TEST BANK for Organic Chemistry 6th Edition
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ff Smith / All Chapters 1 - 29 / Full Complete
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Page ff1
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
ff ff ff ff ff ff ff ff
Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
ff ff ff ff
Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
ff ff ff ff ff ff
Chapter 9 Alcohols, Ethers, and Related Compounds
ff ff ff ff ff ff
Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
ff ff ff ff ff ff ff ff
Substitution
ff
Chapter ff 21 ff Substitution Reactions of Carbonyl Compounds at the α-Carbon
ff ff ff ff ff ff ff
Chapter ff 22 ff Carbonyl Condensation Reactions ff ff
Chapter ff 23 ff Amines
Chapter ff 24 ff Carbon-Carbon Bond-Forming Reactions in Organic Synthesis ff ff ff ff ff
Chapter ff 25 ff Pericyclic Reactions ff
Chapter ff 26 ff Carbohydrates
Chapter ff 27 ff Amino Acids and Proteins
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Chapter ff 28 ff Synthetic Polymers ff
Chapter ff 29 ff Lipids (Available online)
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Page ff2
, Chapter 1: Structure and Bonding
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1. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffcarbon
2 2 5
ffatom? ffA) f f 1s , ff2s , ff2p B) f f 1s2, ff2s2, ff2p2 C) f f 1s2, ff2s2,
6
ff2p D) f f 1s2, ff2s2, ff2p4
2. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa fffluorine
2 2 2
ffatom?fA) f f 1s , ff2s , ff2p B) f f 1s2, ff2s2, ff2p3 C) f f 1s2, ff2s2,
4 2 2 5
ff2p D) f f 1s , ff2s , ff2p
3. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffmagnesium ffcation
2+
ff(Mg )?fA) 1s2, ff2s2, ff2p6 C) 1s2, ff2s2,
6 2
ff2p , ff3s
B) 1s2, ff2s2, ff2p6, ff3s1 D) 1s2, ff2s2, ff2p6, ff3s2, ff3p2
4. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffchlorine ffanion
—
ff(Cl )?fA) 1s2, ff2s2, ff2p6 C)
2 2 6 2 5
1s , ff2s , ff2p , ff3s , ff3p
B) 1s2, ff2s2, ff2p6, ff3s2, ff3p6 D) 1s2, ff2s2, ff2p6, ff3s2, ff3p4
5. Which ffof ffthe fffollowing ffstatements ffabout ffvalence ffelectrons ffis fftrue?
A) They ffare ffthe ffmost fftightly ffheld ffelectrons.
B) They ffdo ffnot ffparticipate ffin ffchemical ffreactions.
Page ff3
, Chapter ff1: ffStructure ffand
ffBonding
C) They ffare ffthe ffoutermost ffelectrons.
D) They ffreveal ffthe ffperiod ffnumber ffof ffa ffsecond-row ffelement.
6. Which ffof ffthe fffollowing ffstatements ffabout ffbonding ffis fftrue?
A) Covalent ffbonds ffresult fffrom ffthe fftransfer ffof ffelectrons fffrom ffone ffelement ffto ffanother.
B) Ionic ffbonds ffresult fffrom ffthe fftransfer ffof ffelectrons fffrom ffa ffmetal ffto ffa ffnon-metal.
C) Ionic ffbonds ffresult fffrom ffthe ffsharing ffof ffelectrons ffbetween fftwo ffnon-metals.
D) Covalent ffbonds ffresult fffrom ffthe ffsharing ffof ffelectrons ffbetween fftwo ffmetals.
7. Which ffof ffthe fffollowing ffwould ffyou ffexpect ffto ffhave ffionic ffbonds?
A) CO B) f f FBr C) f f NF3 D) f f NaCl
8. Which ffof ffthe fffollowing ffmolecules ffhas ffnonpolar ffcovalent ffbonds?
A) HCl B) f f N2 C) f f CHCl3 D) f f NO
9. Which ffof ffthe fffollowing ffmolecules ffcontain ffboth ffcovalent ffand ffionic ffbonds?
A) I, ffII B) f f I, ffIV C) f f II, ffIII D) ffII, ffIV
10. Arrange ffthe fffollowing ffbonds ffin ffdecreasing fforder ffof ffionic ffcharacter, ffputting ffthe
ffmostfionic fffirst.
