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Summary

Samenvatting competitieve vs substitutiereacties

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In dit document worden de verschillen tussen de competitieve en substitutiereacties in de organische chemie overlopen. Het geeft een goed overzicht over de beide reacties.

Institution
Universiteit Gent (UGent)
Course
Organische Chemie

Content preview

Samenvatting organische chemie

Competitie tussen substitutie en eliminatie
(9.8, 9.9 en 9.10 in cursus)

Primaire halogeenalkanen => E2 of Sn2
Tertiaire en secundaire halogeenalkanen => E2, Sn1 of E1
- Goed nucleofiel/sterke base => E2
- Zwakke base => E1 of Sn1

Sn2/E2 reactie?
Sn2; primair > secundair > teriair
E2; teriair > secundair > primair

- Primair halogeenalkaan = Sn2
- Sterisch gehinderd primair halogeenalkaan = E2
- Secundair halogeenalkaan = afh sterkte en omvang Nucleofiel/Base:
Hoe sterker en volumineuzer base = E2
Hogere temperaturen = meer E2
- Tertiaire halogeenalkanen = E2

Sn1/E1 reactie?
Aanval van nucleofiel op cbc => substitutieprod
Verlies van proton van het cbc => eliminatieprod

Primaire halogeenalkanen ondergaan geen Sn1 of E1

Als het een geladen nucleofiel of base is = E1
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Institution
Universiteit Gent (UGent)
Study
Farmaceutische Wetenschappen
Course
Organische Chemie

Document information

Uploaded on
January 14, 2022
Number of pages
1
Written in
2021/2022
Type
SUMMARY

Subjects

  • competitiereacties
  • substitutiereacties
  • organische chemie
  • farmacie
  • annemieke madder
  • samenvatting
  • universiteit gent
  • farmaceutische wetenschappen
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