Tuesday 9 June 2026 – Morning
A Level Chemistry A
H432/02 Synthesis and analytical techniques
Time allowed: 2 hours 15 minutes
You must have:
GCE
*
• the Data Sheet for Chemistry A
You can use:
• a ruler (cm/mm)
• a scientific or graphical calculator
Chemistry A
• an HB pencil
H432/02: Synthesis and analytical techniques
* H 4 3 2 0 2 *
*
Please write clearly in black ink. Do not write in the barcodes. A Level
Centre number Candidate number
Mark Scheme for June 2026
First name(s)
Last name
INSTRUCTIONS
• Use black ink. You can use an HB pencil, but only for graphs and diagrams.
• Write your answer to each question in the space provided. If you need extra space use
the lined page at the end of this booklet. The question numbers must be clearly shown.
• Answer all the questions.
• Where appropriate, your answer should be supported with working. Marks might be
given for using a correct method, even if your answer is wrong.
INFORMATION
• The total mark for this paper is 100.
• The marks for each question are shown in brackets [ ].
• Quality of extended response will be assessed in questions marked with an asterisk (*).
• This document has 32 pages.
ADVICE
• Read each question carefully before you start your answer.
Cambridge 2026 [601/5255/2] Cambridge is an exempt Charity
DC (EV/SG) 363916/5 Turn over
Cambridge
, 2
Section A
You should spend a maximum of 20 minutes on this section.
Cambridge is a leading UK awarding body, providing a wide range of qualifications to
Write your answer to each question in the box provided.
meet the needs of candidates of all ages and abilities. Cambridge qualifications include
1 A non-cyclic alkene has the molecular formula C6H8. AS/A Levels, Diplomas, GCSEs, Cambridge Nationals, Cambridge Technicals, Functional Skills,
Key Skills, Entry Level qualifications, NVQs and vocational qualifications in areas such as IT,
What is the number of π-bonds in one molecule of C6H8? business, languages, teaching/training, administration and secretarial skills.
A 2 It is also responsible for developing new specifications to meet national requirements and the
needs of students and teachers. Cambridge is a not-for-profit organisation; any surplus
B 3 made is invested back into the establishment to help towards the development of qualifications
and support, which keep pace with the changing needs of today’s society.
C 4
This mark scheme is published as an aid to teachers and students, to indicate the requirements
D 6 of the examination. It shows the basis on which marks were awarded by examiners. It does not
indicate the details of the discussions which took place at an examiners’ meeting before marking
Your answer commenced.
[1]
All examiners are instructed that alternative correct answers and unexpected approaches in
candidates’ scripts must be given marks that fairly reflect the relevant knowledge and skills
2 What is a correct name of the compound below? demonstrated.
H3C Cl Mark schemes should be read in conjunction with the published question papers and the report
on the examination.
C C
F CH3
Cambridge 2026
A cis-1,2-dimethyl-1-chloro-2-fluoroethene
B E-2-chloro-3-fluorobut-2-ene
C trans-1,2-dimethyl-1-chloro-2-fluoroethene
D Z-2-chloro-3-fluorobut-2-ene
Your answer
[1]
Cambridge 2026
Cambridge
, H432/02 Mark Scheme June 2026
3
3 Nitrobenzene reacts with Br2 in the presence of a halogen carrier.
MARKING INSTRUCTIONS
NO2 PREPARATION FOR MARKING
RM ASSESSOR
1. Make sure that you have accessed and completed the relevant training packages for on-screen marking: RM Assessor Assessor Online Training;
Nitrobenzene Essential Guide to Marking.
What is the most likely organic product? 2. Make sure that you have read and understood the mark scheme and the question paper for this unit. These are posted on the RM Cambridge
Assessment Support Portal
3. Log-in to RM Assessor and mark the required number of practice responses (“scripts”) and the number of required standardisation responses.
A Br NO2
MARKING
Br 1. Mark strictly to the mark scheme.
2. Marks awarded must relate directly to the marking criteria.
B Br NO2
3. The schedule of dates is very important. It is essential that you meet the RM Assessor 50% and 100% (traditional 40% Batch 1 and 100% Batch 2)
deadlines. If you experience problems, you must contact your Team Leader (Supervisor) without delay.
Br 4. If you are in any doubt about applying the mark scheme, consult your Team Leader by telephone or the RM Assessor messaging system, or by email.
Br 5. Crossed Out Responses
Where a candidate has crossed out a response and provided a clear alternative then the crossed out response is not marked. Where no alternative
response has been provided, examiners may give candidates the benefit of the doubt and mark the crossed out response where legible.
