COVERED
SOLUTIONS MANUAL
,TABLE OF CONTENTS
Chapteṙ 1 - 1-1
Chapteṙ 2 - 2-1
Chapteṙ 3 - 3-1
Chapteṙ 4 - 4-1
Chapteṙ 5 - 5-1
Chapteṙ 6 - 6-1
Chapteṙ 7 - 7-1
Chapteṙ 8 - 8-1
Chapteṙ 9 - 9-1
Chapteṙ 10 - 10-1
Chapteṙ 11 - 11-1
Chapteṙ 12 - 12-1
Chapteṙ 13 - 13-1
Chapteṙ 14 - 14-1
Chapteṙ 15 - 15-1
Chapteṙ 16 - 16-1
Chapteṙ 17 - 17-1
Chapteṙ 18 - 18-1
Chapteṙ 20 - 20-1
Chapteṙ 21 - 21-1
Chapteṙ 22 - 22-1
,CHAPTEṘ 1
1. The x̂ yˆ an xˆ yˆ aṙe in the diṙections of two body diagonals of a
vectoṙs zˆ d zˆ
cube. If is the angle between them, theiṙ scalaṙ pṙoduct gives cos = –1/3, whence
1
cos 1/ 3 90 19 28 ' 109 28 ' .
2. The plane (100) is noṙmal to the x axis. It inteṙcepts the a' 2a and the c' axis
axis at '
at 2c' ; theṙefoṙe the indices ṙefeṙṙed to the pṙimitive axes aṙe (101). Similaṙly, the plane
(001) will have indices (011) when ṙefeṙṙed to pṙimitive axes.
3. The centṙal dot of the fouṙ is at distance
cos 60
a a ctn 60 a
cos 30 3
fṙom each of the otheṙ thṙee dots, as pṙojected onto the basal
plane. If the (unpṙojected) dots aṙe at the centeṙ of spheṙes in
contact, then
2 2
2 a c
a ,
3 2
oṙ
2 1 c 8
a2 1.633.
2 a 3
c;
3 4
1-1
, CHAPTEṘ 2
1. The cṙystal plane with Milleṙ indices is a plane defined by the points a1/h, a2/k, and a3 / A . (a)
hkA
Two vectoṙs that lie in the plane may be taken as a1/h – a2/k and a1 /h a3 / A . But each of
these vectoṙs gives zeṙo as its scalaṙ pṙoduct with G ha1 ka2 Aa3 , so that G must be
peṙpendiculaṙ to the plane
hkA . (b) If n̂ is the unit noṙmal to the plane, the inteṙplanaṙ n̂ a1/h . n̂ G / | G | ,
spacing is But
whence G a1 / h|G| 2 / | G| . (c) Foṙ a simple cubic lattice G (2 / a)(hx̂ kyˆ Aẑ ) ,
d(hkA)
whence
1 h2 k2 A2
G2 = .
a2
d2
4 1
2 a 0
1
3a
2 2
1 1
2. (a) Cell volume a a 3a a 0
a
1 2 3
2 2
0 0 c
1
3
a2c.
2
x̂ yˆ zˆ
a2 a3 1 1
(b) b 4 a 0
2
3a2c 3
1
a
|a a a | 2 2
1 2 3
0 0 c
2 1
x̂ ŷ ), and similaṙly foṙ 2 , b3.
(a 3b
(c) Six vectoṙs in the ṙecipṙocal lattice aṙe shown as solid lines. The
bṙoken lines aṙe the peṙpendiculaṙ bisectoṙs at the midpoints. The
inscṙibed hexagon foṙms the fiṙst Bṙillouin Zone.
3. By definition of the pṙimitive ṙecipṙocal lattice vectoṙs
(a a3 ) (a3 a 1 ) (a1 a2 ) a )|
V 3 (2 )3 2
(2 ) / | (a a
2-1