TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Pageh1
,Chapter 1 Structure and Bonding
h h h h
Chapter 2 Acids and Bases
h h h h
Chapter 3 Introduction to Organic Molecules and Functional Groups
h h h h h h h h
Chapter 4 Alkanes
h h
Chapter 5 Stereochemistry
h h
Chapter 6 Understanding Organic Reactions
h h h h
Chapter 7 Alkyl Halides and Nucleophilic Substitution
h h h h h h
Chapter 8 Alkyl Halides and Elimination Reactions
h h h h h h
Chapter 9 Alcohols, Ethers, and Related Compounds
h h h h h h
Chapter 10 Alkenes and Addition Reactions
h h h h h
Chapter 11 Alkynes and Synthesis
h h h h
Chapter 12 Oxidation and Reduction
h h h h
Spectroscopy A Mass Spectrometry
h h h
Spectroscopy B Infrared Spectroscopy
h h h
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
h h h h h
Chapter 13 Radical Reactions
h h h
Chapter 14 Conjugation, Resonance, and Dienes
h h h h h
Chapter 15 Benzene and Aromatic Compounds
h h h h h
Chapter 16 Reactions of Aromatic Compounds
h h h h h
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxid
h h h h h h h h
ation and Reduction
h h
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
h h h h h
Chapter 19 Carboxylic Acids and Nitriles
h h h h h
Chapter 20 Carboxylic Acids and Their Derivatives-
h h h h h h
Nucleophilic Acyl Substitution
h h h
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
h h h h h h h h h
Chapter 22 Carbonyl Condensation Reactions
h h h h
Chapter 23 Amines
h h
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
h h h h h h h
Chapter 25 Pericyclic Reactions
h h h
Chapter 26 Carbohydrates
h h
Chapter 27 Amino Acids and Proteins
h h h h h
Chapter 28 Synthetic Polymers
h h h
Chapter 29 Lipids (Available online)
h h h h
Pageh2
, Chapter 1: Structure and Bonding
h h h h
1. Whathishthehground-
statehelectronichconfigurationhofhahcarbonhatom?hA)h 1s2,h2s2,h2p5
B)h 1s2,h2s2,h2p2 C)h 1s2,h2s2,h2p6 D)h 1s2,h2s2,h2p4
2. Whathishthehground-
statehelectronichconfigurationhofhahfluorinehatom?hA)h 1s2,h2s2,h2p2
B)h 1s2,h2s2,h2p3 C)h 1s2,h2s2,h2p4 D)h 1s2,h2s2,h2p5
3. Whathishthehground-
statehelectronichconfigurationhofhahmagnesiumhcationh(Mg2+)?hA) 1s2,h2s2,h2p6
C) 1s2,h2s2,h2p6,h3s2
B) 1s2,h2s2,h2p6,h3s1 D) 1s2,h2s2,h2p6,h3s2,h3p2
4. Whathishthehground-statehelectronichconfigurationhofhahchlorinehanionh(Cl—
)?hA) 1s2,h2s2,h2p6 C) 1s2,h2s2,h2p6,h3s2,h3p5
B) 1s2,h2s2,h2p6,h3s2,h3p6 D) 1s2,h2s2,h2p6,h3s2,h3p4
5. Whichhofhthehfollowinghstatementshabouthvalencehelectronshishtrue?
A) Theyharehthehmosthtightlyhheldhelectrons.
B) Theyhdohnothparticipatehinhchemicalhreactions.
Pageh3
, Chapterh1:hStructurehandhBonding
C) Theyharehthehoutermosthelectrons.
D) Theyhrevealhthehperiodhnumberhofhahsecond-rowhelement.
6. Whichhofhthehfollowinghstatementshabouthbondinghishtrue?
A) Covalenthbondshresulthfromhthehtransferhofhelectronshfromhonehelementhtohanother.
B) Ionichbondshresulthfromhthehtransferhofhelectronshfromhahmetalhtohahnon-metal.
C) Ionichbondshresulthfromhthehsharinghofhelectronshbetweenhtwohnon-metals.
D) Covalenthbondshresulthfromhthehsharinghofhelectronshbetweenhtwohmetals.
7. Whichhofhthehfollowinghwouldhyouhexpecthtohhavehionichbonds?
A) CO B)h FBr C)h NF3 D)h NaCl
8. Whichhofhthehfollowinghmoleculeshhashnonpolarhcovalenthbonds?
A) HCl B)h N2 C)h CHCl3 D)h NO
9. Whichhofhthehfollowinghmoleculeshcontainhbothhcovalenthandhionichbonds?
A) I,hII B)h I,hIV C)h II,hIII D)hII,hIV
10. Arrangehthehfollowinghbondshinhdecreasinghorderhofhionichcharacter,hputtinghthehmosthi
onichfirst.
A) Ih>hIIh>hIIIh>hIV C) IVh>hIIIh>hIIh>hI
B) IVh>hIIh>hIh>hIII D) IVh>hIIh>hIIIh>hI
11. Whichhofhthehfollowinghstatementshcorrectlyhdescribeshthehtypicalhnumberhofhbondshforhc
arbon,hnitrogen,handhoxygenhinhmosthneutralhorganichmolecules?
A) Carbonhformsh4hcovalenthbonds,hnitrogenhformsh2hcovalenthbondshandhoxygenhformsh3
hcovalenth bonds.
B) Carbonhformsh4hcovalenthbonds,hnitrogenhformsh3hcovalenthbondshandhoxygenhformsh2
hcovalenth bonds.