C
NO2
Rubric Error Responses – Optional Questions
Where candidates have a choice of question across a whole paper or a whole section and have provided more answers than required, then all responses
are marked and the highest mark allowable within the rubric is given. Enter a mark for each question answered into RM assessor, which will select the
Br Br
2
D
NO2
Your answer
[1]
Cambridge 2026 Turn over
, H432/02 Mark Scheme June 2026
4
4 Complete combustion of 2.00 g of a hydrocarbon forms 2.57 g of water. highest mark from those awarded. (The underlying assumption is that the candidate has penalised themselves by attempting more questions than
necessary in the time allowed.)
What is the empirical formula of the hydrocarbon?
Multiple Choice Question Responses
A CH
When a multiple choice question has only a single, correct response and a candidate provides two responses (even if one of these responses is correct),
B CH2 then no mark should be awarded (as it is not possible to determine which was the first response selected by the candidate).
When a question requires candidates to select more than one option/multiple options, then local marking arrangements need to ensure consistency of
C CH3 approach.
D CH4 Contradictory Responses
When a candidate provides contradictory responses, then no mark should be awarded, even if one of the answers is correct.
Your answer
[1] Short Answer Questions (requiring only a list by way of a response, usually worth only one mark per response)
Where candidates are required to provide a set number of short answer responses then only the set number of responses should be marked. The
response space should be marked from left to right on each line and then line by line until the required number of responses have been considered. The
5 What is the number of chiral centres in the molecule below? remaining responses should not then be marked. Examiners will have to apply judgement as to whether a ‘second response’ on a line is a development
OH of the ‘first response’, rather than a separate, discrete response. (The underlying assumption is that the candidate is attempting to hedge their bets
CH3 and therefore getting undue benefit rather than engaging with the question and giving the most relevant/correct responses.)
Short Answer Questions (requiring a more developed response, worth two or more marks)
CH3 If the candidates are required to provide a description of, say, three items or factors and four items or factors are provided, then mark on a similar basis
– that is downwards (as it is unlikely in this situation that a candidate will provide more than one response in each section of the response space.)
Longer Answer Questions (requiring a developed response)
Where candidates have provided two (or more) responses to a medium or high tariff question which only required a single (developed) response and
O
not crossed out the first response, then only the first response should be marked. Examiners will need to apply professional judgement as to whether
the second (or a subsequent) response is a ‘new start’ or simply a poorly expressed continuation of the first response.
A 3
B 4
C 5
D 6
3
Your answer
[1]
Cambridge 2026
A Level Chemistry A
H432/02 Synthesis and analytical techniques
Time allowed: 2 hours 15 minutes
You must have:
GCE
*
• the Data Sheet for Chemistry A
You can use:
• a ruler (cm/mm)
• a scientific or graphical calculator
Chemistry A
• an HB pencil
H432/02: Synthesis and analytical techniques
* H 4 3 2 0 2 *
*
Please write clearly in black ink. Do not write in the barcodes. A Level
Centre number Candidate number
Mark Scheme for June 2026
First name(s)
Last name
INSTRUCTIONS
• Use black ink. You can use an HB pencil, but only for graphs and diagrams.
• Write your answer to each question in the space provided. If you need extra space use
the lined page at the end of this booklet. The question numbers must be clearly shown.
• Answer all the questions.
• Where appropriate, your answer should be supported with working. Marks might be
given for using a correct method, even if your answer is wrong.
INFORMATION
• The total mark for this paper is 100.
• The marks for each question are shown in brackets [ ].
• Quality of extended response will be assessed in questions marked with an asterisk (*).
• This document has 32 pages.
ADVICE
• Read each question carefully before you start your answer.
Cambridge 2026 [601/5255/2] Cambridge is an exempt Charity
DC (EV/SG) 363916/5 Turn over
Cambridge
, 2
Section A
You should spend a maximum of 20 minutes on this section.
Cambridge is a leading UK awarding body, providing a wide range of qualifications to
Write your answer to each question in the box provided.
meet the needs of candidates of all ages and abilities. Cambridge qualifications include
1 A non-cyclic alkene has the molecular formula C6H8. AS/A Levels, Diplomas, GCSEs, Cambridge Nationals, Cambridge Technicals, Functional Skills,
Key Skills, Entry Level qualifications, NVQs and vocational qualifications in areas such as IT,
What is the number of π-bonds in one molecule of C6H8? business, languages, teaching/training, administration and secretarial skills.
A 2 It is also responsible for developing new specifications to meet national requirements and the
needs of students and teachers. Cambridge is a not-for-profit organisation; any surplus
B 3 made is invested back into the establishment to help towards the development of qualifications
and support, which keep pace with the changing needs of today’s society.
C 4
This mark scheme is published as an aid to teachers and students, to indicate the requirements
D 6 of the examination. It shows the basis on which marks were awarded by examiners. It does not
indicate the details of the discussions which took place at an examiners’ meeting before marking
Your answer commenced.
