in oil




.
3 LPG causes least
pollution Kerosene Perrol
; causes some
pollution ;
and CNG Causes less pollution .




.
4
HydrCarbon
I
↓ ↓ ↓

saturated Unsaturated Aromatic


5. alkanes at So
are inere room temperative they are called paraffin
Clittle affinity)

.
6 alkane C -C >
-
154Pm

C H -
>
-


112 Pm




.
7 Butane-2
9
isomers
Pentane -
3




.
8 CHn-
> 1 Carbon




3
9 Hexane - 5

isomers
Heptane -
9

Decane -
75




10
·
Preparation of alkane :




From unsatured : PtGPd catalyse the
hydrogenation reaction at

hydrocorbs room temp . but Ni catalyst need high temp -E pressure

, CH
=
(H2 + MXxpt/Ni >
CHz
-


CHz



CHz-C
=
Ch2+ H2 Pd/Ni
> CHy-Chi-Cry

CH3-CEC-H +
22 Cpd/Ni< Chz-CH2-CH3

From alkyl halide :

flourine
- Not
+
Hy >
(Hu MC(x 1)
CH
-X + = x Br
, ,




2Hj -P +
1 (4) + H




CUCUCH4 +
>CrzCUC + H




E
Brck gether
CHzBr + 2wa +
,
>
CH-CHz + 2NaBr

Wurtz
reaction
[HgBr + 2Na +
BrEUyetery CUz
=



CH5

From
Carboxylic acid
3 :


Sodalime-mixture of NaOH + CaO


sodalime
X
Decarboxylation :




CH CooNa" CHy
,
+ Naoh > +
Na 3




Kolbe's elecnolysis :




CooNat
2CH
,
+
2110 Zecnolysis> CHz-CHz + 20 ,


+ H2 + NaOH




Anode :
CO2 CHC
,



Cathode H2
:

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