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Organic Chemistry II Exam 2 with verified answers

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Institution Organic Chemistry II
Module Organic Chemistry II
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Organic Chemistry II Exam 2 with verified answers

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Organic Chemistry II Exam 2 with verified answers
| | | | | | |




In |ketones |and |aldehydes, |the |C=O |carbonyl |has |a |partial |__________ |charge |on |the |C |and |a
|partial |_________ |charge |on |the |O |- |** |VERIFIED |ANSWERS |✔✔positive; |negative




Based |on |respective |partial |charges, |nucleophiles |are |drawn |to |the |_ |atom |and |electrophiles
|are |drawn |to |the |_ |atom |in |a |C=O |bond. |- |** |VERIFIED |ANSWERS |✔✔C; |O




When |naming |aldehydes |and |ketones, |start |with |the |end |________ |(closest |or |furthest) |from
|the |carbonyl |- |** |VERIFIED |ANSWERS |✔✔closest




Aldehydes |end |with |-__ |and |ketones |end |with |-____ |- |** VERIFIED |ANSWERS
| ✔✔al; |one
|




Synthesis |of |aldehydes/ketones: |HO-CH₂-R |→ |R-C=O. |What |goes |on |the |reaction |arrow? |-
|** |VERIFIED |ANSWERS |✔✔PCC




Synthesis |of |aldehydes/ketones: |H-C-(triple |bond)C-R |→ |

R-C(O)-R. |What |goes |on |the |reaction |arrow? |(1. |and |2.) |- |** VERIFIED |ANSWERS
|


|✔✔1)R₂BH



2)H₂O₂, |OH⁻


R-C(OH)-R' |--> |R-C(O)-R'. |What |goes |on |the |reaction |arrow? |- |** VERIFIED |ANSWERS
|


|✔✔Na₂Cr₂O₇




R-CC-R |--> |R-C(O)-R. |What |goes |on |the |reaction |arrow? |(1. |and |2.) |- |** |VERIFIED
|ANSWERS |✔✔H₂SO₄; |HgSO₄




Nucleophilic |Addition: |___________- |turns |an |aldehyde |or |ketone |into |a |geminal |diol |- |**
|VERIFIED |ANSWERS |✔✔hydration

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