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Aromatic Substitution

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Aromatic Substitution Reactions Handout – Your Go-To Guide for EAS Mastery Nail electrophilic aromatic substitution (EAS) reactions with this clear, organized, and high-yield handout that breaks down one of Organic Chemistry’s most reaction-rich topics. What’s included: Step-by-step mechanism breakdowns for key EAS reactions: nitration, sulfonation, halogenation, Friedel-Crafts alkylation & acylation Activating vs. deactivating groups explained with real examples Ortho/para vs. meta directors and how to predict substitution patterns Summary chart of common substituents and their directing effects Practice problems with reaction predictions and full solutions Tips to avoid common mistakes in exam questions and synthesis problems Perfect for Organic Chemistry students preparing for exams, quizzes, or reaction mechanism reviews.

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Institution
University Of Florida
Course
CHM2211 (CHM2211)











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Institution
University Of Florida
Course
CHM2211 (CHM2211)
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Uploaded on
May 22, 2025
Number of pages
33
Written in
2024/2025
Type
Class notes
Professor(s)
Pete punthasee
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1
Chapter 18 – Electrophilic Aromatic Substitution



Chapter 18 – Aromatic Substitution Reactions
Unexpected Bromination of Benzene




Electrophilic Aromatic Substitution




Me when I saw a mirror at the gym

, 2
Chapter 18 – Electrophilic Aromatic Substitution


Rxn1: Halogenation




Mechanism of the formation of Fe-Br complex




Mechanism of Bromination of Benzene




Me when I saw a mirror at the gym

, 3
Chapter 18 – Electrophilic Aromatic Substitution




This is the target




sincedenzene
Rxn2: Sulfonation are




Me when I saw a mirror at the gym

, 4
Chapter 18 – Electrophilic Aromatic Substitution


Rxn3: Nitration




= -1 4 pica
=
-3)stronger
pla
.




- 1
W
↑
: -1 7
pica
.




- 1
H
A ↳
4




under
acidic
Rxn3.1: Reduction of NO2 group condition

↓




Ammulinium On




Me when I saw a mirror at the gym
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