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,TABLE OF CONTENT
CHAPTER 1 Carbon and Its Compounds......Page 27
CHAPTER 2 Anatomy of an Organic Molecule......Page 73
CHAPTER 3 Molecules in Motion: Conformations by Rotations......Page 112
CHAPTER 4 Stereochemistry: Three-Dimensional Structure in Molecules......Page 151
CHAPTER 5 Organic Reaction Mechanism: Using Curved Arrows to Analyze Reaction Mechanisms......Page 212
CHAPTER 6 Acids and Bases......Page 261
CHAPTER 7 π Bonds as Electrophiles: Reactions of Carbonyls and Related Functional Groups......Page 298
CHAPTER 8 π Bonds as Nucleophiles: Reactions of Alkenes, Alkynes, Dienes, and Enols......Page 354
CHAPTER 9 Conjugation and Aromaticity......Page 424
CHAPTER 10 Synthesis Using Aromatic Materials: Electrophilic Aromatic Substitution and Directed Ortho
Metalation......Page 457
CHAPTER 11 Displacement Reactions on Saturated Carbons: SN1 and SN2 Substitution Reactions......Page 520
CHAPTER 12 Formation of π Bonds by Elimination Processes: Elimination and Oxidation Reactions......Page 566
CHAPTER 13 Structure Determination I: Nuclear Magnetic Resonance Spectroscopy......Page 603
CHAPTER 14 Structure Determination II: Mass Spectrometry and Infrared Spectroscopy......Page 674
CHAPTER 15 π Bond Electrophiles Connected to Leaving Groups: Carboxylic Acid Derivatives......Page 722
CHAPTER 16 π Bonds with Hidden Leaving Groups: Reactions of Acetals and Related Compounds......Page 790
CHAPTER 17 Carbonyl-Based Nucleophiles: Aldol, Claisen, Wittig, and Related Enolate Reactions......Page 836
CHAPTER 18 Selectivity and Reactivity in Enolate Reactions: Control of Stereoselectivity and......Page 925
CHAPTER 19 Radicals: Halogenation, Polymerization, and Reduction Reactions......Page 997
CHAPTER 20 Reactions Controlled by Orbital Interaction
Copyright Cengage Learning. Powered by Cognero. Page 2
,Test Bank for
Organic Chemistry Mechanistic Patterns 2nd Edition by Ogilvie, Ackroyd, Browning,
Deslongchamps, Sauer ISBN 9780176702717
Chapter 1-20
CHAPTER 1 - Carbon and Its Compounds
2-
1. Which of the following represents the ground state electron configuration for a O
a. 1s22s22p4
b. 1s22s22p2
c. 1s22s22p6
d. 2s22p4
ANSWER: c
2. How many valence electrons does a nitrogen atom contain?
a. 2
b. 3
c. 5
d. 7
ANSWER: c
ion?
2-
3. How many valence electrons does an O
a. 2
b. 6
c. 8
d. 10
ANSWER: c
ion contain?
4. What is the Lewis structure of a compound that has the formula of CCl3 and contains 24 valence electrons?
a.
b.
c.
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, d.
ANSWER: d
5. How many bonded and non-bonded electrons does a molecule with no formal charges and the formula
C2H4O2 contain?
