CHEMISTRY 12TH EDITION BY ATKINS ALL
19 CHAPTERS COVERED BY PETER ATKINS
JULIO DE PAULA AND JAMES KEELER SOLUTIONS
MANUAL UPDATED 2026 GRADED A+
,TABLE OF CONTENT
1. Focus 1: The properties of gases
2. Focus 2: The First Law
3. Focus 3: The Second and Third Laws
4. Focus 4: Physical transformations of pure substances
5. Focus 5: Simple mixtures
6. Focus 6: Chemical equilibrium
7. Focus 7: Quantum theory
8. Focus 8: Atomic structure and spectra
9. Focus 9: Molecular structure
10. Focus 10: Molecular symmetry
11. Focus 11: Molecular spectroscopy
12. Focus 12: Magnetic resonance
13. Focus 13: Statistical thermodynamics
14. Focus 14: Molecular interactions
15. Focus 15: Solids
16. Focus 16: Molecules in motion
17. Focus 17: Chemical kinetics
18. Focus 18: Reaction dynamics
19. Focus 19: Processes at solid surfaces
,CHAPTER 1: THE PROPERTIES OF GASES
This chapter explores gas behavior through kinetic molecular theory, gas laws,
and real versus ideal gas deviations. Key concepts include pressure, volume,
temperature relationships, diffusion, effusion, and molar mass determination.
Understanding these principles allows chemists to predict gas behavior, apply
stoichiometry in reactions, calculate densities, and address practical laboratory
and industrial gas handling safely and accurately.
1. Which law relates pressure and volume of a gas at constant
temperature?
A. Charles’ Law
B. Boyle’s Law
C. Avogadro’s Law
D. Gay-Lussac’s Law
Correct Answer: B
Rationale: Boyle’s Law states that pressure is inversely proportional to
volume at constant temperature; other laws relate temperature or moles
to volume or pressure.
2. A 2.0 L container of gas at 1.0 atm is compressed to 1.0 L at constant
temperature. What is the new pressure?
A. 0.5 atm
B. 1.0 atm
C. 2.0 atm
D. 4.0 atm
Correct Answer: C
Rationale: Using Boyle’s Law (P1V1 = P2V2), pressure doubles when
volume is halved at constant temperature.
3. At constant pressure, which variable is directly proportional to gas
volume?
A. Temperature
B. Pressure
C. Moles
D. Density
Correct Answer: A
Rationale: Charles’ Law states that gas volume increases linearly with
temperature at constant pressure; density and moles are not directly
involved in this relation.
, 4. A gas has a volume of 3.0 L at 300 K. If heated to 450 K at constant
pressure, what is the new volume?
A. 2.0 L
B. 4.5 L
C. 3.5 L
D. 6.0 L
Correct Answer: B
Rationale: Charles’ Law: V1/T1 = V2/T2 → V2 = (3.0 × 450)/300 = 4.5 L.
5. Which gas law involves the relationship between pressure and
temperature at constant volume?
A. Boyle’s Law
B. Charles’ Law
C. Gay-Lussac’s Law
D. Avogadro’s Law
Correct Answer: C
Rationale: Gay-Lussac’s Law states that pressure is directly proportional
to temperature at constant volume.
6. One mole of an ideal gas occupies 22.4 L at STP. Which principle is used?
A. Dalton’s Law
B. Ideal Gas Law
C. Graham’s Law
D. Raoult’s Law
Correct Answer: B
Rationale: The Ideal Gas Law (PV = nRT) calculates molar volume at STP;
Dalton’s and Graham’s laws are unrelated to molar volume.
7. Two gases at the same temperature and pressure have equal volumes.
What can be inferred? A. Different moles
B. Same number of molecules
C. Different densities
D. Different temperatures
Correct Answer: B
Rationale: Avogadro’s Law states equal volumes of gases at the same T
and P contain equal molecules, regardless of identity.
8. A gas mixture exerts a total pressure of 3 atm. If one component exerts 1
atm, what is the partial pressure of the other?
A. 1 atm
B. 2 atm