t\l cohols HYDRoxy COM PDUNDS 1[. Ft-om 6 ri 3ria.-d R-e "'-3 e." ~ ·
c..10.s.s tfi c.q t::i~s · 0. . Ald&_\..,\jck Ond kebo~ :
½. Po½ h'j dric. Al Loh ob '. Gr
71.e..se... cn-e. cf +wo t~pe.s I
i 0)1
~ Ll1 3 - CJ1-i_· 0hlM~
c.Jh-011
O>j
\ . A!c.,ohol f>= lf -011 g~p 1'sc.onneLteJ
-t"o Sid e- chain Dr al l<.:tL g rtr\,.p . t\1
Ex . ,,Z,,, ~011 v1 OH
1-1 OH
'2. . P he-nol.5 .:- l f
-or1 ~rtf\.\p is dire.ct~
cJ1 1-o r1 CH1-~;CL
Co nne.ct::e.d.. to be.n ·2..e_Y\.Q.. rihB ·
Ex : Cs), ©-oH GMP :
0
c . t3'j 1-1:.i,-,'.3 ~ster-
ci
m,
ALwhol.5 1. F r-o tn A*e..ri e.s C.11 r C11 - O - C.)1 He M'.) l:>..- '> I
~ H3 ot- He -C-H~
- 12,Qs ed.. oh no . cf - or1'jYO'\..tp5 a. . AC..I d - C q tr>.½ <:>ed \., 'j d re,,_ b' C/Y) ' .
c{. [3~ Ltsin3 Epu-.,;i des 1-4.
, I . Monoh-:fd.-,'c. cdcohol..s : b . 1-f B O re o. c.t-icn--,
q . lo.,, c-11ron l$c.pv· pr-imar~ c.. oH D 1--e"'t t-im
('.) 11
C..11 3 - C ti ::-c.ri,2 H -t I
.:.. CHrCH2. -o H 30 ') (YJ?, -C.r\- Cf13
b :r:::. C.t1.3 - 01-a ri
I
I HBO
01.,3 C..onditicrn.s :
0-'3 I
C · 3' .::> 013 - C. - Ori t e. Reo.rro.n t. Pi-o~cC:-.
C\ . Cc. r b o C<:1 b 'a-n
'
C..\13 b. ~ 11 ru. le.
(_jc. ~ ·c:. Ti-ans; b'an
-<. Dih~dric. Ak.o'nal.5
a . \/icinaL[1 1.23 > C>-12- c.n2 '--
S1.:-q l:e
X A-11 h.tl e +. 61:1 L{S i"~ c jO.nicle
C!;Jc.u.'r_ Hu.rcur,'c.
l
0)1
I
01-1 1-lc.e..t-o..t::e..i'O'h
X Ml'i.lle.
R-c ==t-1 Hd·-\1Ct~
H30~ ~ -c-= Jt-1--H
I
CH 3
6.o!.. ,l.2J DJt ) 012~01, -Ci').2 H30+
.-+--.
I I 011
3
- Tr{),jdl--'\'c.. Alc_o\.-io).S
OH 01-1 Get- E t:-K ~~
R-c-or1
I
HJ!)+
\ I 1 Me.
ol-\ 011 OH
, R . H::/dl-1:)½s ,s cf Eth e..r
R-o -R 113 0 -+ ~ .2R - 011
·- --
'3- Epo -< id es -E- to
C 2. H:2-201 , -+ H2..o 1">"-,o,\t9'5 ~
1
2CG H 12..0£
( 6\--f,1.06 1-11..0 '2.:;t(\'"J c.s5 2c,1-1s-or1 +
rd
ef G·pt :c.-ia-m1 <'/ \t1 <N °11
-+-
< esbe.r . o e.i-
3 . Hjdl "D'3 €.h in pr<.<ieric.e.. of r-li c_an ~~ c.e .
'2.C o2._ ma.5.5 -
of Ru-(. B .p l-:«X l"no\ .
Cc. -.-60>(..'.:Jlic. :l '"O'\.<P in r~s s~» CE'..
Co,,..,p\c.x . (_ 5 H 1cP :1\/\..,o l-1) ~ 0
)1) Av,OH
t..o it;\.i rJq_ v,
~. R.~d.,t.c.b'Ch-\ of Es t~ 1 l3ronci,;"'jo<' _I_
Gco )1 i5 ca\l e_d '2,o vio lt-6 lwn c Q~J.,..,
Esce.r- . ef B -pt .
2 Cl. 115 011 -i-2CoLf
~ . (3 _)'-' Hud
J 1-o
l>_js1:.S
'2.j>Y \ Q Se.. -..>
7 - l\lc.ohc,ls a~ "hG L.\. ~l !:uLvo.H:1'.s
~t-o /o "/.a koh ol c:\ . Ac i d 1'c h:,d v-o~ s,s . Li b-YI\..O !::est
R-l -o -t- Jfi_o ~ R-t -mi+ 17{ 1oH
- Aci ~c... ck~ ~c t-e.-r-
l
C.:,<v.h/ =yc J Hz.So~
ti°',) -t
lo,,, _Hl~o ~ b . B;s k h'j d~ ~ is c_s.,poni!l~a R-O H ~R -or l~-- \-\- 1
l O 0°/o f u.re. l t I
R-C11 - o - R1 .L r-Ja c::i\ 1~"n'-c.- oNq -t'R -DH .
11 l
1 5
'! c.
, 11 "l,oyt
t-o <,°f.