a. 4 bonded, 4 non-bonded
b. 7 bonded. 4 non-bonded
c. 7 bonded, 5 non-bonded
d. 4 bonded, 7 non-bonded
ANSWER: b
Figure 1
6. Referring to Figure 1, what is the formal charge of the oxygen atom at I?
a. +1
b. 0
c. -1
d. -2
ANSWER: b
7. Referring to Figure 1, what is the formal charge of the oxygen atom at II?
a. +1
b. 0
c. -1
d. -2
ANSWER: c
8. Referring to Figure 1, what is the formal charge of the oxygen atom at III?
a. +1
b. 0
c. -1
d. -2
ANSWER: a
9. What best represents a C-H bond in CH4?
Copyright Cengage Learning. Powered by Cognero. Page 4
,TABLE OF CONTENT
CHAPTER 1 Carbon and Its Compounds......Page 27
CHAPTER 2 Anatomy of an Organic Molecule......Page 73
CHAPTER 3 Molecules in Motion: Conformations by Rotations......Page 112
CHAPTER 4 Stereochemistry: Three-Dimensional Structure in Molecules......Page 151
CHAPTER 5 Organic Reaction Mechanism: Using Curved Arrows to Analyze Reaction Mechanisms......Page 212
CHAPTER 6 Acids and Bases......Page 261
CHAPTER 7 π Bonds as Electrophiles: Reactions of Carbonyls and Related Functional Groups......Page 298
CHAPTER 8 π Bonds as Nucleophiles: Reactions of Alkenes, Alkynes, Dienes, and Enols......Page 354
CHAPTER 9 Conjugation and Aromaticity......Page 424
CHAPTER 10 Synthesis Using Aromatic Materials: Electrophilic Aromatic Substitution and Directed Ortho
Metalation......Page 457
CHAPTER 11 Displacement Reactions on Saturated Carbons: SN1 and SN2 Substitution Reactions......Page 520
CHAPTER 12 Formation of π Bonds by Elimination Processes: Elimination and Oxidation Reactions......Page 566
CHAPTER 13 Structure Determination I: Nuclear Magnetic Resonance Spectroscopy......Page 603
CHAPTER 14 Structure Determination II: Mass Spectrometry and Infrared Spectroscopy......Page 674
CHAPTER 15 π Bond Electrophiles Connected to Leaving Groups: Carboxylic Acid Derivatives......Page 722
CHAPTER 16 π Bonds with Hidden Leaving Groups: Reactions of Acetals and Related Compounds......Page 790
CHAPTER 17 Carbonyl-Based Nucleophiles: Aldol, Claisen, Wittig, and Related Enolate Reactions......Page 836
CHAPTER 18 Selectivity and Reactivity in Enolate Reactions: Control of Stereoselectivity and......Page 925
CHAPTER 19 Radicals: Halogenation, Polymerization, and Reduction Reactions......Page 997
CHAPTER 20 Reactions Controlled by Orbital Interaction
Copyright Cengage Learning. Powered by Cognero. Page 2
,Test Bank for
Organic Chemistry Mechanistic Patterns 2nd Edition by Ogilvie, Ackroyd, Browning,
Deslongchamps, Sauer ISBN 9780176702717
Chapter 1-20
CHAPTER 1 - Carbon and Its Compounds
2-
1. Which of the following represents the ground state electron configuration for a O
a. 1s22s22p4
b. 1s22s22p2
c. 1s22s22p6
d. 2s22p4
ANSWER: c
2. How many valence electrons does a nitrogen atom contain?
a. 2
b. 3
c. 5
d. 7
ANSWER: c
ion?
2-
3. How many valence electrons does an O
a. 2
b. 6
c. 8
d. 10
ANSWER: c
ion contain?
4. What is the Lewis structure of a compound that has the formula of CCl3 and contains 24 valence electrons?
a.
b.
c.
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, d.
ANSWER: d
5. How many bonded and non-bonded electrons does a molecule with no formal charges and the formula
C2H4O2 contain?
a. 4 bonded, 4 non-bonded
b. 7 bonded. 4 non-bonded
c. 7 bonded, 5 non-bonded
d. 4 bonded, 7 non-bonded
ANSWER: b
Figure 1
6. Referring to Figure 1, what is the formal charge of the oxygen atom at I?
a. +1
b. 0
c. -1
d. -2
ANSWER: b
7. Referring to Figure 1, what is the formal charge of the oxygen atom at II?
a. +1
b. 0
c. -1
d. -2
ANSWER: c
8. Referring to Figure 1, what is the formal charge of the oxygen atom at III?
a. +1
b. 0
c. -1
d. -2
ANSWER: a
9. What best represents a C-H bond in CH4?
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