,Student Solutions
Manual to
Accompany Atkins’
Physical Chemistry
ELEVENTH EDITION
Peter Bolgar
Haydn Lloyd
Aimee North
Vladimiras Oleinikovas
Stephanie Smith
and
James Keeler
Department of Chemistry
University of Cambridge
UK
1
, 1
Great Clarendon Street, Oxford, OX2 6DP,
United Kingdom
Oxford University Press is a department of the University of Oxford.
It furthers the University’s objective of excellence in research, scholarship,
and education by publishing worldwide. Oxford is a registered trade mark of
Oxford University Press in the UK and in certain other countries
© Oxford University Press 2018
The moral rights of the authors have been asserted
Eighth edition 2006
Ninth edition 2010
Tenth edition 2014
Impression: 1
All rights reserved. No part of this publication may be reproduced, stored in
a retrieval system, or transmitted, in any form or by any means, without the
prior permission in writing of Oxford University Press, or as expressly permitted
by law, by licence or under terms agreed with the appropriate reprographics
rights organization. Enquiries concerning reproduction outside the scope of the
above should be sent to the Rights Department, Oxford University Press, at the
address above
You must not circulate this work in any other form
and you must impose this same condition on any acquirer
Published in the United States of America by Oxford University Press
198 Madison Avenue, New York, NY 10016, United States of America
British Library Cataloguing in Publication Data
Data available
ISBN 978–0–19–255086–6
Printed in Great Britain by
Bell & Bain Ltd., Glasgow
Links to third party websites are provided by Oxford in good faith and
for information only. Oxford disclaims any responsibility for the materials
contained in any third party website referenced in this work.
, Table of contents
Preface vii
1 The properties of gases 1
1A The perfect gas 1
1B The kinetic model 12
1C Real gases 24
2 Internal energy 41
2A Internal energy 41
2B Enthalpy 47
2C Thermochemistry 50
2D State functions and exact differentials 58
2E Adiabatic changes 66
3 The second and third laws 73
3A Entropy 73
3B Entropy changes accompanying specific processes 79
3C The measurement of entropy 91
3D Concentrating on the system 101
3E Combining the First and Second Laws 107
4 Physical transformations of pure substances 119
4A Phase diagrams of pure substances 119
4B Thermodynamic aspects of phase transitions 121
5 Simple mixtures 137
5A The thermodynamic description of mixtures 137
5B The properties of solutions 149
5C Phase diagrams of binary systems: liquids 165
5D Phase diagrams of binary systems: solids 173
5E Phase diagrams of ternary systems 179
5F Activities 184
6 Chemical equilibrium 199
6A The equilibrium constant 199
Manual to
Accompany Atkins’
Physical Chemistry
ELEVENTH EDITION
Peter Bolgar
Haydn Lloyd
Aimee North
Vladimiras Oleinikovas
Stephanie Smith
and
James Keeler
Department of Chemistry
University of Cambridge
UK
1
, 1
Great Clarendon Street, Oxford, OX2 6DP,
United Kingdom
Oxford University Press is a department of the University of Oxford.
It furthers the University’s objective of excellence in research, scholarship,
and education by publishing worldwide. Oxford is a registered trade mark of
Oxford University Press in the UK and in certain other countries
© Oxford University Press 2018
The moral rights of the authors have been asserted
Eighth edition 2006
Ninth edition 2010
Tenth edition 2014
Impression: 1
All rights reserved. No part of this publication may be reproduced, stored in
a retrieval system, or transmitted, in any form or by any means, without the
prior permission in writing of Oxford University Press, or as expressly permitted
by law, by licence or under terms agreed with the appropriate reprographics
rights organization. Enquiries concerning reproduction outside the scope of the
above should be sent to the Rights Department, Oxford University Press, at the
address above
You must not circulate this work in any other form
and you must impose this same condition on any acquirer
Published in the United States of America by Oxford University Press
198 Madison Avenue, New York, NY 10016, United States of America
British Library Cataloguing in Publication Data
Data available
ISBN 978–0–19–255086–6
Printed in Great Britain by
Bell & Bain Ltd., Glasgow
Links to third party websites are provided by Oxford in good faith and
for information only. Oxford disclaims any responsibility for the materials
contained in any third party website referenced in this work.
, Table of contents
Preface vii
1 The properties of gases 1
1A The perfect gas 1
1B The kinetic model 12
1C Real gases 24
2 Internal energy 41
2A Internal energy 41
2B Enthalpy 47
2C Thermochemistry 50
2D State functions and exact differentials 58
2E Adiabatic changes 66
3 The second and third laws 73
3A Entropy 73
3B Entropy changes accompanying specific processes 79
3C The measurement of entropy 91
3D Concentrating on the system 101
3E Combining the First and Second Laws 107
4 Physical transformations of pure substances 119
4A Phase diagrams of pure substances 119
4B Thermodynamic aspects of phase transitions 121
5 Simple mixtures 137
5A The thermodynamic description of mixtures 137
5B The properties of solutions 149
5C Phase diagrams of binary systems: liquids 165
5D Phase diagrams of binary systems: solids 173
5E Phase diagrams of ternary systems 179
5F Activities 184
6 Chemical equilibrium 199
6A The equilibrium constant 199
