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Chem 331 Final exam Questions and All Correct Answers Updated.

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Slaters Rule - Answer same n = 0.35 n-1 = 0.85 all others = 1 Slaters Rule - Answer same n = 0.35 n-1 = 0.85 all others = 1 IR active vibration - Answer Must give rise to a change in the dipole moment of the molecule Raman active vibration - Answer Must give rise to a change in the polarizability of the molecule Determining hybridization - Answer # of atoms + # of lone pairs =x if x= 4 -- sp3 x=3 -- sp2 X=2 -- sp Cubic Close Packing (CCP) - Answer - one sphere is in contact with 12 others - every third layer is the same ABCABC - also called face center cubic Hexagonal Close Packed (HCP) - Answer - every second layer is the same ABAB -coordination # 12 (always touching 12 atoms) Interstitial holes - Answer Close packed structures have octahedral and tetrahedral holes Coordination # - Answer - # of atoms each atom touches - Smaller coordination # = lower space occupancy Polymorphism - Answer If a substance can exist as more than one crystalline form

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Chem 331 Final exam Questions and
All Correct Answers 2025-2026
Updated.
Slaters Rule - Answer same n = 0.35

n-1 = 0.85

all others = 1



Slaters Rule - Answer same n = 0.35

n-1 = 0.85

all others = 1



IR active vibration - Answer Must give rise to a change in the dipole moment of the molecule



Raman active vibration - Answer Must give rise to a change in the polarizability of the
molecule



Determining hybridization - Answer # of atoms + # of lone pairs =x

if x= 4 --> sp3

x=3 --> sp2

X=2 --> sp



Cubic Close Packing (CCP) - Answer - one sphere is in contact with 12 others

- every third layer is the same ABCABC

- also called face center cubic



Hexagonal Close Packed (HCP) - Answer - every second layer is the same ABAB

-coordination # 12 (always touching 12 atoms)



Interstitial holes - Answer Close packed structures have octahedral and tetrahedral holes



Coordination # - Answer - # of atoms each atom touches

- Smaller coordination # = lower space occupancy



Polymorphism - Answer If a substance can exist as more than one crystalline form

, ie: Diamond and Graphite



Unit cell density - Answer ((mass/avogadros #)/length) = g/cm3



Lattice energy - Answer In ionic compounds it is the change in internal energy that
accompanies the formation of 1 mol of solid from its constituent gas phase ions @ 0K



Defacto - Answer Characterizes the connectivity of elements,

# of bonds for an element

ie: SH2 = divalent

SO2 = tetravalent (Draw it)



Determining Oxidation state - Answer 1. determine the most electronegative atom

2. count the # of electrons they usually have in their ionic state

3. Determine what the overall charge for each atom is



Group 1 elements - Answer - Highly reactive, strong reducing agents

- Used extensively as a strong base

-created using the Downs Process



Downs process - Answer NaCl + CaCl --> Na(l) + 1/2 Cl2(g)



Via electrolysis



Electrolysis - Answer The best way to reduce an element



Group 2 elements - Answer - Strong reducing agents

- Good lewis acids

- Highly reactive



IR Active symmetry labels - Answer Labels that have x,y,z values then they are IR active



Raman Active symmetry labels - Answer Labels that have a product equation (ie: x^2, xy) are
Raman active

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