Pageh4
Smith / All Chapters 1 - 29 / Full Complete
Pageh1
,Chapter 1 Structure and Bonding
h h h h
Chapter 2 Acids and Bases
h h h h
Chapter 3 Introduction to Organic Molecules and Functional Groups
h h h h h h h h
Chapter 4 Alkanes
h h
Chapter 5 Stereochemistry
h h
Chapter 6 Understanding Organic Reactions
h h h h
Chapter 7 Alkyl Halides and Nucleophilic Substitution
h h h h h h
Chapter 8 Alkyl Halides and Elimination Reactions
h h h h h h
Chapter 9 Alcohols, Ethers, and Related Compounds
h h h h h h
Chapter 10 Alkenes and Addition Reactions
h h h h h
Chapter 11 Alkynes and Synthesis
h h h h
Chapter 12 Oxidation and Reduction
h h h h
Spectroscopy A Mass Spectrometry
h h h
Spectroscopy B Infrared Spectroscopy
h h h
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
h h h h h
Chapter 13 Radical Reactions
h h h
Chapter 14 Conjugation, Resonance, and Dienes
h h h h h
Chapter 15 Benzene and Aromatic Compounds
h h h h h
Chapter 16 Reactions of Aromatic Compounds
h h h h h
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxid
h h h h h h h h
ation and Reduction
h h
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
h h h h h
Chapter 19 Carboxylic Acids and Nitriles
h h h h h
Chapter 20 Carboxylic Acids and Their Derivatives-
h h h h h h
Nucleophilic Acyl Substitution
h h h
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
h h h h h h h h h
Chapter 22 Carbonyl Condensation Reactions
h h h h
Chapter 23 Amines
h h
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
h h h h h h h
Chapter 25 Pericyclic Reactions
h h h
Chapter 26 Carbohydrates
h h
Chapter 27 Amino Acids and Proteins
h h h h h
Chapter 28 Synthetic Polymers
h h h
Chapter 29 Lipids (Available online)
h h h h
Pageh2
, Chapter 1: Structure and Bonding
h h h h
1. Whathishthehground-
statehelectronichconfigurationhofhahcarbonhatom?hA)h 1s2,h2s2,h2p5
B)h 1s2,h2s2,h2p2 C)h 1s2,h2s2,h2p6 D)h 1s2,h2s2,h2p4
2. Whathishthehground-
statehelectronichconfigurationhofhahfluorinehatom?hA)h 1s2,h2s2,h2p2
B)h 1s2,h2s2,h2p3 C)h 1s2,h2s2,h2p4 D)h 1s2,h2s2,h2p5
3. Whathishthehground-
statehelectronichconfigurationhofhahmagnesiumhcationh(Mg2+)?hA) 1s2,h2s2,h2p6
C) 1s2,h2s2,h2p6,h3s2
B) 1s2,h2s2,h2p6,h3s1 D) 1s2,h2s2,h2p6,h3s2,h3p2
4. Whathishthehground-statehelectronichconfigurationhofhahchlorinehanionh(Cl—
)?hA) 1s2,h2s2,h2p6 C) 1s2,h2s2,h2p6,h3s2,h3p5
B) 1s2,h2s2,h2p6,h3s2,h3p6 D) 1s2,h2s2,h2p6,h3s2,h3p4
5. Whichhofhthehfollowinghstatementshabouthvalencehelectronshishtrue?
A) Theyharehthehmosthtightlyhheldhelectrons.
B) Theyhdohnothparticipatehinhchemicalhreactions.
Pageh3
, Chapterh1:hStructurehandhBonding
C) Theyharehthehoutermosthelectrons.
D) Theyhrevealhthehperiodhnumberhofhahsecond-rowhelement.
6. Whichhofhthehfollowinghstatementshabouthbondinghishtrue?
A) Covalenthbondshresulthfromhthehtransferhofhelectronshfromhonehelementhtohanother.
B) Ionichbondshresulthfromhthehtransferhofhelectronshfromhahmetalhtohahnon-metal.
C) Ionichbondshresulthfromhthehsharinghofhelectronshbetweenhtwohnon-metals.
D) Covalenthbondshresulthfromhthehsharinghofhelectronshbetweenhtwohmetals.
7. Whichhofhthehfollowinghwouldhyouhexpecthtohhavehionichbonds?
A) CO B)h FBr C)h NF3 D)h NaCl
8. Whichhofhthehfollowinghmoleculeshhashnonpolarhcovalenthbonds?
A) HCl B)h N2 C)h CHCl3 D)h NO
9. Whichhofhthehfollowinghmoleculeshcontainhbothhcovalenthandhionichbonds?
A) I,hII B)h I,hIV C)h II,hIII D)hII,hIV
10. Arrangehthehfollowinghbondshinhdecreasinghorderhofhionichcharacter,hputtinghthehmosthi
onichfirst.
A) Ih>hIIh>hIIIh>hIV C) IVh>hIIIh>hIIh>hI
B) IVh>hIIh>hIh>hIII D) IVh>hIIh>hIIIh>hI
11. Whichhofhthehfollowinghstatementshcorrectlyhdescribeshthehtypicalhnumberhofhbondshforhc
arbon,hnitrogen,handhoxygenhinhmosthneutralhorganichmolecules?
A) Carbonhformsh4hcovalenthbonds,hnitrogenhformsh2hcovalenthbondshandhoxygenhformsh3
hcovalenth bonds.
B) Carbonhformsh4hcovalenthbonds,hnitrogenhformsh3hcovalenthbondshandhoxygenhformsh2
hcovalenth bonds.
Pageh4
