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Difunctional Carbonyls notes
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An introduction to the reactions of malonates and 1,3 dicarbonyls including Claisen reaction, alkylation, ring synthesis. A look at enones, how to create them and their reactivity of 1,2 and 1,4 addition attack, the use of organometallics with enones. Then notes on the formation and addition of 1,5 dicarbonyls including Robinson's annelation. An introduction to the disconnection approach for retrosynthesis. 1,4 dicarbonyls and their reactions are introduced. 1,2 Dicarbonyls/Difunctionals reacti...

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  • Class notes
  •  • 15 pages • 
  • by sophieberry • 
  • uploaded  30-05-2020
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Orgo II 4
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Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Carbonyl rearrangements: Schmidt, Beckmann, Curtius, Wolff Enols and Enolates: ketone deuteration, alpha-halogenations, alpha-alkylations, enamine alkylations, decarboxylation Aldol Reaction: general, condensation, Cross Aldol condensation, ...

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  • Class notes
  •  • 23 pages • 
  • by hzhang22 • 
  • uploaded  24-04-2020
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Answer key for Mid-term 2 exam Form A(1)
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CHEM 2420 ---Organic Chemistry II Fall 2015 Mid-Exam No. 2: Chapter 17-18 (Form A) Name: ÿ'ÿ,ÿt ÿ-,4 Instructions: A) Please print your name on the line above. B) Make sure you have 12 pages. C) Good luck! Question Score Multiple choice /80 Free response Bonus Total /20 /5 /105 1 IP aÿ.,o e Section 1. Multiple Choice (80 points) Bubble the choice that best completes each phrase and/or answers the question on the Scantron sheet provided. Answers written in this section of...

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  •  Book
  • Exam (elaborations)
  •  • 12 pages • 
  • by studysoup • 
  • uploaded  25-04-2021
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Carbonyl Group Chemistry
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Application of carbonyl group chemistry in organic synthesis: The material covered in this section includes (i) a-hydrogen acidity, (ii) acid and base promoted keto-enol tautomerism, (iii) a-enolate chemistry, including alkylation (iv) named reactions including Michael reaction, Aldol addition, Aldol condensation, Claisen condensation (v) ring-forming reactions including Dieckman condensation and Robinson annulations

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  • Class notes
  •  • 24 pages • 
  • by Elizabeth1234 • 
  • uploaded  28-01-2020
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