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SCH4U / AP Chem Exam: Unit 4a Chemical Equilibrium Practice Test (ICE Tables, Keq, Qc)

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This high-yield practice exam is the ultimate study tool to master chemical equilibrium calculations and thermodynamics. It features rigorous problems focu sing on calculating Keq from equilibrium concentrations, applying stoichiometry via ICE tables, and finding equilibrium concentrations using perfect squares, the quadratic formula, and approximation methods. It also includes comprehensive sections on evaluating the reaction quotient Qc to predict shifts, determining standard entropy changes S, computing Gibbs Free Energy G for spontaneity, and applying Le Chatelier's Principle to temperature variations. Accompanied by a fully worked, step-by-step answer key that outlines mathematical formulas and final equilibrium states, this resource is perfect for chemistry students looking to secure an A+ on their next midterm or final exam.

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Chemical Equilibrium Practice Test - Unit 4a
Type 1: Calculating Keq from Equilibrium Concentrations

1. Question: A 5.00 L container at 230 °C reaches equilibrium with 0.0185 mol of PCl3, 0.0870 mol of Cl2,
and 0.0158 mol of PCl5. Calculate the value of Keq for the reaction:

PCl3(g) + Cl2(g) ⇌ PCl5(g)

2. Question: A 2.50 L container holds 0.240 mol of CO, 0.4775 mol of H2, and 0.0375 mol of methanol
(CH3OH) at 250 °C in an equilibrium mixture. Calculate Keq for:

CO(g) + 2H2(g) ⇌ CH3OH(g)

3. Question: In a 6.75 L container at 298 K, a system is at equilibrium with 4.725 mol of N2O3, 2.025 mol
of NO2, and 2.025 mol of NO. Calculate the value of Keq for:

N2O3(g) ⇌ NO2(g) + NO(g)




Type 2: Calculating Keq and Equilibrium Concentrations (ICE)

1. Question: Initially, 1.000 mol of water vapor is placed into a 3.00 L container at a specific temperature.
When equilibrium is reached, 0.900 mol of H2O remains. Calculate the equilibrium concentrations of all
substances and the Keq value:

2H2O(g) ⇌ 2H2(g) + O2(g)




2. Question: A student places 3.000 mol of N2 and 2.500 mol of H2 into a 1.00 L closed system. At
equilibrium, the concentration of ammonia (NH3) is 0.850 mol/L. Use an ICE table to find the remaining
equilibrium concentrations and Keq:

N2(g) + 3H2(g) ⇌ 2NH3(g)




3. Question: A sample of 0.873 mol of nitric oxide (NO) and 0.0437 mol of bromine (Br2) is placed in a
3.50 L container. At equilibrium, the mixture contains 0.0518 mol of nitrosyl bromide (NOBr). Calculate
the Keq for the reaction:

2NO(g) + Br2(g) ⇌ 2NOBr(g)

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