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University of Wisconsin–Madison
W Department of Chemistry
EST. 1848
NUMEN LUMEN · THE WISCONSIN IDEA
Chem 104 Exam #2 Study Materials
G E N E RA L C H E M I ST RY I I — M O L E CU L A R G E O M E T RY, O R GA N I C C H E M I ST RY &
T H E R M O DY N A M I CS
INSTITUTION University of Wisconsin–Madison PROGRAM Bachelor of Science — General
Chemistry II
COURSE CODE Chem 104 COURSE TITLE General Chemistry II
ACADEMIC YEAR EXAM TITLE Chem 104 Exam #2 Study Materials
TOTAL QUESTIONS 48 Questions FORMAT Multiple Choice — Select the
Single Best Answer
STUDY GUIDE INSTRUCTIONS
▸ This study guide covers molecular geometry, intermolecular forces, organic functional groups, fatty
acids, isomers, and thermodynamics for Chem 104 Exam 2.
▸ Each question tests one discrete concept, definition, or classification from the course material.
▸ Select the single best answer for each question. Correct answers and detailed rationales are provided.
▸ Pay careful attention to VSEPR theory nomenclature (electron geometry vs. molecular geometry), IUPAC
functional group naming, and thermodynamic sign conventions.
▸ All content reflects the standard General Chemistry II curriculum at UW–Madison.
, CHEM 104 — VSEPR, ORGANIC FUNCTIONAL GROUPS &
Questions 1 – 48
THERMODYNAMICS
1. A student is identifying an organic functional group that contains a carbonyl group (C=O)
bonded to a hydroxyl group (–OH), represented as –COOH. This functional group is
characteristic of organic acids. What is its name?
A. Ester
B. Aldehyde
C. Carboxyl acid (carboxylic acid)
D. Ketone
CORRECT ANSWER C — Carboxyl acid (carboxylic acid)
RATIONALE A carboxyl (carboxylic acid) group consists of a carbonyl (C=O) bonded to a
hydroxyl (–OH), written as –COOH. It is the functional group of organic acids like
acetic acid. An ester (Option A) has –COOR where R is an alkyl group. An aldehyde
(Option B) has –CHO with H attached to the carbonyl carbon. A ketone (Option D)
has C=O with two alkyl groups. Carboxylic acids are acidic because the –OH
proton is readily donated, stabilized by resonance with the carbonyl oxygen.