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Bonding: - 🧠ANSWER ✔✔■ covalent or ionic (higher mpt)
■ octet rule= elements bound to become stable (8ve)
■ stable full non-octets (H,He,Li,Be,B, semi-full transition metals)
■ expanded octet rule= elements that can fit more than 8ve are also stable
(N=3 or greater)
3 bond types: - 🧠ANSWER ✔✔1. ionic=gain/lose ve
2. covalent=shared ve
3. coordinate covalent=one sided 2e contribution to form bond
,Ionic bonds: - 🧠ANSWER ✔✔-transfer of ve from element with low IE→high
IE (metals to halogens)
-between elements of large ΔEN>1.7 (metal to nonmetals)
-electrostatic attraction btn ions (after exchange) keeps bond close
-forms crystalline lattices (high mpt)
-vulnerable to shifts caused by polar solvent (Na and snow)
Covalent bonds: - 🧠ANSWER ✔✔■ sharing of ve btn elements of similar
EN
■ increase bond order (-,=,≡) will increase ↑strength, ↑energy, but has
↓distance
■ Formal changes=due to more/fewer ve after bonding
*resonance occurs in pi bonds (which electrons can alternate btn the 2
bonds)
3 type of covalent bonds: - 🧠ANSWER ✔✔■ nonpolar=balanced EN btn
atoms (ΔEN<0.5)
, ■ polar=unbalanced EN btn atoms (ΔEN=0.5-1.7)
■ coordinate covalent bonds=single atom contributes 2ve into bond(Lewis
acid bases)
Valence shell electron pair repulsion theory (VSEPRT): - 🧠ANSWER ✔✔-
predicts 3D geometry based on e- to e- repulsion
-lone pairs contribute more to angles (push closer to nucleus)
-electronic geometry=position of all (e-)
-molecular geometry=position of bonding pairs only
*when electron domain= you count lone pairs as groups, bonded pairs are
another group
Polarity of molecules: - 🧠ANSWER ✔✔■ depends on sum of dipole
moments (unbalance or not)
■ σ bonds=single head to head overlap (direct)
■ π bonds=overlap of parallel electron clouds (side) in addition to single σ
bond
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