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Exam (elaborations)

Chem 162 Exam Questions with Verified Solutions

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Chem 162 Exam Questions with Verified Solutions

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Chem 162 Exam Questions with
Verified Solutions

exothermic reaction - ANS-a chemical reaction that releases energy to its surroundings

"Heat" is best described as - ANS-the energy transferred as a result of a temperature
difference

endothermic reaction - ANS-A reaction that ABSORBS energy in the form of heat

Iodine Vapor depositing on a cool surface - ANS-exothermic

water condensing on a cold glass - ANS-exothermic

propane burning - ANS-exothermic

dry ice subliming - ANS-physical, endothermic reaction

work - ANS--P delta V

the horizontal part of heating curve indicates:
- the mass of material is irrelivant
the energy being added is being used to overcome intermolecular forces
there is no net energy change during phase changes
the material can no longer fain energy
the temperature is rising - ANS-there is no net energy change during phase changes

solid to gas is called - ANS-sublimation

liquid to gas is called - ANS-evaporation

liquid to solid is called - ANS-freezing

solid to liquid - ANS-melting

given = masses of each, same T initial and same amount energy lost, which will end
with the lowest temperature?
highest or lowest Cp (specific heat) - ANS-A copper pot (lowest specific heat (Cp)

which species has a standard enthalpy of formation of zero (delta H of f degrees)
- C (s, diamond)

, - NaCl (s)
- H2 (g)
- Br (l)
- Al2 (s) - ANS-H2 (g)

which of the following ways is not a way to calculate enthalpy of a reaction?
using enthalpies of formation
the temperature change of a reaction is the enthalpy of reaction
the using a calorimeter to determine q cal, relate that. to q run and then delta h rxn
apply hess law using a series of known enthalpy of reactions to achieve an overall
enthalpy of reaction
using bond energies of the reactants and products - ANS-- the temperature change of a
reaction is the enthalpy of reaction

which of the following processes is spontaneous?
- you get an a in this course
- the Tupperware drawer is organized
- a broken touchscreen fixes itself
- rust turns into iron metal and oxygen gas
- sugar dissolves in tea - ANS-- sugar dissolves in tea

in a spontaneous process, the entropy of the ______________ always increases
- universe
- surroundings
- system
- system and the universe
- system, surroundings, and universe - ANS-- universe

at 0 K the entropy of a perfect crystal is
<0
>0
=0 - ANS-= 0

positive entropy - ANS-more disorder

In an exothermic reaction, the external entropy (entropy of the surroundings)
__________ - ANS-increases

endothermic rxn and q - ANS-q is +

exothermic rxn and q - ANS-q is -

w = + - ANS-work done ON system (delta v is -)

w = - - ANS-work done BY system

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