NQ" t R-£ ."5/::-c.t>i/i ~a ~
rc ct /f;ed s pld t .
c..10.s.s tfi c.q t::i~s · 0. . Ald&_\..,\jck Ond kebo~ :
½. Po½ h'j dric. Al Loh ob '. Gr
71.e..se... cn-e. cf +wo t~pe.s I
i 0)1
~ Ll1 3 - CJ1-i_· 0hlM~
c.Jh-011
O>j
\ . A!c.,ohol f>= lf -011 g~p 1'sc.onneLteJ
-t"o Sid e- chain Dr al l<.:tL g rtr\,.p . t\1
Ex . ,,Z,,, ~011 v1 OH
1-1 OH
'2. . P he-nol.5 .:- l f
-or1 ~rtf\.\p is dire.ct~
cJ1 1-o r1 CH1-~;CL
Co nne.ct::e.d.. to be.n ·2..e_Y\.Q.. rihB ·
Ex : Cs), ©-oH GMP :
0
c . t3'j 1-1:.i,-,'.3 ~ster-
ci
m,
ALwhol.5 1. F r-o tn A*e..ri e.s C.11 r C11 - O - C.)1 He M'.) l:>..- '> I
~ H3 ot- He -C-H~
- 12,Qs ed.. oh no . cf - or1'jYO'\..tp5 a. . AC..I d - C q tr>.½ <:>ed \., 'j d re,,_ b' C/Y) ' .
c{. [3~ Ltsin3 Epu-.,;i des 1-4.
, I . Monoh-:fd.-,'c. cdcohol..s : b . 1-f B O re o. c.t-icn--,
q . lo.,, c-11ron l$c.pv· pr-imar~ c.. oH D 1--e"'t t-im
('.) 11
C..11 3 - C ti ::-c.ri,2 H -t I
.:.. CHrCH2. -o H 30 ') (YJ?, -C.r\- Cf13
b :r:::. C.t1.3 - 01-a ri
I
I HBO
01.,3 C..onditicrn.s :
0-'3 I
C · 3' .::> 013 - C. - Ori t e. Reo.rro.n t. Pi-o~cC:-.
C\ . Cc. r b o C<:1 b 'a-n
'
C..\13 b. ~ 11 ru. le.
(_jc. ~ ·c:. Ti-ans; b'an
-<. Dih~dric. Ak.o'nal.5
a . \/icinaL[1 1.23 > C>-12- c.n2 '--
S1.:-q l:e
X A-11 h.tl e +. 61:1 L{S i"~ c jO.nicle
C!;Jc.u.'r_ Hu.rcur,'c.
l
0)1
I
01-1 1-lc.e..t-o..t::e..i'O'h
X Ml'i.lle.
R-c ==t-1 Hd·-\1Ct~
H30~ ~ -c-= Jt-1--H
I
CH 3
6.o!.. ,l.2J DJt ) 012~01, -Ci').2 H30+
.-+--.
I I 011
3
- Tr{),jdl--'\'c.. Alc_o\.-io).S
OH 01-1 Get- E t:-K ~~
R-c-or1
I
HJ!)+
\ I 1 Me.
ol-\ 011 OH
, R . H::/dl-1:)½s ,s cf Eth e..r
R-o -R 113 0 -+ ~ .2R - 011
·- --
'3- Epo -< id es -E- to
C 2. H:2-201 , -+ H2..o 1">"-,o,\t9'5 ~
1
2CG H 12..0£
( 6\--f,1.06 1-11..0 '2.:;t(\'"J c.s5 2c,1-1s-or1 +
rd
ef G·pt :c.-ia-m1 <'/ \t1 <N °11
-+-
< esbe.r . o e.i-
3 . Hjdl "D'3 €.h in pr<.<ieric.e.. of r-li c_an ~~ c.e .
'2.C o2._ ma.5.5 -
of Ru-(. B .p l-:«X l"no\ .
Cc. -.-60>(..'.:Jlic. :l '"O'\.<P in r~s s~» CE'..
Co,,..,p\c.x . (_ 5 H 1cP :1\/\..,o l-1) ~ 0
)1) Av,OH
t..o it;\.i rJq_ v,
~. R.~d.,t.c.b'Ch-\ of Es t~ 1 l3ronci,;"'jo<' _I_
Gco )1 i5 ca\l e_d '2,o vio lt-6 lwn c Q~J.,..,
Esce.r- . ef B -pt .
2 Cl. 115 011 -i-2CoLf
~ . (3 _)'-' Hud
J 1-o
l>_js1:.S
'2.j>Y \ Q Se.. -..>
7 - l\lc.ohc,ls a~ "hG L.\. ~l !:uLvo.H:1'.s
~t-o /o "/.a koh ol c:\ . Ac i d 1'c h:,d v-o~ s,s . Li b-YI\..O !::est
R-l -o -t- Jfi_o ~ R-t -mi+ 17{ 1oH
- Aci ~c... ck~ ~c t-e.-r-
l
C.:,<v.h/ =yc J Hz.So~
ti°',) -t
lo,,, _Hl~o ~ b . B;s k h'j d~ ~ is c_s.,poni!l~a R-O H ~R -or l~-- \-\- 1
l O 0°/o f u.re. l t I
R-C11 - o - R1 .L r-Ja c::i\ 1~"n'-c.- oNq -t'R -DH .
11 l
1 5
'! c.
, 11 "l,oyt
t-o <,°f.
NQ" t R-£ ."5/::-c.t>i/i ~a ~
rc ct /f;ed s pld t .
