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AQA A level Chemistry 3.1.8-Thermodynamics

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AQA A level Chemistry 3.1.8-Thermodynamics

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AQA A level Chemistry 3.1.8-
Thermodynamics
What are standard conditions? - 298K/25°C

100kPa/1 atm

1 moldm-3



Enthalpy change of formation - The enthalpy change when 1 mole of a compound
is formed from its constituent elements under standard conditions, with all
reactants and products in their standard states.



Enthalpy change of combustion - The enthalpy change when 1 mole of a
substance is burned completely in oxygen.



Enthalpy change of atomisation - The enthalpy change that accompanies the
formation of 1 mole of gaseous atoms from the element in its standard state.



First ionisation enthalpy - The enthalpy change when 1 mole of gaseous atoms
loses 1 electron per atom to form 1 mole of gaseous 1+ ions.



Second ionisation enthalpy - The enthalpy change when 1 mole of gaseous 1+ ions
loses 1 electron per atom to form 1 mole of gaseous 2+ ions.

, AQA A level Chemistry 3.1.8-
Thermodynamics
First electron affinity - The enthalpy change when 1 mole gaseous atoms gains 1
electron per atom to form 1 mole of gaseous 1- ions.



Second electron affinity - The enthalpy change when 1 mole of gaseous 1- ions
gains 1 electron per atom to form 1 mole of gaseous 2- ions.



Mean bond enthalpy - The enthalpy change when 1 mole of gaseous molecules
each breaks a covalent bond to form 2 gaseous ions or free radicals.



Lattice enthalpy of formation - The enthalpy change when 1 mole of a solid ionic
compound is formed from its gaseous ions.



Lattice enthalpy of dissociation - The enthalpy change when 1 mole of a solid ionic
compound dissociates into its gaseous ions.



Enthalpy of hydration - The enthalpy change when 1 mole of gaseous ions
dissolves completely in water.

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