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Polar Covalent Bonds: Acids and Bases

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Organic molecules often have polar covalent bonds as a result of unsymmetrical electron sharing caused by differences in the electronegativity of atoms.  The polarity of a molecule is measured by its dipole moment, .  (+) and () indicate formal charges on atoms in molecules to keep track of valence electrons around an atom.  Some substances must be shown as a resonance hybrid of two or more resonance forms that differ by the location of electrons.  A Brønsted(–Lowry) acid donates a proton.  A Brønsted(–Lowry) base accepts a proton.  The strength Brønsted acid is related to the negative logarithm of the acidity constant, pKa. Weaker acids have higher pKa’s. A Lewis acid has an empty orbital that can accept an electron pair.  A Lewis base can donate an unshared electron pair.  In condensed structures C-C and C-H are implied.  Skeletal structures show bonds and not C or H (C is shown as a junction of two lines) – other atoms are shown.  Molecular models are useful for representing structures for study.  Noncovalent interactions have several types: dipole- dipole, dispersion, and hydrogen bond forces.


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