Solution Manual: Molecular Driving Forces (Statistical Thermodynamics) – Chapter 1 to 7

123456279 74 3292343 66721556563
 27 6676232 65
67

7
26637 
652
76 6526933156455!5
"#$%65! !








































,G
G
LMNOPQRUS
VRWXYWOZQ[\]VR\^N^WZWP_S
ST

ST ST



S?EG1:I 7877 81:5:97E
` `

01245675889714777 59411967159155551




!"#$$
!$%!&'()*!+
"&,-!.(/!0.12.1/!+0,3!4$
!5
)**!.!)!61$7.7'
'')*!8$
9

!
:7578757;<=>?=;@A<=>B=5;C<=>D=EF274547
57857767577877E
5GH454781:5:94512I717J47759751757857K
:GH454781:5:94512J99:75787::14C565 5@2924K

5Ga47`897`J5`1`1967`4`81:97``1`7599`45`J47`81:5:97`57
`b
cde;ecdecf`5`12`J5`47`81:5:9`1`767`ghiFj@`k`12`5`lmnfb;noh
i4 7E`H47`767`57`lmfmpnnohieqrnmsbtehi5`12`J5`47`81:5:9`1
`767`ghiuv`k`12`5`pddhi 47`81:5:97E`a47717`J7` `1` 227`47
`81: 97`1`5`Fj@`5`uv`81:97E`H7`J5` 47`81:5:9`1`I7 I`1
`C`uv`@ A`1`E`w2`4`/$)*(9`4798`:7527`477`767`57`1`22599
`7x9267`22599`7x9267`75` 45` `17`45887` 47`147`51
`45 887E`1`J7` `5I5E`a47`81:5:9`1`57857`17J477`yhip``yh
i
p`<`?`z{|yhi}`J477`yhi}``47`81:5:9`45`8$
91)` 7~77`767J477E
`+4$
91)`7 47`5787`17J477`1`8$
91)`1E`w2` 4`81:5:9`rpchi:7
`82``47`5:167`7E`yhi}`<`47`81:5:9`45`8$
91)`7~77`5`C`Fj@`5
`@ A`Fj@`5`E`a477`767`57`7877`1`J7`4567`47`5J7E`a47
`81: 5:9`1` 7~71`5`C``;}C`<`?`z{|=>D`<`=>DE`v7~71`5`@A`
`;}@A`<`?`z{|=>B`<`=>E`v7~71`5`` `;}`<`?`z{|=>?`<`=>€E
`a 47717`yhi}`<`=>D=>=>€`<`=>B?DE`a47717`47`81:5:9`1`5`975`17
`57857
<`yhip`<`?`z{|yhi}`<`=>‚DE



?

, 01245689 689689858598985686968886668669

020


2880!"20!#2
88 !$"!%
%
&8 68 658 5886568 80288598 898868'8
8568 99168' 969(8)6*6886688868 ''+86,'96(
84 568 11 698886(845689 6885685688959(8456668
8 9 9168' 969868-688'81+8../01%2568 ''+86,'96
8669836564885678/79/01%2 6668669

:028;80<2=:0


28;80<


2=:0>?
@28;80<>?
@2=88$A%
%
86B'6+4

8020


20>?
@28;8020


20<>?
@2
;020<


20>?
@28;8CDECDECD
D
5668568986 898568 11 +8866888#485689686 
8669698668888


81'86*688>?
@48568586 
8669698668888>?
@81'86*688


486(8F58
8569686698 98 ''+86,'968586968865856G85666856+86
88 6(8F58'86 8669698666866984886, 648
80.%2


80.%2>?
@(84566688 989 688688568968859
8 16 868880.%2


481'86868HIJKL8681'8>?
@(8459
8 11 +8 9

020


28888020


2:0>?
@28;80<>?
@2=
880!"20!#2
88 !$"!%
%
M685868'8568968 80285689 68+G88'85686B'6
838'88568 68 99168 ''+86,'968669(8N'8856-
858836985689 689689816801'86858 '58 686'98892(








O

, 
-
/ 86410 90142441
01123467866749281410826742847 8014244
943 341

8

7861674 86!99"67414244000067 2"783
784#



7861674 86!99"6741424400000000067 2"783
784#



7861674 86!99"8!14244678678192$%&'6 (%&'6 )%&'*
84127816786
8
#


8

1870 8140 210670 86!0.2+0740 86!0 90803450 160.01
0. 2+0 903450 160-010.2+0 903450 1606010.2+0 907450 160+010.2+8
08 010 @0A744084080 81410740 86!0 906710149014244010
.2+

09 06
 :;0<=>.? 



B83408140810
8
08 C4



1870149014244078106740 86!0"C408 C40 2600671081406744084
038 !0 1140142441077018619!067404243460678604078C40+03%&'0-0745%&'0-
0D%&'080.
E0F 038!08406744#040168608104078C40 40 49 40 !081123"0804
0 G 461084016"21784074408408,08 8"434610 904016"21784
0 G 4610080480142440
7409160 4080 4008!0 9040 8410674
014008!0 906740438"04"760 84108010 
0H26040IJK%L016"217
067409203%&'0104078C40 C42640 !080986 0 90+,08032160C406710 26
040I JK%L016"217067406 0745%&'0104078C40 C42640 !0-,0803216081
0C406710 2600010 0B06740 86!0 9078C"067103 1601
8, . 98 


+,-,-,., + ?:?.+:4











6