A) I ff> ffII ff> ffIII ff> ffIV C) IV ff> ffIII ff> ffII ff> ffI
B) IV ff> ffII ff> ffI ff> ffIII D) IV ff> ffII ff> ffIII ff> ffI
11. Which ffof ffthe fffollowing ffstatements ffcorrectly ffdescribes ffthe fftypical ffnumber ffof ffbonds
ffforfcarbon, ffnitrogen, ffand ffoxygen ffin ffmost ffneutral fforganic ffmolecules?
A) Carbon ffforms ff4 ffcovalent ffbonds, ffnitrogen ffforms ff2 ffcovalent ffbonds ffand ffoxygen
ffformsf3 ffcovalent ffbonds.
B) Carbon ffforms ff4 ffcovalent ffbonds, ffnitrogen ffforms ff3 ffcovalent ffbonds ffand ffoxygen
ffformsf2 ffcovalent ffbonds.
Page ff4
ff ff ff ff ff ff
ff Smith / All Chapters 1 - 29 / Full Complete
ff ff ff ff ff ff ff ff ff
Page ff1
,Chapter 1 Structure and Bonding
ff ff ff ff
Chapter 2 Acids and Bases
ff ff ff ff
Chapter 3 Introduction to Organic Molecules and Functional Groups
ff ff ff ff ff ff ff ff
Chapter 4 Alkanes
ff ff
Chapter 5 Stereochemistry
ff ff
Chapter 6 Understanding Organic Reactions
ff ff ff ff
Chapter 7 Alkyl Halides and Nucleophilic Substitution
ff ff ff ff ff ff
Chapter 8 Alkyl Halides and Elimination Reactions
ff ff ff ff ff ff
Chapter 9 Alcohols, Ethers, and Related Compounds
ff ff ff ff ff ff
Chapter 10 Alkenes and Addition Reactions
ff ff ff ff ff
Chapter 11 Alkynes and Synthesis
ff ff ff ff
Chapter 12 Oxidation and Reduction
ff ff ff ff
Spectroscopy A Mass Spectrometry
ff ff ff
Spectroscopy B Infrared Spectroscopy
ff ff ff
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
ff ff ff ff ff
Chapter 13 Radical Reactions
ff ff ff
Chapter 14 Conjugation, Resonance, and Dienes
ff ff ff ff ff
Chapter 15 Benzene and Aromatic Compounds
ff ff ff ff ff
Chapter 16 Reactions of Aromatic Compounds
ff ff ff ff ff
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
ff ff ff ff ff ff ff
Oxidation and Reduction
ff ff ff
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
ff ff ff ff ff
Chapter 19 Carboxylic Acids and Nitriles
ff ff ff ff ff
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
ff ff ff ff ff ff ff ff
Substitution
ff
Chapter ff 21 ff Substitution Reactions of Carbonyl Compounds at the α-Carbon
ff ff ff ff ff ff ff
Chapter ff 22 ff Carbonyl Condensation Reactions ff ff
Chapter ff 23 ff Amines
Chapter ff 24 ff Carbon-Carbon Bond-Forming Reactions in Organic Synthesis ff ff ff ff ff
Chapter ff 25 ff Pericyclic Reactions ff
Chapter ff 26 ff Carbohydrates
Chapter ff 27 ff Amino Acids and Proteins
ff ff ff
Chapter ff 28 ff Synthetic Polymers ff
Chapter ff 29 ff Lipids (Available online)
ff ff
Page ff2
, Chapter 1: Structure and Bonding
ff ff ff ff
1. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffcarbon
2 2 5
ffatom? ffA) f f 1s , ff2s , ff2p B) f f 1s2, ff2s2, ff2p2 C) f f 1s2, ff2s2,
