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Chapter 16 - Alcohols, Diols, and Thiols (Test Bank)

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Organic Chemistry 10th Edition by Francis Carey - Test Bank

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1. What is the product of the following reaction?




A. cyclohexanol
B. cyclohexane
C. cyclohexene
D. 1,2-cyclohexanediol

Bloom's Level: 3. Apply
Chapter: 16
Difficulty: Medium
Gradable: automatic
Section: 16.02
Subtopic: Reactions of aldehydes and ketones acting as electrophiles
Topic: Aldehydes and Ketones

2 What is the product of the following reactions?
.




A. CH3CH2CH2CH2CH2CO2H
B.CH3CH2CH2CH2CH2CH2OH
C.CH3CH2CH2CH2CH=CH2
D. CH3CH2CH2CH2CH2CH3

Bloom's Level: 3. Apply
Chapter: 16
Difficulty: Medium
Gradable: automatic
Section: 16.02
Subtopic: Reactions of aldehydes and ketones acting as electrophiles
Topic: Aldehydes and Ketones




16-1
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

,3. Which of the following cannot be made by the reduction of a ketone or aldehyde with NaBH 4 in methanol?

A. 1-butanol
B. 2-butanol
C. 2-methyl-1-propanol
D. 2-methyl-2-propanol

Accessibility: Keyboard Navigation
Bloom's Level: 4. Analyze
Chapter: 16
Difficulty: Hard
Gradable: automatic
Section: 16.02
Subtopic: Reactions of aldehydes and ketones acting as electrophiles
Topic: Aldehydes and Ketones


4. Which of the following methods will NOT produce an alcohol as the product?

A. acid-catalyzed hydration of an alkene
B. hydroboration-oxidation of an alkene
C. reaction of a Grignard reagent with an aldehyde
D. oxidation of an aldehyde

Accessibility: Keyboard Navigation
Bloom's Level: 2. Understand
Chapter: 16
Difficulty: Easy
Gradable: automatic
Section: 16.01
Subtopic: Reactions of alcohols
Topic: Alcohols

5. In general, the reduction of a ketone to an alcohol can be accomplished by all of the following except one. Which one
will not reduce a ketone?

A. H2/Pt
B. HIO4
C. LiAlH4
D. NaBH4

Accessibility: Keyboard Navigation
Bloom's Level: 1. Remember
Chapter: 16
Difficulty: Easy
Gradable: automatic
Section: 16.02
Subtopic: Reactions of aldehydes and ketones acting as electrophiles
Topic: Aldehydes and Ketones




16-2
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

, 6. 6 What is the product of the following reaction?
.




A. A
B. B
C. C
D. D

Bloom's Level: 3. Apply
Chapter:
16
Difficulty: Medium
Gradable: automatic
Section:
16.02
Subtopic: Reactions of aldehydes and ketones acting as electrophiles
Topic: Aldehydes and Ketones

7. Which one of the following is not readily oxidized by K2Cr2O7 in H2SO4/H2O?

A. n-butyl alcohol
B. isobutyl alcohol
C. sec-butyl alcohol
D. tert-butyl alcohol

Accessibility: Keyboard Navigation
Bloom's Level: 3. Apply
Chapter:
16
Difficulty: Medium
Gradable: automatic
Section:
16.09
Subtopic: Reactions of
alcohols
Topic:
Alcohols




16-3
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

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