[1]
All examiners are instructed that alternative correct answers and unexpected approaches in
candidates’ scripts must be given marks that fairly reflect the relevant knowledge and skills
2 What is a correct name of the compound below? demonstrated.
H3C Cl Mark schemes should be read in conjunction with the published question papers and the report
on the examination.
C C
F CH3
Cambridge 2026
A cis-1,2-dimethyl-1-chloro-2-fluoroethene
B E-2-chloro-3-fluorobut-2-ene
C trans-1,2-dimethyl-1-chloro-2-fluoroethene
D Z-2-chloro-3-fluorobut-2-ene
Your answer
[1]
Cambridge 2026
Cambridge
, H432/02 Mark Scheme June 2026
3
3 Nitrobenzene reacts with Br2 in the presence of a halogen carrier.
MARKING INSTRUCTIONS
NO2 PREPARATION FOR MARKING
RM ASSESSOR
1. Make sure that you have accessed and completed the relevant training packages for on-screen marking: RM Assessor Assessor Online Training;
Nitrobenzene Essential Guide to Marking.
What is the most likely organic product? 2. Make sure that you have read and understood the mark scheme and the question paper for this unit. These are posted on the RM Cambridge
Assessment Support Portal
3. Log-in to RM Assessor and mark the required number of practice responses (“scripts”) and the number of required standardisation responses.
A Br NO2
MARKING
Br 1. Mark strictly to the mark scheme.
2. Marks awarded must relate directly to the marking criteria.
B Br NO2
3. The schedule of dates is very important. It is essential that you meet the RM Assessor 50% and 100% (traditional 40% Batch 1 and 100% Batch 2)
deadlines. If you experience problems, you must contact your Team Leader (Supervisor) without delay.
Br 4. If you are in any doubt about applying the mark scheme, consult your Team Leader by telephone or the RM Assessor messaging system, or by email.
Br 5. Crossed Out Responses
Where a candidate has crossed out a response and provided a clear alternative then the crossed out response is not marked. Where no alternative
response has been provided, examiners may give candidates the benefit of the doubt and mark the crossed out response where legible.
C
NO2
Rubric Error Responses – Optional Questions
Where candidates have a choice of question across a whole paper or a whole section and have provided more answers than required, then all responses
are marked and the highest mark allowable within the rubric is given. Enter a mark for each question answered into RM assessor, which will select the
Br Br
2
D
NO2
Your answer
[1]
Cambridge 2026 Turn over
, H432/02 Mark Scheme June 2026
4
4 Complete combustion of 2.00 g of a hydrocarbon forms 2.57 g of water. highest mark from those awarded. (The underlying assumption is that the candidate has penalised themselves by attempting more questions than
necessary in the time allowed.)
What is the empirical formula of the hydrocarbon?
Multiple Choice Question Responses
A CH
When a multiple choice question has only a single, correct response and a candidate provides two responses (even if one of these responses is correct),
B CH2 then no mark should be awarded (as it is not possible to determine which was the first response selected by the candidate).
When a question requires candidates to select more than one option/multiple options, then local marking arrangements need to ensure consistency of
C CH3 approach.
D CH4 Contradictory Responses
When a candidate provides contradictory responses, then no mark should be awarded, even if one of the answers is correct.
Your answer
[1] Short Answer Questions (requiring only a list by way of a response, usually worth only one mark per response)
Where candidates are required to provide a set number of short answer responses then only the set number of responses should be marked. The
response space should be marked from left to right on each line and then line by line until the required number of responses have been considered. The
5 What is the number of chiral centres in the molecule below? remaining responses should not then be marked. Examiners will have to apply judgement as to whether a ‘second response’ on a line is a development
OH of the ‘first response’, rather than a separate, discrete response. (The underlying assumption is that the candidate is attempting to hedge their bets
CH3 and therefore getting undue benefit rather than engaging with the question and giving the most relevant/correct responses.)
Short Answer Questions (requiring a more developed response, worth two or more marks)
CH3 If the candidates are required to provide a description of, say, three items or factors and four items or factors are provided, then mark on a similar basis
– that is downwards (as it is unlikely in this situation that a candidate will provide more than one response in each section of the response space.)
Longer Answer Questions (requiring a developed response)
Where candidates have provided two (or more) responses to a medium or high tariff question which only required a single (developed) response and
O
not crossed out the first response, then only the first response should be marked. Examiners will need to apply professional judgement as to whether
the second (or a subsequent) response is a ‘new start’ or simply a poorly expressed continuation of the first response.
A 3
B 4
C 5
D 6
3
Your answer
[1]
Cambridge 2026
