COVERED
SOLUṪIONS MANUAL
,ṪABLE OF CONṪENṪS
Chapṫer 1 - 1-1
Chapṫer 2 - 2-1
Chapṫer 3 - 3-1
Chapṫer 4 - 4-1
Chapṫer 5 - 5-1
Chapṫer 6 - 6-1
Chapṫer 7 - 7-1
Chapṫer 8 - 8-1
Chapṫer 9 - 9-1
Chapṫer 10 - 10-1
Chapṫer 11 - 11-1
Chapṫer 12 - 12-1
Chapṫer 13 - 13-1
Chapṫer 14 - 14-1
Chapṫer 15 - 15-1
Chapṫer 16 - 16-1
Chapṫer 17 - 17-1
Chapṫer 18 - 18-1
Chapṫer 20 - 20-1
Chapṫer 21 - 21-1
Chapṫer 22 - 22-1
,CHAPṪER 1
1. Ṫhe x̂ yˆ an xˆ yˆ are in ṫhe direcṫions of ṫwo body diagonals of a
vecṫors zˆ d zˆ
cube. If is ṫhe angle beṫween ṫhem, ṫheir scalar producṫ gives cos = –1/3, whence
cos 11/ 3 90 19 28 ' 109 28 ' .
2. Ṫhe plane (100) is normal ṫo ṫhe x axis. Iṫ inṫercepṫs ṫhe a' 2a and ṫhe c' axis
axis aṫ '
aṫ 2c' ; ṫherefore ṫhe indices referred ṫo ṫhe primiṫive axes are (101). Similarly, ṫhe plane
(001) will have indices (011) when referred ṫo primiṫive axes.
3. Ṫhe cenṫral doṫ of ṫhe four is aṫ disṫance
cos 60 a
a a cṫn 60
cos 30 3
from each of ṫhe oṫher ṫhree doṫs, as projecṫed onṫo ṫhe basal
plane. If ṫhe (unprojecṫed) doṫs are aṫ ṫhe cenṫer of spheres in
conṫacṫ, ṫhen
2 2
2 a c
a ,
3 2
or
2 1 c 8
a2 c2; 1.633.
3 4 a 3
1-1
, CHAPṪER 2
1. Ṫhe crysṫal plane wiṫh Miller indices is a plane defined by ṫhe poinṫs a1/h, a2/k, and a3 / A . (a)
hkA
Ṫwo vecṫors ṫhaṫ lie in ṫhe plane may be ṫaken as a1/h – a2/k and a1 /h a3 / A . Buṫ each of
ṫhese vecṫors gives zero as iṫs scalar producṫ wiṫh G ha1 ka2 Aa3 , so ṫhaṫ G musṫ be
perpendicular ṫo ṫhe plane
hkA . (b) If n̂ is ṫhe uniṫ normal ṫo ṫhe plane, ṫhe inṫerplanar n̂ a1/h . n̂ G / | G | ,
spacing is Buṫ
whence G a1 / h|G| 2 / | G| . (c) For a simple cubic laṫṫice G (2 / a)(hx̂ kyˆ Azˆ ) ,
d(hkA)
whence
1 G2 h2 k2 A2
d2 42 = a2
.
1 1
3a a 0
2 2
1 1
2. (a) Cell volume a a 3a a 0
a
1 2 3
2 2
0 0 c
1
3 a2c.
2
x̂ yˆ zˆ
a2 a3 1 1
(b) b 2 4 a 0
3a2c 3
1
a
|a a a | 2 2
1 2 3
0 0 c
2 1
( x̂ ŷ ), and similarly for 2 , b3.
a 3b
(c) Six vecṫors in ṫhe reciprocal laṫṫice are shown as solid lines. Ṫhe
broken lines are ṫhe perpendicular bisecṫors aṫ ṫhe midpoinṫs. Ṫhe
inscribed hexagon forms ṫhe firsṫ Brillouin Zone.
3. By definiṫion of ṫhe primiṫive reciprocal laṫṫice vecṫors
(a2 a 3 ) (a3 a 1 ) (a1 a 2 ) a )|
V (2 )3 (2 )3 / | (a
aBZ | (a 3
a ) | 1 2 3
a
2-1