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AQA A-Level Chemistry Notes: Atomic Structure (3.1.1) – Full Revision Guid

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Comprehensive, concise, and beautifully organized handwritten revision notes for AQA A-Level Chemistry: 3.1.1 Atomic Structure. These high-yield summary grid notes cover everything required for exam success, including: Atomic Structure & Fundamentals: History of atomic models (plum pudding to Rutherford nuclear model), subatomic particles (protons, neutrons, electrons), mass and atomic numbers, isotopes, and relative atomic mass (A_r) definitions. Time of Flight (TOF) Mass Spectrometry: Clear 5-step process breakdown (Ionisation, Acceleration, Ion drift, Detection, Analysis), calculations, isotope abundances, and Chlorine (Cl_2) peak ratio analysis. Electron Configuration & Orbitals: s, p, d, f orbital types, shapes, capacities, Aufbau filling principle, Hund's rule, Pauli exclusion principle, full orbital box diagrams, and transition metal exceptions (Cr and Cu). Ionisation Energy (IE): Definition equations, successive IE trends/shell evidence, periodicity trends across periods and down groups, plus detailed explanations for the Group 2 to 3 (Mg to Al) and Group 5 to 6 (P to S) anomalies.

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AQA Chem · 3.1.1 p.1


atomic structure
Models change as evidence changes: plum pudding → nuclear / electron shell model (Rutherford scattering, 1911).



nucleus Shell model (Li shown)
Small, dense nucleus of protons + neutrons : positive, holds almost all the mass
Electrons orbit in shells
Neutral atom: electrons = protons
shell Max per shell = 2n² (shell 2 = 2×4 = 8). Fill each shell before the next.


Proton Neutron Electron
Relative charge +1 0 −1
Relative mass 1 1 1/1840

Mass & atomic number Isotopes
A mass number = protons + neutrons Same Z, different neutrons → different A
Z atomic number = protons Same chemistry (same electron config), different
N: Z = 7, A = 14 → 7 p, 7 e⁻, 14 − 7 = 7 n physical properties
H: 1p 0n · Deuterium: 1p 1n · Tritium: 1p 2n

Relative atomic mass, Aᵣ
of a C-12 atom)
Aᵣ = mean mass of an atom of the element ÷ (1/12 × mass
t
takes the relative abundance of each isotope into accoun
Ions form when an atom loses or gains electrons → overall charge.




atomic structure ·

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