[-**] Half Life
·
Rxn Rate Energy of uxns
·
·
# 693) /In =
- concentration
1
0
TDHrXn Ea(frod)-Eacrevs]
= = .
2
must account :
↳
Solig for coefficients order
S
Temperature 4 -> ·
CDHENDO HAH EXO
t12 ↑ ↓
[ [A]m[B]n]
3 when K
Energy ↑ Rate =
Ea/fwd)
·
↳ surface area ↑
+
(vev) are inverses
~
·
product [] always increases
Treactants , I ·
Activation Energy
constant
Reactant [J always decreases
↓ TK :
Ae FaIRT]tmp (k)
ratefrequency
3
-
↓
1st order DOUBLES E
·
Product =
2nd Order QUADROPLES
·
overall run order energy
Oth Order NO CHANGE
·
final
-
i
-
·
Molecularity is based on of restants
-
=( Tz
-
↑ Initial
negas) product-
Equilibrium
[k =Proce
Partial Pressure Ca/Balsr/C / Br/
·
, * Neutral :
n(gas) reactant
1/ NOz I ClOy
[Kp
-
Ea(tw() Ealrev/
kc(RT) Angas ]
=
=
: 0 0021
.
-k 1
·
K) 1/Q - PROD
* AcidIC : ASOy /HCOg-
=
Q use pressures like concentrations
K at K <
1/Q7 REACT
·
=
any other equilibrium
Alf a question gives a concentration , assume ICE CHART
point
·
Q/17 only Include (9) (99)
·
Pressure :
adding/removing a product/reactant
equation but only temp affects K
-
can shift
1) Balance equation
& ADDING heat to an ENDO rn INCREASES K
2) rid of (s)/(l)
(i)
↳ ADDING heat to an EXO rxn DECREASES K
coefficients become exponents
-
If
find Q from
reversed
[prod]/Creact]
the
& In Dr I
multiplied multiplier
>
If
multiply all Ke kc(overall)
·
=
ACIDS/Proton DONORS Strong ACICS Strong Bases "b" Percent Dissociation
· · ·
·
I J
BASES/Proton ACCEPTORS HzS HNO3 LiOH 3 (sOH
CHAJinit[HA] diss
·
↳ >
[HA] as
·
diss
* CB has 7 less H 1 -HI HC1 3 NaOH 3 (a(OH)z <100
more
neg
:
&
CHAJin't ·
smaller Ka / lower diss
* CA has 7 more H 1 less
3) HBr DHClOy 3 KOH 3 Sr(OH)2
neg
+
3
"So 1 Brought
o RbOlt Ba(OH)2 * WB + SA-ACIDIC
Reaction favors WA/WB clean clothes
"
- -
Initial concent .
* SB + WA-BASIC
·
Autolonization of water pH scale of JB/SA * SB + SA- NEUTRAL
[kw
-
[OH]]
I
-
↓
CH30 ] :
DH 14 pOt
= = -
* WB + WAT DEPENDS
L V
&) IE-14
POH =
-10g [OH-] pH -10g [H30 + ]
=
Lewis acds
accept e-pair (H)
·
·
[A30 ] +
> [OH] ACIDIC OH = 10
-
POH HzOt =
18-PH LeWIS bases dinate e pair (-)
[H30 ] +
< [OH-] BASIC 18 pka
·
ka
-log(ka)
-
pKa
= =
-
↓
[H30"] [OH] NEUTRAL M
·
=
same for Kb
17bxka =
kw
·
Rxn Rate Energy of uxns
·
·
# 693) /In =
- concentration
1
0
TDHrXn Ea(frod)-Eacrevs]
= = .
2
must account :
↳
Solig for coefficients order
S
Temperature 4 -> ·
CDHENDO HAH EXO
t12 ↑ ↓
[ [A]m[B]n]
3 when K
Energy ↑ Rate =
Ea/fwd)
·
↳ surface area ↑
+
(vev) are inverses
~
·
product [] always increases
Treactants , I ·
Activation Energy
constant
Reactant [J always decreases
↓ TK :
Ae FaIRT]tmp (k)
ratefrequency
3
-
↓
1st order DOUBLES E
·
Product =
2nd Order QUADROPLES
·
overall run order energy
Oth Order NO CHANGE
·
final
-
i
-
·
Molecularity is based on of restants
-
=( Tz
-
↑ Initial
negas) product-
Equilibrium
[k =Proce
Partial Pressure Ca/Balsr/C / Br/
·
, * Neutral :
n(gas) reactant
1/ NOz I ClOy
[Kp
-
Ea(tw() Ealrev/
kc(RT) Angas ]
=
=
: 0 0021
.
-k 1
·
K) 1/Q - PROD
* AcidIC : ASOy /HCOg-
=
Q use pressures like concentrations
K at K <
1/Q7 REACT
·
=
any other equilibrium
Alf a question gives a concentration , assume ICE CHART
point
·
Q/17 only Include (9) (99)
·
Pressure :
adding/removing a product/reactant
equation but only temp affects K
-
can shift
1) Balance equation
& ADDING heat to an ENDO rn INCREASES K
2) rid of (s)/(l)
(i)
↳ ADDING heat to an EXO rxn DECREASES K
coefficients become exponents
-
If
find Q from
reversed
[prod]/Creact]
the
& In Dr I
multiplied multiplier
>
If
multiply all Ke kc(overall)
·
=
ACIDS/Proton DONORS Strong ACICS Strong Bases "b" Percent Dissociation
· · ·
·
I J
BASES/Proton ACCEPTORS HzS HNO3 LiOH 3 (sOH
CHAJinit[HA] diss
·
↳ >
[HA] as
·
diss
* CB has 7 less H 1 -HI HC1 3 NaOH 3 (a(OH)z <100
more
neg
:
&
CHAJin't ·
smaller Ka / lower diss
* CA has 7 more H 1 less
3) HBr DHClOy 3 KOH 3 Sr(OH)2
neg
+
3
"So 1 Brought
o RbOlt Ba(OH)2 * WB + SA-ACIDIC
Reaction favors WA/WB clean clothes
"
- -
Initial concent .
* SB + WA-BASIC
·
Autolonization of water pH scale of JB/SA * SB + SA- NEUTRAL
[kw
-
[OH]]
I
-
↓
CH30 ] :
DH 14 pOt
= = -
* WB + WAT DEPENDS
L V
&) IE-14
POH =
-10g [OH-] pH -10g [H30 + ]
=
Lewis acds
accept e-pair (H)
·
·
[A30 ] +
> [OH] ACIDIC OH = 10
-
POH HzOt =
18-PH LeWIS bases dinate e pair (-)
[H30 ] +
< [OH-] BASIC 18 pka
·
ka
-log(ka)
-
pKa
= =
-
↓
[H30"] [OH] NEUTRAL M
·
=
same for Kb
17bxka =
kw
