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Che 232 Exam 1 UKY steelman Questions and Answers

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Che 232 Exam 1 UKY steelman Questions and Answers

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Che 232 Exam 1 UKY steelman
Questions and Answers

steps to naming an alcohol - ANS-1. identify and name parent (carbon attached to -
OH)-- replace "e" with "ol"
2. identify and name substituent
3. locant to each substituent
4. assemble the substituents alphabetically

isopropyl alcohol - ANS-

tert-butyl alcohol - ANS-

benzyl alcohol - ANS-

alcohols have higher boiling points due to.... .... - ANS-hydrogen bonding

conjugate base of an alcohol= - ANS-alkoxide ion R-O

pKa for alcohols= - ANS-15-18


alcohols can be prepared via ....where the leaving group is replaced with an .... - ANS-
substitution, -OH

primary substrate requires= - ANS-SN2

tertiary substrate requires= - ANS-SN1

the conversion of a ketone/aldehyde--> alcohol is an example of - ANS-reduction

three reducing agents: (aldehyde/ketone -->alcohol) - ANS-1. H2, Pt, Pd, or Ni
2. NaBH4 (solvent= EtOH, MeOH, H2O)
3. LiAlH4 (solvent=H2O)-- 2 steps!!

LiAlH4 will react with.... and ... ....but NaBH4 will not - ANS-ester, carboxylic acid

LiAlH4 allows carbonyl to.... - ANS-reform

in order for an oxidation reaction to take place, the alpha carbon must bear a.... - ANS-
proton (not be tertiary)

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