Allenshieh

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Virginia Commonwealth University

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Organic Chemistry I - Free Radical Halogenation Overview (CHEM 301)

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This note covers essential, highly tested concepts for Free Radical Halogenation (FRH) (i.e. FR Bromination and Chlorination). Topics include: 1. The three mechanistic steps of FRH (Initiation, Propagation, Termination) 2. Single vs. double-headed arrows (i.e. electron-pushing diagrams) 3. Selectivity differences between FR Bromination and FR Chlorination 4. What is hv and NBS? 5. Radical resonance (aka “rearrangement”)

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• 3 pages •
by allenshieh •
uploaded 2021

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