6
ff2p D) f f 1s2, ff2s2, ff2p4
2. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa fffluorine
2 2 2
ffatom?fA) f f 1s , ff2s , ff2p B) f f 1s2, ff2s2, ff2p3 C) f f 1s2, ff2s2,
4 2 2 5
ff2p D) f f 1s , ff2s , ff2p
3. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffmagnesium ffcation
2+
ff(Mg )?fA) 1s2, ff2s2, ff2p6 C) 1s2, ff2s2,
6 2
ff2p , ff3s
B) 1s2, ff2s2, ff2p6, ff3s1 D) 1s2, ff2s2, ff2p6, ff3s2, ff3p2
4. What ffis ffthe ffground-state ffelectronic ffconfiguration ffof ffa ffchlorine ffanion
—
ff(Cl )?fA) 1s2, ff2s2, ff2p6 C)
2 2 6 2 5
1s , ff2s , ff2p , ff3s , ff3p
B) 1s2, ff2s2, ff2p6, ff3s2, ff3p6 D) 1s2, ff2s2, ff2p6, ff3s2, ff3p4
5. Which ffof ffthe fffollowing ffstatements ffabout ffvalence ffelectrons ffis fftrue?
A) They ffare ffthe ffmost fftightly ffheld ffelectrons.
B) They ffdo ffnot ffparticipate ffin ffchemical ffreactions.
Page ff3
, Chapter ff1: ffStructure ffand
ffBonding
C) They ffare ffthe ffoutermost ffelectrons.
D) They ffreveal ffthe ffperiod ffnumber ffof ffa ffsecond-row ffelement.
6. Which ffof ffthe fffollowing ffstatements ffabout ffbonding ffis fftrue?
A) Covalent ffbonds ffresult fffrom ffthe fftransfer ffof ffelectrons fffrom ffone ffelement ffto ffanother.
B) Ionic ffbonds ffresult fffrom ffthe fftransfer ffof ffelectrons fffrom ffa ffmetal ffto ffa ffnon-metal.
C) Ionic ffbonds ffresult fffrom ffthe ffsharing ffof ffelectrons ffbetween fftwo ffnon-metals.
D) Covalent ffbonds ffresult fffrom ffthe ffsharing ffof ffelectrons ffbetween fftwo ffmetals.
7. Which ffof ffthe fffollowing ffwould ffyou ffexpect ffto ffhave ffionic ffbonds?
A) CO B) f f FBr C) f f NF3 D) f f NaCl
8. Which ffof ffthe fffollowing ffmolecules ffhas ffnonpolar ffcovalent ffbonds?
A) HCl B) f f N2 C) f f CHCl3 D) f f NO
9. Which ffof ffthe fffollowing ffmolecules ffcontain ffboth ffcovalent ffand ffionic ffbonds?
A) I, ffII B) f f I, ffIV C) f f II, ffIII D) ffII, ffIV
10. Arrange ffthe fffollowing ffbonds ffin ffdecreasing fforder ffof ffionic ffcharacter, ffputting ffthe
ffmostfionic fffirst.
A) I ff> ffII ff> ffIII ff> ffIV C) IV ff> ffIII ff> ffII ff> ffI
B) IV ff> ffII ff> ffI ff> ffIII D) IV ff> ffII ff> ffIII ff> ffI
11. Which ffof ffthe fffollowing ffstatements ffcorrectly ffdescribes ffthe fftypical ffnumber ffof ffbonds
ffforfcarbon, ffnitrogen, ffand ffoxygen ffin ffmost ffneutral fforganic ffmolecules?
A) Carbon ffforms ff4 ffcovalent ffbonds, ffnitrogen ffforms ff2 ffcovalent ffbonds ffand ffoxygen
ffformsf3 ffcovalent ffbonds.
B) Carbon ffforms ff4 ffcovalent ffbonds, ffnitrogen ffforms ff3 ffcovalent ffbonds ffand ffoxygen
ffformsf2 ffcovalent ffbonds.
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